氰尿酰氯
氰尿酰氯用途
用于合成荧光增白剂、活性染料、医药、农药等
【用途二】
三聚氯氰是生产高效、低毒的均三氮苯类除草剂和杀虫剂的重要中间体，也是生产荧光增白剂、涤纶等多种合成纤维染色用的活性染料的中间体。还用于合成树脂、橡胶、聚合物防老剂、炸药、织物防缩水剂、表面活性剂等方面的生产。
氰尿酰氯名称
[ CAS 号 ]:
108-77-0
[ 中文名 ]:
三氯三聚氰
[ 英文名 ]:
Cyanuric chloride
[中文别名 ]:
[英文别名 ]:
- CYANURIC CHLORIDE FOR SYNTHESIS
- CYANURIC CHLORIDE (2,4,6-TRICHLORO-1,3,5-TRIACINE)
- 1,3,5-Triazine, 2,4,6-trichloro-
- chlorotriazine
- Cyanuric chloride
- Cyanuricchloride
- trichloro-s-triazine
- CYANURCHLORID
- trichloro-1,3,5-triazine
- 2,4,6-TRICHLORO-S-TRIAZINE
氰尿酰氯物理化学性质
[ 密度 ]:
1.8±0.1 g/cm3
[ 沸点 ]:
190.0±0.0 °C at 760 mmHg
[ 熔点 ]:
145-147 °C(lit.)
[ 分子式 ]:
C3Cl3N3
[ 分子量 ]:
184.411
[ 闪点 ]:
214.4±8.8 °C
[ 精确质量 ]:
182.915787
[ PSA ]:
38.67000
[ LogP ]:
2.00
[ 外观性状 ]:
白色结晶粉末
[ 蒸汽密度 ]:
6.36 (vs air)
[ 蒸汽压 ]:
0.8±0.3 mmHg at 25°C
[ 折射率 ]:
1.586
[ 储存条件 ]:
库房通风低温干燥,与氧化剂、碱分开存放
[ 稳定性 ]:
Stable. Incompatible with strong oxidizing agents, water.
[ 水溶解性 ]:
reacts
氰尿酰氯MSDS
氰尿酰氯毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- XZ1400000
- CHEMICAL NAME :
- s-Triazine, 2,4,6-trichloro-
- CAS REGISTRY NUMBER :
- 108-77-0
- BEILSTEIN REFERENCE NO. :
- 0124246
- LAST UPDATED :
- 199710
- DATA ITEMS CITED :
- 14
- MOLECULAR FORMULA :
- C3-Cl3-N3
- MOLECULAR WEIGHT :
- 184.41
- WISWESSER LINE NOTATION :
- T6N CN ENJ BG DG FG
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- REFERENCE :
- 28ZPAK "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha, Czechoslovakia, 1972 Volume(issue)/page/year: -,152,1972
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration into the eye
- SPECIES OBSERVED :
- Rodent - rabbit
- REFERENCE :
- 28ZPAK "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha, Czechoslovakia, 1972 Volume(issue)/page/year: -,152,1972 ** ACUTE TOXICITY DATA **
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 485 mg/kg
- TOXIC EFFECTS :
- Behavioral - somnolence (general depressed activity) Nutritional and Gross Metabolic - weight loss or decreased weight gain Nutritional and Gross Metabolic - body temperature decrease
- REFERENCE :
- GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 12(8),35,1968
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 350 mg/kg
- TOXIC EFFECTS :
- Behavioral - somnolence (general depressed activity) Behavioral - food intake (animal) Nutritional and Gross Metabolic - weight loss or decreased weight gain
- REFERENCE :
- GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 12(8),35,1968
- TYPE OF TEST :
- LC50 - Lethal concentration, 50 percent kill
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 10 mg/m3/2H
- TOXIC EFFECTS :
- Autonomic Nervous System - other (direct) parasympathomimetic Behavioral - somnolence (general depressed activity) Musculoskeletal - other changes
- REFERENCE :
- GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 12(8),35,1968
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 10 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- 38MKAJ "Patty's Industrial Hygiene and Toxicology," 3rd rev. ed., Clayton, G.D., and F.E. Clayton, eds., New York, John Wiley & Sons, Inc., 1978-82. Vol. 3 originally pub. in 1979; pub. as 2nd rev. ed. in 1985. Volume(issue)/page/year: 2C,4891,1982
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intravenous
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 18 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#07336 ** OTHER MULTIPLE DOSE TOXICITY DATA **
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 2800 mg/kg/28D-C
- TOXIC EFFECTS :
- Liver - changes in liver weight Blood - pigmented or nucleated red blood cells Related to Chronic Data - death
- REFERENCE :
- TOXID9 Toxicologist. (Soc. of Toxicology, Inc., 475 Wolf Ledge Parkway, Akron, OH 44311) V.1- 1981- Volume(issue)/page/year: 12,119,1992
- TYPE OF TEST :
- TCLo - Lowest published toxic concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 1880 ug/m3/4H/11W-I
- TOXIC EFFECTS :
- Blood - changes in erythrocyte (RBC) count Nutritional and Gross Metabolic - weight loss or decreased weight gain Related to Chronic Data - death
- REFERENCE :
- GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 12(8),35,1968 ** TUMORIGENIC DATA **
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 20 gm/kg/73W-I
- TOXIC EFFECTS :
- Tumorigenic - equivocal tumorigenic agent by RTECS criteria Skin and Appendages - tumors Reproductive - Tumorigenic effects - uterine tumors
- REFERENCE :
- VOONAW Voprosy Onkologii. Problems of Oncology. For English translation, see PONCAU. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-10, 1928-37; V.1- 1955- Volume(issue)/page/year: 12(4),78,1966
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Multiple routes
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 16 gm/kg/73W-I
- TOXIC EFFECTS :
- Tumorigenic - equivocal tumorigenic agent by RTECS criteria Skin and Appendages - tumors Tumorigenic - tumors at site of application
- REFERENCE :
- VOONAW Voprosy Onkologii. Problems of Oncology. For English translation, see PONCAU. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-10, 1928-37; V.1- 1955- Volume(issue)/page/year: 12(4),78,1966 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X4559 No. of Facilities: 20 (estimated) No. of Industries: 2 No. of Occupations: 3 No. of Employees: 2336 (estimated) No. of Female Employees: 299 (estimated)
氰尿酰氯安全信息
[ 符号 ]:
GHS05, GHS06
[ 信号词 ]:
Danger
[ 危害声明 ]:
H302-H314-H317-H330-H335
[ 补充危害声明 ]:
Reacts violently with water.
[ 警示性声明 ]:
P260-P280-P284-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338
[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
[ 危害码 (欧洲) ]:
C:Corrosive
[ 风险声明 (欧洲) ]:
R14;R22;R26;R34;R43
[ 安全声明 (欧洲) ]:
S26-S28-S36/37/39-S45-S46-S63-S28A
[ 危险品运输编码 ]:
UN 2670 8/PG 2
[ WGK德国 ]:
1
[ RTECS号 ]:
XZ1400000
[ 包装等级 ]:
II
[ 危险类别 ]:
8
[ 海关编码 ]:
2933691000
氰尿酰氯合成路线
氰尿酰氯上下游产品
氰尿酰氯上游产品
氰尿酰氯下游产品
氰尿酰氯制备
三聚氯氰的生产通常由氯氰制备和氯氰聚合两个过程组成。生成氯氰的方法有多种，诸如硫氰酸甲酯和氯的合成法、氢氰酸溶于氯仿通入氯气的合成法、氢氰酸法、氰化钠法、尿素法、氢氰酸与氯气的直接氯氰化法等，目前工业上生产三聚氯氰一般采用氰化钠及氢氰酸为原料的两种方法。1.氰化钠法 用氰化钠为原料与氯气反应生成氯氰，再聚合生成三聚氯氰经急冷、结晶制得产品。原料消耗定额：氰化钠1073kg/t、氯气1700kg/t。2.氢氰酸法以氢氰酸为原料与氯气反应生成氯氰，再聚合生成三聚氯氰，经急冷、结晶制得产品。原料消耗定额：氢氰酸500kg/t、氯气1200kg/t。
氰尿酰氯海关
[ 海关编码 ]: 2933691000
[ 中文概述 ]:
2933691000 三聚氰氯。监管条件:无。增值税率:17.0%。退税率:9.0%。最低关税:6.0%。普通关税:20.0%
[ 申报要素 ]: 品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期
[ Summary ]:
2933691000 2,4,6-trichloro-1,3,5-triazine。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。Lowest tariff:6.0%。General tariff:20.0%
氰尿酰氯文献
J. Chromatogr. A. 1388 , 60-8, (2015)
Electrospray ionization (ESI) is the most useful interface for mass spectrometry associated with liquid chromatography (LC). However, analyses of polar metabolites become a challenge because the high ...
Metal Microporous Aromatic Polymers with Improved Performance for Small Gas Storage.Chemistry 21 , 13357-63, (2015)
A novel metal-doping strategy was developed for the construction of iron-decorated microporous aromatic polymers with high small-gas-uptake capacities. Cost-effective ferrocene-functionalized micropor...
Microwave assisted synthesis of 2,2'-arylene-substituted bis(4H-3,1-benzoxazin-4-one) derivatives using the complex cyanuric chloride/N,N-dimethylformamide.Molecules 17(10) , 11607-15, (2012)
A new and efficient method has been designed to prepare 2,2'-arylene-substituted bis(4H-3,1-benzoxazin-4-one) derivatives by using the mixture of cyanuric chloride and N,N-dimethylformamide in a micro...
相关化工产品/化学物质：
推荐生产厂家/供应商：
公司名：上海吉至生化科技有限公司
区域：上海市奉贤区
价格：
￥138.0/500g
联系人：刘佳
产品详情：三聚氯氰
公司名：上海源溪生物科技有限公司
区域：上海市浦东新区
价格：
￥需询单/1g
联系人：赖经理
产品详情：2,4,6-Trichloro-s-triazine
公司名：上海阿拉丁生化科技股份有限公司
区域：上海市浦东新区
价格：
￥需询单/1g
￥33.0/50g
￥149.0/500g
￥29.0/25g
联系人：阿拉丁李高志
产品详情：三聚氯氰
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相关化合物
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