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己二酰氯

己二酰氯用途

【用途一】
有机中间体。医药上用以合成胆影酸。
【用途二】
有机中间体，医药上用以合成胆影酸。

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己二酰氯名称

[ CAS 号 ]:
111-50-2

[ 中文名 ]:
己二酰氯

[ 英文名 ]:
Adipoyl chloride

[中文别名 ]:

[英文别名 ]:

MFCD00000759
HEXANEDIOYL CHLORIDE
Adipoyl chloride
Hexyl Dichlroide
adipoyl
Adipic dichloride
adipinyl dichloride
Adipoyldichlorid
adipic chloride
Hexanedioyl dichloride

己二酰氯物理化学性质

[ 密度 ]:
1.3±0.1 g/cm3

[ 沸点 ]:
273.9±0.0 °C at 760 mmHg

[ 分子式 ]:
C₆H₈Cl₂O₂

[ 分子量 ]:
183.033

[ 闪点 ]:
99.4±21.2 °C

[ 精确质量 ]:
181.990128

[ PSA ]:
34.14000

[ LogP ]:
1.52

[ 外观性状 ]:
棕色透明液体

[ 蒸汽压 ]:
0.0±0.5 mmHg at 25°C

[ 折射率 ]:
1.460

[ 储存条件 ]:
Refrigerator

[ 稳定性 ]:
Stability Reacts violently with water to form hydrochloric acid. Incompatible with water, alcohols, bases, oxidizing agents. Protect from moisture.

[ 水溶解性 ]:
起反应

己二酰氯MSDS

己二酰氯安全信息

[ 符号 ]:

GHS05

[ 信号词 ]:
Danger

[ 危害声明 ]:
H314

[ 警示性声明 ]:
P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
C:Corrosive

[ 风险声明 (欧洲) ]:
R14;R20/21/22;R29;R34

[ 安全声明 (欧洲) ]:
S26-S36/37/39-S45-S8

[ 危险品运输编码 ]:
UN 3265 8/PG 2

[ WGK德国 ]:
3

[ 包装等级 ]:
II

[ 危险类别 ]:
8

[ 海关编码 ]:
2917190090

己二酰氯合成路线

己二酰氯上下游产品

己二酰氯上游产品

己二酰氯下游产品

己二酰氯制备

由己二酸与氯化亚砜反应：将己二酸与氯化亚砜投入反应锅，在90-95℃回流氯化5h，放冷，减压除去剩余的氯化亚砜，得成品。原料消耗定额：己二酸830kg/t、氯化亚砜1660kg/t。

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己二酰氯海关

[ 海关编码 ]: 2917190090

[ 中文概述 ]:
2917190090 其他无环多元羧酸. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 对苯二甲酸请注明4-CBA值, 对苯二甲酸请注明P-TL酸值, 对苯二甲酸请注明色度, 对苯二甲酸请注明水分

[ Summary ]:
2917190090 acyclic polycarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

己二酰氯文献

Poly(anhydride-ester) and poly(N-vinyl-2-pyrrolidone) blends: salicylic acid-releasing blends with hydrogel-like properties that reduce inflammation.

Macromol. Biosci. 15(3) , 342-50, (2015)

Polymers such as poly(N-vinyl-2-pyrrolidone) (PVP) have been used to prepare hydrogels for wound dressing applications but are not inherently bioactive. For enhanced healing, PVP was blended with sali...

Novel Redox-Responsive Amphiphilic Copolymer Micelles for Drug Delivery: Synthesis and Characterization.

AAPS J. 17 , 1357-68, (2015)

A novel redox-responsive amphiphilic polymer was synthesized with bioreductive trimethyl-locked quinone propionic acid for a potential triggered drug delivery application. The aim of this study was to...

Ultrasensitive and label-free molecular-level detection enabled by light phase control in magnetoplasmonic nanoantennas.

Nat. Commun. 6 , 6150, (2015)

Systems allowing label-free molecular detection are expected to have enormous impact on biochemical sciences. Research focuses on materials and technologies based on exploiting localized surface plasm...

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