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2-氨基蒽醌

2-氨基蒽醌用途

【用途一】
用于制蒽醌染料等
【用途二】
还原染料的中间体，主要用于制造还原蓝RSN，还原黄G，还原黄8G和1-氯-2-氨基蒽醌染料。此外，在造纸工业中可用作催化剂以节约烧碱。

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2-氨基蒽醌名称

[ CAS 号 ]:
117-79-3

[ 中文名 ]:
2-氨基蒽醌

[ 英文名 ]:
2-Aminoanthraquinone

[中文别名 ]:

[英文别名 ]:

EINECS 204-208-4
2-Amino-9,10-anthraquinone
2-Aminoanthraquinone
9,10-Anthracenedione, 2-amino-
MFCD00001233

2-氨基蒽醌物理化学性质

[ 密度 ]:
1.4±0.1 g/cm3

[ 沸点 ]:
472.9±34.0 °C at 760 mmHg

[ 熔点 ]:
292-295 °C (dec.)(lit.)

[ 分子式 ]:
C₁₄H₉NO₂

[ 分子量 ]:
223.227

[ 闪点 ]:
239.8±25.7 °C

[ 精确质量 ]:
223.063324

[ PSA ]:
60.16000

[ LogP ]:
2.75

[ 外观性状 ]:
深棕色粉末

[ 蒸汽压 ]:
0.0±1.2 mmHg at 25°C

[ 折射率 ]:
1.708

[ 储存条件 ]:
库房通风低温干燥

[ 稳定性 ]:
Stable. Incompatible with strong oxidizing agents.

2-氨基蒽醌MSDS

2-氨基蒽醌毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: CB5120000

CHEMICAL NAME :: Anthraquinone, 2-amino-

CAS REGISTRY NUMBER :: 117-79-3

LAST UPDATED :: 199701

DATA ITEMS CITED :: 22

MOLECULAR FORMULA :: C14-H9-N-O2

MOLECULAR WEIGHT :: 223.24

WISWESSER LINE NOTATION :: L C666 BV IVJ EZ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 336 gm/kg/8W-C

TOXIC EFFECTS :: Kidney, Ureter, Bladder - urine volume increased Kidney, Ureter, Bladder - proteinuria

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 77 gm/kg/48W-I

TOXIC EFFECTS :: Kidney, Ureter, Bladder - changes in tubules (including acute renal failure, acute tubular necrosis) Endocrine - hyperglycemia Blood - pigmented or nucleated red blood cells

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 115 gm/kg/78W-C

TOXIC EFFECTS :: Tumorigenic - Carcinogenic by RTECS criteria Liver - tumors

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 655 gm/kg/78W-C

TOXIC EFFECTS :: Tumorigenic - Carcinogenic by RTECS criteria Liver - tumors Blood - lymphoma, including Hodgkin's disease

TYPE OF TEST :: TD - Toxic dose (other than lowest)

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 225 gm/kg/78W-C

TOXIC EFFECTS :: Tumorigenic - neoplastic by RTECS criteria Liver - tumors

TYPE OF TEST :: TD - Toxic dose (other than lowest)

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 330 gm/kg/78W-C

TOXIC EFFECTS :: Tumorigenic - equivocal tumorigenic agent by RTECS criteria Liver - tumors Blood - lymphoma, including Hodgkin's disease

TYPE OF TEST :: TD - Toxic dose (other than lowest)

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 32 gm/kg/77W-C

TOXIC EFFECTS :: Tumorigenic - neoplastic by RTECS criteria Liver - tumors

TYPE OF TEST :: TD - Toxic dose (other than lowest)

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1890 gm/kg/78W-C

TOXIC EFFECTS :: Tumorigenic - Carcinogenic by RTECS criteria Liver - tumors

TYPE OF TEST :: TD - Toxic dose (other than lowest)

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 3780 gm/kg/78W-C

TOXIC EFFECTS :: Tumorigenic - Carcinogenic by RTECS criteria Liver - tumors

TYPE OF TEST :: TD - Toxic dose (other than lowest)

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 2730 gm/kg/78W-C

TOXIC EFFECTS :: Tumorigenic - equivocal tumorigenic agent by RTECS criteria Liver - tumors

TYPE OF TEST :: TD - Toxic dose (other than lowest)

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 5600 gm/kg/80W-C

TOXIC EFFECTS :: Tumorigenic - Carcinogenic by RTECS criteria Liver - tumors

MUTATION DATA

TYPE OF TEST :: Micronucleus test

TEST SYSTEM :: Rodent - mouse Cells - not otherwise specified

DOSE/DURATION :: 6 mg/L

REFERENCE :: EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume(issue)/page/year: 24,96,1994 *** REVIEWS *** IARC Cancer Review:Animal Limited Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 27,191,1982 IARC Cancer Review:Human No Adequate Data IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 27,191,1982 IARC Cancer Review:Group 3 IMSUDL IARC Monographs, Supplement. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) No.1- 1979- Volume(issue)/page/year: 7,56,1987

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2-氨基蒽醌安全信息

[ 符号 ]:

GHS08

[ 信号词 ]:
Warning

[ 危害声明 ]:
H351

[ 警示性声明 ]:
P281

[ 个人防护装备 ]:
Eyeshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
Xn:Harmful;

[ 风险声明 (欧洲) ]:
R40

[ 安全声明 (欧洲) ]:
S36/37/39

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ RTECS号 ]:
CB5120000

[ 包装等级 ]:
II

[ 海关编码 ]:
2922399090

2-氨基蒽醌合成路线

2-氨基蒽醌上下游产品

2-氨基蒽醌上游产品

2-氨基蒽醌下游产品

2-氨基蒽醌制备

由蒽醌-2-磺酸铵盐氨化制得，工艺过程如下：将蒽醌-2-磺酸铵盐240kg、间硝基苯磺酸钠（防染盐S）70kg及25%氨水（含氨100%174kg）打浆，压入高压釜。加热至184-188℃，压力为3.73-3.92MPa（表压），保温压反应10h，反应毕，边冷却，边放氨。冷至80℃，将物料压入脱氨锅在80℃脱氨2h。升温至100℃，吸滤，用100℃热水3000L洗涤。将滤饼烘干，得2-氨基蒽醌。收率70%。（2）2-氯蒽醌和氨水在催化剂硫酸铜的悬浮物中经高温压反应，制得2-氨基蒽醌。先将2-氯蒽醌、硫酸铜、氨水打浆，充分混合压入氨化高压锅中，升温至213-215℃，于5.1-5.39MPa压力下反应5h，放压回收余氨。将反应产物压入过滤器，经过滤、水洗、干燥而得成品。产品规格：外观为红棕色粉末的工业品含量（以总氨值计）86.0%。

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2-氨基蒽醌海关

[ 海关编码 ]: 2922399090

[ 中文概述 ]:
2922399090 其他氨基醛、氨基酮及其盐（包括氨基醌及其盐，但含有一种以上含氧基的除外）. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 乙醇胺及其盐应报明色度, 乙醇胺及其盐应报明包装

[ Summary ]:
2922399090 other amino-aldehydes, amino-ketones and amino-quinones, other than those containing more than one kind of oxygen function; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

2-氨基蒽醌文献

Reversible off-on fluorescence probe for hypoxia and imaging of hypoxia-normoxia cycles in live cells.

J. Am. Chem. Soc. 134(48) , 19588-91, (2012)

We report a fully reversible off-on fluorescence probe for hypoxia. The design employs QSY-21 as a Förster resonance energy transfer (FRET) acceptor and cyanine dye Cy5 as a FRET donor, based on our f...

[A routine analytical method for carcinogenic isomers in commercial 1-aminoanthraquinone and 1-aminoanthracene by high performance liquid chromatography].

Sangyo. Igaku. 28(2) , 124-5, (1986)

Alterations in drug-metabolizing enzymes during feeding of the carcinogen 2-aminoanthraquinone.

Toxicol. Appl. Pharmacol. 60(2) , 204-12, (1981)

更多文献

2-氨基蒽醌

2-氨基蒽醌用途

2-氨基蒽醌名称

2-氨基蒽醌物理化学性质

2-氨基蒽醌MSDS

详细MSDS(安全技术说明书)

2-氨基蒽醌毒性和生态

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

2-氨基蒽醌安全信息

2-氨基蒽醌合成路线

详细合成路线

2-氨基蒽醌上下游产品

2-氨基蒽醌上游产品

2-氨基蒽醌下游产品

2-氨基蒽醌制备

2-氨基蒽醌海关

2-氨基蒽醌文献

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