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二茂铁甲醛

二茂铁甲醛用途

用于制备手性乙烯亚氨基甲醇二茂铁，应用在选择性偶氮甲碱叶立德环化加成反应用于制备手性乙烯亚氨基甲醇二茂铁，应用在选择性偶氮甲碱叶立德环化加成反应用于光敏剂，防腐剂，手性催化剂以及抗肿瘤医药的中间体（飞机隐形原料）

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二茂铁甲醛名称

[ CAS 号 ]:
12093-10-6

[ 中文名 ]:
二茂铁甲醛

[ 英文名 ]:
Ferrocenecarboxaldehyde

[中文别名 ]:

[英文别名 ]:

FORMYLFERROCENE
MFCD00001429
Ferrocene,formyl
1-carboxaldehyde-ferrocene
formyl-ferrocen
FERROCENECARBALDEHYDE
FERROCENEALDEHYDE
Cyclopentadienyl(formylcyclopentadienyl)iron
Ferrocene Carboxyaldehyde
ferrocene monocarbaldehyde

二茂铁甲醛物理化学性质

[ 密度 ]:
1.149g/cm3

[ 沸点 ]:
213.6ºC at 760 mmHg

[ 熔点 ]:
118-120 °C(lit.)

[ 分子式 ]:
C₁₁H₁₀FeO

[ 分子量 ]:
214.042

[ 闪点 ]:
98.8ºC

[ 精确质量 ]:
214.008102

[ PSA ]:
17.07000

[ LogP ]:
1.60960

[ 外观性状 ]:
结晶固体

[ 蒸汽压 ]:
5.03mmHg at 25°C

[ 折射率 ]:
1.623

[ 储存条件 ]:
存放于惰性气体之中;避免空气

[ 稳定性 ]:
Stable. Incompatible with strong oxidizing agents.

[ 水溶解性 ]:
不溶

二茂铁甲醛MSDS

二茂铁甲醛安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 危害码 (欧洲) ]:
T

[ 风险声明 (欧洲) ]:
R45:May cause cancer. R23/24/25:Toxic by inhalation, in contact with skin and if swallowed . R34:Causes burns. R42/43:May cause sensitization by inhalation and skin contact .

[ 安全声明 (欧洲) ]:
22-24/25

[ 危险品运输编码 ]:
UN 3262 8/PG 2

[ WGK德国 ]:
3

[ 包装等级 ]:
II

[ 危险类别 ]:
6.1

[ 海关编码 ]:
2912299000

二茂铁甲醛合成路线

二茂铁甲醛上下游产品

二茂铁甲醛上游产品

二茂铁甲醛下游产品

二茂铁甲醛海关

[ 海关编码 ]: 2912299000

[ 中文概述 ]:
2912299000. 其他不含其他含氧基的环醛. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 四聚甲醛报明外观

[ Summary ]:
2912299000. other cyclic aldehydes without other oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

二茂铁甲醛文献

Photocytotoxic oxovanadium(IV) complexes of ferrocenyl-terpyridine and acetylacetonate derivatives.

Eur. J. Med. Chem. 92 , 332-41, (2015)

Oxovanadium(IV) complexes [VO(Fc-tpy)(acac)](ClO4) (1), [VO(Fc-tpy)(nap-acac)](ClO4) (2), [VO(Fc-tpy)(py-acac)](ClO4) (3) and [VO(Ph-tpy)(py-acac)](ClO4) (4) of 4'-ferrocenyl-2,2':6',2"-terpyridine (F...

Interaction of ferrocene appended Ru(II), Rh(III) and Ir(III) dipyrrinato complexes with DNA/protein, molecular docking and antitumor activity.

Eur. J. Med. Chem. 84 , 17-29, (2014)

Efficacy of the ferrocene appended piano-stool dipyrrinato complexes [(η(6)-C6H6)RuCl(fcdpm)] (1), [(η(6)-C10H14)RuCl(fcdpm)] (2), [(η(6)-C12H18)RuCl(fcdpm)] (3) [(η(5)-C5Me5)RhCl(fcdpm)] (4) and [(η(...

A carbon nanotube/poly [Ni-(Protoporphyrin IX)] composite for amperometric detection of long chain aliphatic amines.

Bioelectrochemistry 104 , 51-7, (2015)

Poly [Ni-Protoporphyrin] film (pNiPP), containing multiwall carbon nanotubes (MWCNT) was used to cover a glassy carbon electrode. The hybrid material (pNiPP/MWCNT) successfully combines the permselect...

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