苯氧乙酸
苯氧乙酸用途
苯氧乙酸名称
[ CAS 号 ]:
122-59-8
[ 中文名 ]:
苯氧乙酸
[ 英文名 ]:
Phenoxyacetic acid
[中文别名 ]:
[英文别名 ]:
- PHENOXYETHYLBROMIDE
- 1-phenoxy-2-bromoethane
- phenoxy acetic acid
- PhO-CH2COOH
- 2-phenoxy-ethyl bromide
- 2-bromoethyl phenyl ether
- B-BROMOPHENETOLE
- Phenylium
- Acetic acid, 2-phenoxy-
- 1-bromo-2-phenyloxyethane
苯氧乙酸生物活性
苯氧乙酸物理化学性质
[ 密度 ]:
1.2±0.1 g/cm3
[ 沸点 ]:
285.0±0.0 °C at 760 mmHg
[ 熔点 ]:
98-100 °C(lit.)
[ 分子式 ]:
C8H8O3
[ 分子量 ]:
152.147
[ 闪点 ]:
115.1±13.3 °C
[ 精确质量 ]:
152.047348
[ PSA ]:
46.53000
[ LogP ]:
1.34
[ 外观性状 ]:
灰白色结晶粉末
[ 蒸汽压 ]:
0.0±0.6 mmHg at 25°C
[ 折射率 ]:
1.541
[ 储存条件 ]:
室温
[ 稳定性 ]:
Stable. Substances to be avoided include strong bases, strong oxidizing agents. Combustible.
[ 水溶解性 ]:
0.1-0.5 g/100 mL at 17 ºC
苯氧乙酸MSDS
苯氧乙酸毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- AJ2230000
- CHEMICAL NAME :
- Acetic acid, phenoxy-
- CAS REGISTRY NUMBER :
- 122-59-8
- BEILSTEIN REFERENCE NO. :
- 0907949
- LAST UPDATED :
- 199710
- DATA ITEMS CITED :
- 12
- MOLECULAR FORMULA :
- C8-H8-O3
- MOLECULAR WEIGHT :
- 152.16
- WISWESSER LINE NOTATION :
- QV1OR
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- REFERENCE :
- FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 17,887,1979 ** ACUTE TOXICITY DATA **
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 1500 mg/kg
- TOXIC EFFECTS :
- Sense Organs and Special Senses (Eye) - effect, not otherwise specified Behavioral - somnolence (general depressed activity) Gastrointestinal - changes in structure or function of salivary glands
- REFERENCE :
- ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology, Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1- 1990- Volume(issue)/page/year: 1,94,1990
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 323 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- TSPMA6 Travaux de la Societe de Pharmacie de Montpellier. (Soc. de Pharmacie de Montpellier, Faculte de Pharmacie de Montpellier, Ave. Ch.-Flahault, 34060 Montpellier, France) V.1- 1942- Volume(issue)/page/year: 34,121,1974
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 3750 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 46(1),25,1981
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intravenous
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 1 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- PHARAT Pharmazie. (VEB Verlag Volk und Gesundheit, Neue Gruenstr. 18, Berlin DDR-1020, Ger. Dem. Rep.) V.1- 1946- Volume(issue)/page/year: 18,642,1963
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- >200 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 17,887,1979
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- >5 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 17,887,1979
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Unreported
- SPECIES OBSERVED :
- Rodent - guinea pig
- DOSE/DURATION :
- 1400 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 46(1),25,1981 ** OTHER MULTIPLE DOSE TOXICITY DATA **
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 910 mg/kg/26W-I
- TOXIC EFFECTS :
- Liver - liver function tests impaired Blood - changes in other cell count (unspecified) Blood - changes in erythrocyte (RBC) count
- REFERENCE :
- GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 46(1),25,1981 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X6440 No. of Facilities: 5 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 1524 (estimated)
苯氧乙酸安全信息
[ 符号 ]:
GHS07
[ 信号词 ]:
Warning
[ 危害声明 ]:
H302-H315-H319-H335
[ 警示性声明 ]:
P261-P305 + P351 + P338
[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves
[ 危害码 (欧洲) ]:
Xn:Harmful
[ 风险声明 (欧洲) ]:
R22;R36/37/38
[ 安全声明 (欧洲) ]:
S26-S36-S37/39
[ 危险品运输编码 ]:
NONH for all modes of transport
[ WGK德国 ]:
3
[ RTECS号 ]:
AJ2230000
[ 海关编码 ]:
2942000000
苯氧乙酸合成路线
苯氧乙酸上下游产品
苯氧乙酸上游产品
苯氧乙酸下游产品
苯氧乙酸制备
三、生产方法简述
由苯酚与氯乙酸在碱性溶液中进行缩合，然后酸化制得苯氧基乙酸。
苯氧乙酸海关
[ 海关编码 ]: 2918990090
[ 中文概述 ]:
2918990090. 其他含其他附加含氧基羧酸（包括酸酐、酰卤化物、过氧化物和过氧酸及该税号的衍生物）. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%
[ 申报要素 ]: 品名, 成分含量, 用途
[ Summary ]:
2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%
苯氧乙酸文献
Molecules 12(2) , 245-54, (2007)
A series of eight new azomethine derivatives were synthesized by reacting 2-formylphenoxyacetic acid with aromatic amines. The chemical structures of these compounds were confirmed by means of 1H-NMR,...
Penicillin V acylase from Pectobacterium atrosepticum exhibits high specific activity and unique kinetics.Int. J. Biol. Macromol. 79 , 1-7, (2015)
Penicillin V acylases (PVAs, E.C.3.5.11) belong to the Ntn hydrolase super family of enzymes that catalyze the deacylation of the side chain from phenoxymethyl penicillin (penicillin V). Penicillin ac...
Correlations between chromatographic parameters and bioactivity predictors of potential herbicides.J. Chromatogr. Sci. 52 , 676-84, (2014)
Different liquid chromatography techniques, including reversed-phase liquid chromatography on Purosphere RP-18e, IAM.PC.DD2 and Cosmosil Cholester columns and micellar liqud chromatography with a Puro...
相关化工产品/化学物质：
推荐生产厂家/供应商：
公司名：上海吉至生化科技有限公司
区域：上海市奉贤区
价格：
￥218.0/500g
￥68.0/100g
联系人：刘佳
产品详情：苯氧乙酸
公司名：上海脉铂医药科技有限公司
区域：上海市嘉定区
价格：
￥489.0/50mg
￥需询单/1g
￥需询单/1g
￥需询单/1g
联系人：李先生
产品详情：Phenoxyacetic acid
公司名：上海创赛科技有限公司
区域：上海市嘉定区
价格：
￥55.0/100g
￥166.0/500g
￥802.0/2500g
￥490.0/50mg
联系人：夏言
产品详情：[Perfemiker]苯氧乙酸,98%
公司名：上海阿拉丁生化科技股份有限公司
区域：上海市浦东新区
价格：
￥92.9/100g
￥307.9/500g
￥406.9/250mg
￥1132.9/3kg
联系人：阿拉丁李高志
产品详情：苯氧乙酸
公司名：中山市迪欣化工有限公司
区域：中山市三角镇
价格：
￥60.0/25kg
联系人：王洁
产品详情：苯氧乙酸
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相关化合物
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