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四氢吡咯

四氢吡咯用途

【用途一】
用于制备药物、杀菌剂、杀虫剂等
【用途二】
医药原料、有机合成、特殊有机溶剂。
【用途三】
有机合成。杀虫剂。杀菌剂。环氧树脂固化剂。橡胶促进剂。抑制剂。
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四氢吡咯名称

[ CAS 号 ]:
123-75-1

[ 中文名 ]:
四氢吡咯

[ 英文名 ]:
Pyrrolidine

[中文别名 ]:

[英文别名 ]:

四氢吡咯物理化学性质

[ 密度 ]:
0.8±0.1 g/cm3

[ 沸点 ]:
89.5±8.0 °C at 760 mmHg

[ 熔点 ]:
-63 °C

[ 分子式 ]:
C4H9N

[ 分子量 ]:
71.121

[ 闪点 ]:
2.8±0.0 °C

[ 精确质量 ]:
71.073502

[ PSA ]:
12.03000

[ LogP ]:
0.37

[ 外观性状 ]:
透明至黄色液体

[ 蒸汽密度 ]:
2.45 (vs air)

[ 蒸汽压 ]:
58.6±0.2 mmHg at 25°C

[ 折射率 ]:
1.428

[ 储存条件 ]:
库房通风低温干燥,与氧化剂、酸类分开存放

[ 稳定性 ]:
Stable; flammable. Incompatible with strong acids, strong oxidizing agents.

[ 水溶解性 ]:
水溶性：完全混溶；可溶于：醇,氯仿,乙醚

四氢吡咯MSDS

详细MSDS(安全技术说明书)

四氢吡咯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :
UX9650000
CHEMICAL NAME :
Pyrrolidine
CAS REGISTRY NUMBER :
123-75-1
BEILSTEIN REFERENCE NO. :
0102395
LAST UPDATED :
199701
DATA ITEMS CITED :
11
MOLECULAR FORMULA :
C4-H9-N
MOLECULAR WEIGHT :
71.14
WISWESSER LINE NOTATION :
T5MTJ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
300 mg/kg
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold Behavioral - excitement Vascular - other changes
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 18(2),29,1974
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
450 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
BCFAAI Bollettino Chimico Farmaceutico. (Societa Editoriale Farmaceutica, Via Ausonio 12, 20123 Milan, Italy) V.33- 1894- Volume(issue)/page/year: 103,414,1964
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1300 mg/m3/2H
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold Behavioral - excitement Vascular - other changes
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 18(2),29,1974
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
420 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 88,82,1946
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
56 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#06769
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
250 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,104,1982
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
250 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,104,1982
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Mammal - species unspecified
DOSE/DURATION :
250 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 39(4),86,1974 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 0.1 mg/m3;Skin JAN 1993
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四氢吡咯安全信息

[ 符号 ]:

GHS02, GHS05, GHS07

[ 信号词 ]:
Danger

[ 危害声明 ]:
H225-H302 + H332-H314

[ 警示性声明 ]:
P210-P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
F:Flammable;C:Corrosive;

[ 风险声明 (欧洲) ]:
R11;R20/21/22;R35

[ 安全声明 (欧洲) ]:
S16-S26-S36/37/39-S45-S33

[ 危险品运输编码 ]:
UN 1922 3/PG 2

[ WGK德国 ]:
2

[ RTECS号 ]:
UX9650000

[ 包装等级 ]:
II

[ 危险类别 ]:
3

[ 海关编码 ]:
2933990090

四氢吡咯合成路线

详细合成路线

四氢吡咯上下游产品

四氢吡咯上游产品

四氢吡咯下游产品

四氢吡咯制备

１．丁二醇法　经脱氢制γ丁内酯；再氨化而得，其反应式如下：



　２．顺酐法　以顺酐为原料，经一步加氢、氨化而得，其反应式如下：
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四氢吡咯海关

[ 海关编码 ]: 2933990090

[ 中文概述 ]:
2933990090. 其他仅含氮杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期

[ Summary ]:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

四氢吡咯文献

Prediction of the chromatographic retention of acid-base compounds in pH buffered methanol-water mobile phases in gradient mode by a simplified model.

J. Chromatogr. A. 1385 , 42-8, (2015)

Retention of ionizable analytes under gradient elution depends on the pH of the mobile phase, the pKa of the analyte and their evolution along the programmed gradient. In previous work, a model depend...

Electrospray ionization mass spectrometry of non-covalent complexes formed between N-alkylimidazolium-containing zwitterionic sulfonates and protonated bases.

Eur. J. Mass Spectrom. (Chichester, Eng.) 20(6) , 467-75, (2015)

This paper describes non-covalent complexes between zwitterionic 3-(1-alkyl-3N-imidazolio)- propane-1-sulfonates and different amines. Electrospray ionization (ESI) mass spectrometry and collision- in...

Attractors in Sequence Space: Peptide Morphing by Directed Simulated Evolution.

Mol. Inform. 34 , 709-714, (2016)


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【四氢吡咯】化源网提供四氢吡咯CAS号123-75-1，四氢吡咯MSDS及其说明、性质、英文名、生产厂家、作用/用途、分子量、密度、沸点、熔点、结构式等。CAS号查询四氢吡咯上化源网，专业又轻松。>>电脑版：四氢吡咯

标题：四氢吡咯_MSDS_用途_密度_四氢吡咯CAS号【123-75-1】_化源网 地址：https://m.chemsrc.com/mip/cas/123-75-1_58206.html