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N-三甲基硅基乙酰胺

N-三甲基硅基乙酰胺名称

[ CAS 号 ]:
13435-12-6

[ 中文名 ]:
N-三甲基硅基乙酰胺

[ 英文名 ]:
N-(Trimethylsilyl)acetamide

[中文别名 ]:

[英文别名 ]:

EINECS 236-565-7
N-Trimethylsilylacetamide,TMS acetamide
N-(Trimethylsilyl)acetamide
N-Trimethylsilylacetamide
MFCD00008671
N-TMS-acetamide
Acetamide, N-(trimethylsilyl)-

N-三甲基硅基乙酰胺物理化学性质

[ 密度 ]:
0.9±0.1 g/cm3

[ 沸点 ]:
190.2±0.0 °C at 760 mmHg

[ 熔点 ]:
46-49 °C(lit.)

[ 分子式 ]:
C₅H₁₃NOSi

[ 分子量 ]:
131.248

[ 闪点 ]:
57.2±0.0 °C

[ 精确质量 ]:
131.076645

[ PSA ]:
29.10000

[ LogP ]:
0.60

[ 外观性状 ]:
白色至淡黄色结晶块

[ 蒸汽压 ]:
0.5±0.3 mmHg at 25°C

[ 折射率 ]:
1.406

[ 储存条件 ]:
Flammables area

[ 水溶解性 ]:
起反应

N-三甲基硅基乙酰胺MSDS

N-三甲基硅基乙酰胺毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: AD0250000

CHEMICAL NAME :: Acetamide, N-(trimethylsilyl)-

CAS REGISTRY NUMBER :: 13435-12-6

BEILSTEIN REFERENCE NO. :: 0741928

LAST UPDATED :: 199701

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C5-H13-N-O-Si

MOLECULAR WEIGHT :: 131.28

WISWESSER LINE NOTATION :: 1VM-SI-1&1&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 350 mg/kg

TOXIC EFFECTS :: Immunological Including Allergic - decreased immune response

REFERENCE :: StoGD# Personal Communication from G.D. Stoner, Dept. of Community Medicine, School of Medicine, Univ. of California, La Jolla, CA 92037, May 25, 1975 Volume(issue)/page/year: 27MAY1975

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N-三甲基硅基乙酰胺安全信息

[ 危害码 (欧洲) ]:
F:Flammable;Xi:Irritant;

[ 风险声明 (欧洲) ]:
R11;R36/37/38

[ 安全声明 (欧洲) ]:
S37/39-S26

[ 危险品运输编码 ]:
1325

[ WGK德国 ]:
3

[ RTECS号 ]:
AD0250000

[ 包装等级 ]:
III

[ 危险类别 ]:
4.1

[ 海关编码 ]:
2931900090

N-三甲基硅基乙酰胺合成路线

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N-三甲基硅基乙酰胺上游产品

N-三甲基硅基乙酰胺下游产品

N-三甲基硅基乙酰胺海关

[ 海关编码 ]: 2931900090

[ 中文概述 ]:
2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

N-三甲基硅基乙酰胺文献

M.Vecchi and K.Kaiser

J. Chromatogr. A. 26 , 22, (1967)

D.R. Knapp

Handbook of Analytical Derivatization Reactions , (1979), 572

Quantitative analysis of ascorbic acid in tissues by gas-liquid chromatography.

Anal. Biochem. 43 , 401, (1971)

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