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甜菜安

甜菜安用途

Desmedipham 是一种选择性的全身性苯基氨基甲酸酯除草剂。 Desmedipham 的作用是破坏 CO2 的固定,抑制 ATP 和 NADPH2 的产生,以及 Hill 反应的抑制。

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甜菜安名称

[ CAS 号 ]:
13684-56-5

[ 中文名 ]:
甜菜安

[ 英文名 ]:
Desmedipham

[中文别名 ]:

[英文别名 ]:

Ethyl (3-((phenylcarbamoyl)oxy)phenyl)carbamate
EINECS 237-198-5
MFCD00055462
3-[(Ethoxycarbonyl)amino]phenyl phenylcarbamate
ethyl 3-phenylcarbamoyloxycarbanilate
Desmedipham
ethyl {3-[(phenylcarbamoyl)oxy]phenyl}carbamate

甜菜安生物活性

[ 描述 ]:

Desmedipham 是一种选择性的全身性苯基氨基甲酸酯除草剂。 Desmedipham 的作用是破坏 CO2 的固定,抑制 ATP 和 NADPH2 的产生,以及 Hill 反应的抑制。

[ 相关类别 ]:

研究领域 >> 其他

信号通路 >> 其他 >> 其他

[参考文献]

[1]. Tânia Vidal, et al. Acute and Chronic Toxicity of Betanal(®)Expert and Its Active Ingredients on Nontarget Aquatic Organisms From Different Trophic Levels. Environ Toxicol. 2012 Sep;27(9):537-48.

甜菜安物理化学性质

[ 密度 ]:
1.2±0.1 g/cm3

[ 沸点 ]:
495.4±55.0 °C at 760 mmHg

[ 熔点 ]:
120 °C

[ 分子式 ]:
C₁₆H₁₆N₂O₄

[ 分子量 ]:
300.309

[ 闪点 ]:
253.4±31.5 °C

[ 精确质量 ]:
300.110992

[ PSA ]:
76.66000

[ LogP ]:
4.49

[ 蒸汽压 ]:
0.0±1.3 mmHg at 25°C

[ 折射率 ]:
1.568

[ 储存条件 ]:
0-6°C

甜菜安MSDS

甜菜安毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: FD0425000

CHEMICAL NAME :: Carbamic acid, phenylcarbamoyloxyphenyl-, ethyl ester

CAS REGISTRY NUMBER :: 13684-56-5

LAST UPDATED :: 199612

DATA ITEMS CITED :: 6

MOLECULAR FORMULA :: C16-H16-N2-O4

MOLECULAR WEIGHT :: 300.34

WISWESSER LINE NOTATION :: 2OVMR COVMR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 9600 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85ARAE "Agricultural Chemicals," Thomson, W.T., 4 vols., Fresno, CA, Thomson Publications, 1976/77 revision Volume(issue)/page/year: 2,92,1977

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: >500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,237,1991

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >2 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: FMCHA2 Farm Chemicals Handbook. (Meister Pub., 37841 Euclid Ave., Willoughy, OH 44094) Volume(issue)/page/year: -,C99,1991

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - quail

DOSE/DURATION :: 2480 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85DPAN "Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel," Perkow, W., Berlin, Verlag Paul Parey, 1971-1976 Volume(issue)/page/year: -,-,1971/1976 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 1 mg/m3 JAN 1993

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甜菜安安全信息

[ 符号 ]:

GHS09

[ 信号词 ]:
Warning

[ 危害声明 ]:
H410

[ 警示性声明 ]:
P273-P391-P501

[ 个人防护装备 ]:
Eyeshields;Gloves

[ 危害码 (欧洲) ]:
N:Dangerousfortheenvironment;

[ 风险声明 (欧洲) ]:
R50/53

[ 安全声明 (欧洲) ]:
S60-S61

[ 危险品运输编码 ]:
UN 3077

[ RTECS号 ]:
FD0425000

[ 海关编码 ]:
2924299038

甜菜安合成路线

甜菜安上下游产品

甜菜安上游产品

甜菜安下游产品

甜菜安海关

[ 海关编码 ]: 2924299038

[ 中文概述 ]:
2924299038 甜菜安、特丁草胺、乙氧苯草胺等〔包括甜菜宁、戊菌隆、酰草隆、乙草胺、乙霉威〕。监管条件:S(进出口农药登记证明)。增值税率:17.0%。退税率:9.0%。最低关税:6.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 包装

[ 监管条件 ]: S.进出口农药登记证明

[ Summary ]:
2924299038 2-chloro-n-(ethoxymethyl)-n-(2-ethyl-6-methylphenyl)acetamide。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:30.0%

甜菜安文献

Expression of a bacterial gene in transgenic plants confers resistance to the herbicide phenmedipham.

Plant Mol. Biol. 25(6) , 977-87, (1994)

Tobacco plants were genetically engineered to express a detoxifying pathway for the herbicide phenmedipham. A gene from Arthrobacter oxidans strain P52 that encodes an enzyme catalysing the hydrolytic...

Acute and chronic toxicity of Betanal(®)Expert and its active ingredients on nontarget aquatic organisms from different trophic levels.

Environ. Toxicol. 27(9) , 537-48, (2012)

As a way to improve the efficacy to target organisms, new pesticide generation is based on technologically advanced coformulations of two or more active ingredients. One example is Betanal(®)Expert, a...

Liquid chromatographic/mass spectrometric determination of desmedipham and phenmedipham and their metabolites in soil.

J. AOAC Int. 84(5) , 1407-12, (2001)

A simple method is described for the simultaneous determination of residues of 2 carbamate herbicides (phenmedipham and desmedipham) and related metabolites (m-aminophenol, aniline, and m-toluidine) i...

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甜菜安