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3-苯氧基苄醇

3-苯氧基苄醇用途

【用途一】
用作农药、医药中间体
【用途二】
间苯氧基苄醇是氯菊酯、苯醚菊酯和醚菊酯等杀虫剂的中间体。

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3-苯氧基苄醇名称

[ CAS 号 ]:
13826-35-2

[ 中文名 ]:
3-苯氧基苄醇

[ 英文名 ]:
(3-Phenoxyphenyl)methanol

[中文别名 ]:

[英文别名 ]:

Benzenemethanol, 3-phenoxy-
(3-Phenoxyphenyl)methanol
3-(Hydroxymethyl)diphenyl Ether
EINECS 237-525-1
3-phenoxybenzylalcohol
MFCD00004636
3-Phenoxybenzyl alcohol

3-苯氧基苄醇物理化学性质

[ 密度 ]:
1.2±0.1 g/cm3

[ 沸点 ]:
377.8±0.0 °C at 760 mmHg

[ 熔点 ]:
4-7°C

[ 分子式 ]:
C₁₃H₁₂O₂

[ 分子量 ]:
200.233

[ 闪点 ]:
151.3±17.4 °C

[ 精确质量 ]:
200.083725

[ PSA ]:
29.46000

[ LogP ]:
3.03

[ 外观性状 ]:
透明淡黄色液体

[ 蒸汽压 ]:
0.0±0.9 mmHg at 25°C

[ 折射率 ]:
1.596

[ 储存条件 ]:
室温

[ 稳定性 ]:
Stable. Combustible. Incompatible with strong oxidizing agents.

[ 水溶解性 ]:
不溶

3-苯氧基苄醇MSDS

3-苯氧基苄醇毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: DP0775400

CHEMICAL NAME :: Benzyl alcohol, m-phenoxy-

CAS REGISTRY NUMBER :: 13826-35-2

BEILSTEIN REFERENCE NO. :: 0475312

LAST UPDATED :: 199710

DATA ITEMS CITED :: 9

MOLECULAR FORMULA :: C13-H12-O2

MOLECULAR WEIGHT :: 200.25

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0537668 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1496 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Behavioral - ataxia Lungs, Thorax, or Respiration - dyspnea

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0537669

TYPE OF TEST :: LC - Lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >2 gm/m3/1H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0537668

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 2040 mg/kg

TOXIC EFFECTS :: Brain and Coverings - other degenerative changes

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 35(1),47,1991

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 575 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: JAFCAU Journal of Agricultural and Food Chemistry. (American Chemical Soc., Distribution Office Dept. 223, POB 57136, West End Stn., Washington, DC 20037) V.1- 1953- Volume(issue)/page/year: 25,9,1977

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 10 gm/kg

TOXIC EFFECTS :: Behavioral - muscle weakness Behavioral - ataxia Skin and Appendages - dermatitis, other (after systemic exposure)

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0537669

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3-苯氧基苄醇安全信息

[ 符号 ]:

GHS07, GHS09

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302-H400

[ 警示性声明 ]:
P273

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xn:Harmful;

[ 风险声明 (欧洲) ]:
R22

[ 安全声明 (欧洲) ]:
S26-S36/37

[ 危险品运输编码 ]:
UN 3082 9 / PGIII

[ WGK德国 ]:
3

[ RTECS号 ]:
DP0775400

[ 海关编码 ]:
2909491000

3-苯氧基苄醇合成路线

3-苯氧基苄醇上下游产品

3-苯氧基苄醇上游产品

3-苯氧基苄醇下游产品

3-苯氧基苄醇制备

【方法一】
间苯氧基苄醇是由间苯氧基苯甲醛和甲醛在浓碱存在下进行康尼查罗反应，分别得到间苯氧基苄醇和甲酸钠，进行分离等后处理，蒸馏得到产品。
间苯氧基苄醇也可以用间苯氧基苯甲酸酯经氢化铝锂还原、间苯氧基苯甲醛催化加氢还原、间苯氧基氯苄进行水解或与乙酸钠反应生成相应的乙酸酯，再进行水解等方法均能制备产品。

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3-苯氧基苄醇海关

[ 海关编码 ]: 2909491000

[ 中文概述 ]:
2909491000 间苯氧基苄醇。监管条件:无。增值税率:17.0%。退税率:9.0%。最低关税:4.0%。普通关税:11.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2909491000 (3-phenoxyphenyl)methanol。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。Lowest tariff:4.0%。General tariff:11.0%

3-苯氧基苄醇文献

Perturbation of rat heart plasma membrane fluidity due to metabolites of permethrin insecticide.

Cardiovasc. Toxicol. 11(3) , 226-34, (2011)

Due to increased global use, acute and chronic exposures to pyrethroid insecticides in humans are of clinical concern. Pyrethroids have a primary mode of action that involves interference with the sod...

[Gas chromatographic determination of butyl alcohols in the atmospheric air].

Gig. Sanit. (2) , 68-9, (1990)

The in vitro metabolism of a pyrethroid insecticide, permethrin, and its hydrolysis products in rats.

Toxicology 235(3) , 176-84, (2007)

The in vitro metabolism of permethrin and its hydrolysis products in rats was investigated. Cis- and trans-permethrin were mainly hydrolyzed by liver microsomes, and also by small-intestinal microsome...

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3-苯氧基苄醇

3-苯氧基苄醇用途

3-苯氧基苄醇名称

3-苯氧基苄醇物理化学性质

3-苯氧基苄醇MSDS

详细MSDS(安全技术说明书)

3-苯氧基苄醇毒性和生态

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

3-苯氧基苄醇安全信息

3-苯氧基苄醇合成路线

详细合成路线

3-苯氧基苄醇上下游产品

3-苯氧基苄醇上游产品

3-苯氧基苄醇下游产品

3-苯氧基苄醇制备

3-苯氧基苄醇海关

3-苯氧基苄醇文献

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