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4-甲基-5-硝基咪唑

4-甲基-5-硝基咪唑名称

[ CAS 号 ]:
14003-66-8

[ 中文名 ]:
4-甲基-5-硝基咪唑

[ 英文名 ]:
4-Methyl-5-nitroimidazole

[中文别名 ]:

4-硝基-5-甲基咪唑

[英文别名 ]:

4-Methyl-5-nitro-1H-imidazole
EINECS 237-809-5
1H-Imidazole, 5-methyl-4-nitro-
5-Methyl-4-nitro-1H-imidazole
MFCD00091864
1H-imidazole, 4-methyl-5-nitro-
4-Methyl-5-nitroimidazole

4-甲基-5-硝基咪唑物理化学性质

[ 密度 ]:
1.4±0.1 g/cm3

[ 沸点 ]:
380.2±22.0 °C at 760 mmHg

[ 熔点 ]:
249ºC(lit.)

[ 分子式 ]:
C₄H₅N₃O₂

[ 分子量 ]:
127.101

[ 闪点 ]:
183.8±22.3 °C

[ 精确质量 ]:
127.038177

[ PSA ]:
74.50000

[ LogP ]:
0.38

[ 蒸汽压 ]:
0.0±0.8 mmHg at 25°C

[ 折射率 ]:
1.592

4-甲基-5-硝基咪唑毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: NI7562000

CHEMICAL NAME :: Imidazole, 4-methyl-5-nitro-

CAS REGISTRY NUMBER :: 14003-66-8

LAST UPDATED :: 199701

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C4-H5-N3-O2

MOLECULAR WEIGHT :: 127.12

WISWESSER LINE NOTATION :: T5M CNJ D1 ENW

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :: Mutation in microorganisms

TEST SYSTEM :: Bacteria - Klebsiella pneumoniae

DOSE/DURATION :: 10 umol/L/20H

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 66,207,1979

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4-甲基-5-硝基咪唑安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi: Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26;S36

[ 危险品运输编码 ]:
NONH for all modes of transport

[ RTECS号 ]:
NI7562000

[ 海关编码 ]:
2933290090

4-甲基-5-硝基咪唑合成路线

详细合成路线

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4-甲基-5-硝基咪唑海关

[ 海关编码 ]: 2933290090

[ 中文概述 ]:
2933290090. 其他结构含非稠合咪唑环的化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期

[ Summary ]:
2933290090. other compounds containing an unfused imidazole ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

4-甲基-5-硝基咪唑文献

Localized cell stimulation by nitric oxide using a photoactive porous coordination polymer platform.

Nat. Commun. 4 , 2684, (2013)

Functional cellular substrates for localized cell stimulation by small molecules provide an opportunity to control and monitor cell signalling networks chemically in time and space. However, despite i...

1, 4-Dinitroimidazole and derivatives. Structure and thermal rearrangement. Grimmett MR, et al.

Aust. J. Chem. 42(8) , 1281-1289, (1989)

Reaction between heterocyclic NH-acids and dibenzoylacetylene in the presence of triphenylphosphine. Simple synthesis of 1-(3-furyl)-1H-imidazole derivatives. Yavari I, et al.

Tetrahedron Lett. 43(51) , 9449-9452, (2002)

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