二氯二氧化铬
二氯二氧化铬用途
1.有机合成中作氧化剂或氯化剂,及铬酸酐、铬络合物、染料的溶剂。
二氯二氧化铬名称
[ CAS 号 ]:
14977-61-8
[ 中文名 ]:
二氯氧化铬
[ 英文名 ]:
Chromyl chloride
[中文别名 ]:
[英文别名 ]:
- Chromyl chloride
- chromium chloride
- MFCD00010951
- CHROMOUS CHLORIDE
- chromium dichloride
- chromylchloride
- EINECS 239-056-8
- chromium oxychloride
二氯二氧化铬物理化学性质
[ 密度 ]:
1.91
[ 沸点 ]:
117ºC
[ 熔点 ]:
-96.5ºC
[ 分子式 ]:
Cl2CrO2
[ 分子量 ]:
154.90100
[ 闪点 ]:
117ºC
[ 精确质量 ]:
153.86800
[ PSA ]:
34.14000
[ LogP ]:
1.14140
[ 储存条件 ]:
库房通风低温干燥,与碱类、食品添加剂分开存放
二氯二氧化铬MSDS
二氯二氧化铬毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- GB5775000
- CHEMICAL NAME :
- Chromium, dichlorodioxo-
- CAS REGISTRY NUMBER :
- 14977-61-8
- LAST UPDATED :
- 199712
- DATA ITEMS CITED :
- 18
- MOLECULAR FORMULA :
- Cl2-Cr-O2
- MOLECULAR WEIGHT :
- 154.90
- WISWESSER LINE NOTATION :
- CR G2 O2
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
MUTATION DATA
- TYPE OF TEST :
- Mutation in microorganisms
- TEST SYSTEM :
- Bacteria - Salmonella typhimurium
- REFERENCE :
- CRNGDP Carcinogenesis (London). (Oxford Univ. Press, Pinkhill House, Southfield Road, Eynsham, Oxford OX8 1JJ, UK) V.1- 1980- Volume(issue)/page/year: 1,583,1980 *** REVIEWS *** ACGIH TLV-TWA 0.16 mg/m3 (0.025 ppm) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 IARC Cancer Review:Human Sufficient Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 49,49,1990 IARC Cancer Review:Group 1 IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 49,49,1990 *** U.S. STANDARDS AND REGULATIONS *** OSHA PEL (Gen Indu):8H TWA 0.5 mg(Cr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.5 mg(Cr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.5 mg(Cr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.5 mg(Cr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-BELGIUM:TWA 0.025 ppm (0.16 mg/m3) JAN 1993 OEL-FINLAND;Carcinogen JAN 1993 OEL-GERMANY;Carcinogen JAN 1993 OEL-THE NETHERLANDS:TWA 0.025 ppm (0.15 mg/m3) JAN 1993 OEL-SWITZERLAND:TWA 0.05 mg/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO CHROMYL CHLORIDE-air:10H CA TWA 0.001 mg(Cr)/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X4593 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 35 (estimated)
二氯二氧化铬安全信息
[ 符号 ]:
GHS03, GHS05, GHS07, GHS08, GHS09
[ 信号词 ]:
Danger
[ 危害声明 ]:
H271-H314-H317-H340-H350i-H410
[ 警示性声明 ]:
P201-P210-P273-P280-P303 + P361 + P353-P305 + P351 + P338
[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ 危害码 (欧洲) ]:
O:Oxidizing;T:Toxic;N:Dangerousfortheenvironment;
[ 风险声明 (欧洲) ]:
R35;R43;R46;R49;R50/53;R8
[ 安全声明 (欧洲) ]:
S45-S53-S60-S61
[ 危险品运输编码 ]:
UN 3244 8/PG 2
[ WGK德国 ]:
3
[ RTECS号 ]:
GB5775000
[ 包装等级 ]:
I
[ 危险类别 ]:
8
[ 海关编码 ]:
2914700090
二氯二氧化铬合成路线
二氯二氧化铬上下游产品
二氯二氧化铬上游产品
二氯二氧化铬下游产品
二氯二氧化铬制备
1.将150g三氧化铬溶于100mL水中,加入330mL浓盐酸,用冷冻剂冷却至0℃。在搅拌下滴入450mL浓硫酸。此时,溶液的温度应保持在10℃以下。反应结束后,将溶液注入分液漏斗中,分出下层部分的溶液并储存于密闭容器中,收率189g(81%)。
安装精馏装置并将上述溶液进行分馏,收集115~116℃(0.9796×105Pa)的馏分(为粗制品的65%)。保存时,应通入干燥空气以完全逐出氯化氢,然后进行蒸馏并封入安瓿中,置暗处储存。
因生成物侵蚀磨口的润滑脂,造成润滑脂固化使磨口处活动受阻,所以宜采用聚四氟乙烯一类的无润滑脂的磨口。二氯二氧化铬海关
[ 海关编码 ]: 2914700090
[ 中文概述 ]:
2914700090 其他酮及醌的卤化、磺化衍生物(包括硝化和亚硝化衍生物). 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:5.5% 普通关税:30.0%
[ 申报要素 ]: 品名, 成分含量, 用途, 丙酮报明包装
[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%
相关化工产品/化学物质:
推荐生产厂家/供应商:
公司名:上海化源世纪贸易有限公司
区域:上海市普陀区
价格:
联系人:徐经理
产品详情:铬酰氯
公司名:上海阿拉丁生化科技股份有限公司
区域:上海市浦东新区
价格:
¥470.0/5g
¥1910.0/25g
¥需询单/1g
¥需询单/1g
联系人:阿拉丁
产品详情:铬酰氯
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相关化合物
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