Mattson Boronate Urea Pinacol Ester

[ 熔点 ]:
230.39°C

[ 分子式 ]:
C₂₁H₂₁BF₆N₂O₃

[ 分子量 ]:
474.20

[ 储存条件 ]:
2-8°C

[ 危险品运输编码 ]:
NONH for all modes of transport

Urea-catalyzed N-H insertion-arylation reactions of nitrodiazoesters.

J. Org. Chem. 79(11) , 4832-42, (2014)

The power of hydrogen-bond donor catalysis has been harnessed to elicit and control carbene-like reactivity from nitrodiazoesters. Specifically, select ureas have been identified as effective catalyst...

Arylation of diazoesters by a transient N-H insertion organocascade.

Angew. Chem. Int. Ed. Engl. 52(43) , 11317-20, (2013)

It takes two: A unique organocatalyzed cascade for the unsymmetric double arylation of α-nitrodiazoesters is described. This organocascade features the strategic use of carbene-activating anilines in ...

Urea-catalyzed construction of oxazinanes.

Org. Biomol. Chem. 11(35) , 5793-7, (2013)

Highly functionalized oxazinanes are efficiently prepared through urea-catalyzed formal [3 + 3] cycloaddition reactions of nitrones and nitrocyclopropane carboxylates. The reaction system is general w...

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