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8-溴喹啉

8-溴喹啉用途

用作有机合成试剂。

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8-溴喹啉名称

[ CAS 号 ]:
16567-18-3

[ 中文名 ]:
8-溴喹啉

[ 英文名 ]:
8-Bromoquinoline

[中文别名 ]:

8-溴代喹啉

[英文别名 ]:

Quinoline, 8-bromo-
quinolin-8-yl bromide
MFCD00191859
8-Brom-chinolin
8-BROMQUINOLINE
Quinoline,8-bromo
8-Bromoquinoline

8-溴喹啉物理化学性质

[ 密度 ]:
1.6±0.1 g/cm3

[ 沸点 ]:
303.0±0.0 °C at 760 mmHg

[ 熔点 ]:
58-59 °C

[ 分子式 ]:
C₉H₆BrN

[ 分子量 ]:
208.055

[ 闪点 ]:
132.8±19.8 °C

[ 精确质量 ]:
206.968353

[ PSA ]:
12.89000

[ LogP ]:
2.51

[ 外观性状 ]:
白色至淡黄色晶体粉末

[ 蒸汽压 ]:
0.0±0.6 mmHg at 25°C

[ 折射率 ]:
1.674

[ 储存条件 ]:
Refrigerator (+4°C)

8-溴喹啉MSDS

8-溴喹啉安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xi:Irritant

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S36-S37/39

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ 海关编码 ]:
2933499090

8-溴喹啉合成路线

8-溴喹啉上下游产品

8-溴喹啉上游产品

8-溴喹啉下游产品

8-溴喹啉制备

由邻溴苯胺、对溴苯胺或间溴苯胺通过斯克劳普反应合成。

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8-溴喹啉海关

[ 海关编码 ]: 2933499090

[ 中文概述 ]:
2933499090. 其他含喹琳或异喹啉环系的化合物〔但未进一步稠合的〕. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期

[ Summary ]:
2933499090. other compounds containing in the structure a quinoline or isoquinoline ring-system (whether or not hydrogenated), not further fused. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

8-溴喹啉文献

Reactivity of the bifunctional ambiphilic molecule 8-(dimesitylboryl)quinoline: hydrolysis and coordination to Cu(I), Ag(I) and Pd(II).

Dalton Trans. 39(45) , 11081-90, (2010)

The ambiphilic molecule 8-(dimesitylboryl)quinoline (1) was synthesized by treatment of 8-bromoquinoline or 8-iodoquinoline with n-BuLi followed by dimesitylboronfluoride. Hydrolysis of 1 is unusually...

Direct synthesis of tricyclic 5H-pyrido[3,2,1-ij]quinolin-3-one by domino palladium catalyzed reaction.

Org. Biomol. Chem. 4(20) , 3760-2, (2006)

Unexpectedly, the palladium catalyzed coupling reaction of acrolein with 8-bromoquinoline gave 5H-pyrido[3,2,1-ij]quinolin-3-one in a single step.

Facile synthesis of 8-substituted quinolines. Suggs JW and Pearson GDN.

J. Org. Chem. 45(8) , 1514-15, (1980)

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