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1,1-二氯频哪酮

1,1-二氯频哪酮用途

【用途1】
用作医药、农药等的中间体
【用途2】
二氯频那酮是除草剂嗪草酮的中间体，过去也曾用以制备三唑酮类杀菌剂。

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1,1-二氯频哪酮名称

[ CAS 号 ]:
22591-21-5

[ 中文名 ]:
1,1-二氯-3,3-二甲基-2-丁酮

[ 英文名 ]:
1,1-Dichloro-3,3-dimethyl-2-butanone

[中文别名 ]:

[英文别名 ]:

2-Butanone, 1,1-dichloro-3,3-dimethyl-
dichloromethyl tert-butyl ketone
Dichloropinacolin
1,1-Dichlor-3,3-dimethyl-2-butanon
Dichloropinakolin
tert-Butyl Dichloromethyl Ketone
1,1-DICHLOROPINACOLONE
1,1-Dichloropinacoline
dichloropinacolone
1,1-Dichloro-3,3-dimethyl-2-butanone

1,1-二氯频哪酮物理化学性质

[ 密度 ]:
1.1±0.1 g/cm3

[ 沸点 ]:
173.8±20.0 °C at 760 mmHg

[ 熔点 ]:
50ºC

[ 分子式 ]:
C₆H₁₀Cl₂O

[ 分子量 ]:
169.049

[ 闪点 ]:
65.0±22.3 °C

[ 精确质量 ]:
168.010864

[ PSA ]:
17.07000

[ LogP ]:
2.59

[ 外观性状 ]:
白色-类白色晶体-粉末

[ 蒸汽压 ]:
1.2±0.3 mmHg at 25°C

[ 折射率 ]:
1.447

[ 储存条件 ]:
室温

1,1-二氯频哪酮MSDS

1,1-二氯频哪酮毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: EL7500000

CHEMICAL NAME :: 2-Butanone, 1,1-dichloro-3,3-dimethyl-

CAS REGISTRY NUMBER :: 22591-21-5

BEILSTEIN REFERENCE NO. :: 1752918

LAST UPDATED :: 199710

DATA ITEMS CITED :: 11

MOLECULAR FORMULA :: C6-H10-Cl2-O

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1300 mg/kg

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - dyspnea Gastrointestinal - other changes Blood - hemorrhage

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0571099

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 643 mg/m3/4H

TOXIC EFFECTS :: Sense Organs and Special Senses (Eye) - effect, not otherwise specified Lungs, Thorax, or Respiration - other changes

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0571099

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 5 gm/kg

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - dyspnea Gastrointestinal - other changes Blood - hemorrhage

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0571099

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 4150 mg/kg

TOXIC EFFECTS :: Behavioral - altered sleep time (including change in righting reflex) Behavioral - muscle weakness Behavioral - withdrawal

REFERENCE :: GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 52(12),92,1987

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 643 mg/m3/4H

TOXIC EFFECTS :: Sense Organs and Special Senses (Eye) - effect, not otherwise specified Lungs, Thorax, or Respiration - other changes

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0571099

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 3550 mg/kg

TOXIC EFFECTS :: Behavioral - altered sleep time (including change in righting reflex) Behavioral - muscle weakness Behavioral - withdrawal

REFERENCE :: GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 52(12),92,1987

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 1234 mg/m3/4H

TOXIC EFFECTS :: Sense Organs and Special Senses (Eye) - effect, not otherwise specified Lungs, Thorax, or Respiration - other changes

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0571099

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: 2 gm/kg

TOXIC EFFECTS :: Peripheral Nerve and Sensation - flaccid paralysis without anesthesia (usually neuromuscular blockage) Lungs, Thorax, or Respiration - dyspnea

REFERENCE :: BDKS** "Studien uber die Pharmakologie des Pinakolins und einiger seiner Derivate mit besonderer Berucksichtigung der Kreislaufwirkung, Dissertation," Bang, L., Pharmakologischen Abteilung des Karolinischen Instituts, Stockholm, Sweden, 1934 Volume(issue)/page/year: -,-,1934

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - hamster

DOSE/DURATION :: >1234 mg/m3/4H

TOXIC EFFECTS :: Sense Organs and Special Senses (Eye) - effect, not otherwise specified Lungs, Thorax, or Respiration - other changes

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0571099

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1,1-二氯频哪酮安全信息

[ 危害码 (欧洲) ]:
Xi

[ 危险品运输编码 ]:
2811

[ RTECS号 ]:
EL7500000

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1

[ 海关编码 ]:
2914700090

1,1-二氯频哪酮合成路线

1,1-二氯频哪酮上下游产品

1,1-二氯频哪酮上游产品

1,1-二氯频哪酮下游产品

1,1-二氯频哪酮制备

其制备方法是将频那酮加入搪瓷反应釜中，冷却下通入氯气至理论量，结束反应，制得二氯频那酮，

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1,1-二氯频哪酮海关

[ 海关编码 ]: 2914700090

[ 中文概述 ]:
2914700090 其他酮及醌的卤化、磺化衍生物（包括硝化和亚硝化衍生物）. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:5.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 丙酮报明包装

[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

1,1-二氯频哪酮

1,1-二氯频哪酮用途

1,1-二氯频哪酮名称

1,1-二氯频哪酮物理化学性质

1,1-二氯频哪酮MSDS

详细MSDS(安全技术说明书)

1,1-二氯频哪酮毒性和生态

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

1,1-二氯频哪酮安全信息

1,1-二氯频哪酮合成路线

详细合成路线

1,1-二氯频哪酮上下游产品

1,1-二氯频哪酮上游产品

1,1-二氯频哪酮下游产品

1,1-二氯频哪酮制备

1,1-二氯频哪酮海关

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