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苄基缩水甘油醚

苄基缩水甘油醚用途

用作环氧树脂的活性稀释剂,参考用量10%~20%。

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苄基缩水甘油醚名称

[ CAS 号 ]:
2930-05-4

[ 中文名 ]:
苄基缩水甘油醚

[ 英文名 ]:
2-((Benzyloxy)methyl)oxirane

[中文别名 ]:

[英文别名 ]:

苄基缩水甘油醚物理化学性质

[ 密度 ]:
1.1±0.1 g/cm3

[ 沸点 ]:
252.7±15.0 °C at 760 mmHg

[ 分子式 ]:
C10H12O2

[ 分子量 ]:
164.201

[ 闪点 ]:
100.9±19.9 °C

[ 精确质量 ]:
164.083725

[ PSA ]:
21.76000

[ LogP ]:
2.04

[ 外观性状 ]:
液体;Colorless to Light yellow clear liquid

[ 蒸汽压 ]:
0.0±0.5 mmHg at 25°C

[ 折射率 ]:
1.535

[ 储存条件 ]:
Refrigerator

苄基缩水甘油醚MSDS

苄基缩水甘油醚毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TX2860000
CHEMICAL NAME :
Propane, 1-(benzyloxy)-2,3-epoxy-
CAS REGISTRY NUMBER :
2930-05-4
BEILSTEIN REFERENCE NO. :
0115279
LAST UPDATED :
199612
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C10-H12-O2
MOLECULAR WEIGHT :
164.22

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :
Mutation in microorganisms
TEST SYSTEM :
Bacteria - Salmonella typhimurium
DOSE/DURATION :
6 mmol/L
REFERENCE :
CBINA8 Chemico-Biological Interactions. (Elsevier Scientific Pub. Ireland Ltd., POB 85, Limerick, Ireland) V.1- 1969- Volume(issue)/page/year: 45,153,1983
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苄基缩水甘油醚安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xi

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S37-S39

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ RTECS号 ]:
TX2860000

[ 海关编码 ]:
2910900090

苄基缩水甘油醚合成路线

苄基缩水甘油醚上下游产品

苄基缩水甘油醚制备

在装有搅拌器、回流冷凝管、温度计的三口瓶中加入18.4g苯酚、120mL环氧氯丙烷、33.6gKOH、6g苯甲醇,在40℃下剧烈搅拌3h。然后加50~100mL水,分出有机层,水层用乙醚萃取2次,倒入有机层,无水硫酸钠干燥后蒸出乙醚,再减压蒸馏即得产物。合成反应式如

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苄基缩水甘油醚海关

[ 海关编码 ]: 2910900090

[ 中文概述 ]:
2910900090. 三节环环氧化物,环氧醇(酚,醚),包括其卤化,磺化,硝化或亚硝化的衍生物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2910900090. epoxides, epoxyalcohols, epoxyphenols and epoxyethers, with a three-membered ring, and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

苄基缩水甘油醚文献

Synthesis of atactic and isotactic poly(1,2-glycerol carbonate)s: degradable polymers for biomedical and pharmaceutical applications.

J. Am. Chem. Soc. 135(18) , 6806-9, (2013)

The synthesis and characterization of atactic and isotactic linear poly(benzyl 1,2-glycerol carbonate)s are reported. The poly(benzyl 1,2-glycerol carbonate)s were obtained via the ring-opening copoly...

Biocatalytic resolution of benzyl glycidyl ether and its derivates by Talaromyces flavus: effect of phenyl ring substituents on enantioselectivity.

Biotechnol. Lett. 34(8) , 1499-503, (2012)

Talaromyces flavus containing a constitutive epoxide hydrolase (EH) resolved racemic benzyl glycidyl ether and nine derivatives into their (R)-enantiomers. After optimization of the fermentation condi...

Bioresolution of benzyl glycidyl ether using whole cells of Bacillus alcalophilus.

J. Basic Microbiol. 52(4) , 383-9, (2012)

The incubation of whole Bacillus alcalophilus cells grown on a mineral supplemented medium (MSM) containing 1% (w/v) sucrose as carbon source, 1.2% (w/v) tryptone as nitrogen source at pH 6.5 and temp...


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