2,3-二甲氧基-1,3-丁二烯

2,3-二甲氧基-1,3-丁二烯名称

[ CAS 号 ]:
3588-31-6

[ 中文名 ]:
2,3-二甲氧基-1,3-丁二烯

[ 英文名 ]:
2,3-Dimethoxy-1,3-butadiene

[英文别名 ]:

2,3-Dimethoxy-1,3-butadiene
2,3-Dimethoxy-1,3-diene
MFCD00010229
2,3-Dimethoxybuta-1,3-Diene
1,3-Butadiene, 2,3-dimethoxy-
2,3-dimethoxybutadiene
2,3-Dimethoxybutadien

2,3-二甲氧基-1,3-丁二烯物理化学性质

[ 密度 ]:
0.9±0.1 g/cm3

[ 沸点 ]:
151.0±23.0 °C at 760 mmHg

[ 熔点 ]:
19ºC

[ 分子式 ]:
C₆H₁₀O₂

[ 分子量 ]:
114.142

[ 闪点 ]:
32.8±0.0 °C

[ 精确质量 ]:
114.068077

[ PSA ]:
18.46000

[ LogP ]:
1.05

[ 蒸汽压 ]:
4.8±0.3 mmHg at 25°C

[ 折射率 ]:
1.413

[ 储存条件 ]:
2-8°C，密封，干燥

2,3-二甲氧基-1,3-丁二烯MSDS

2,3-二甲氧基-1,3-丁二烯安全信息

[ 符号 ]:

GHS02

[ 信号词 ]:
Warning

[ 危害声明 ]:
H226

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 风险声明 (欧洲) ]:
R10

[ 安全声明 (欧洲) ]:
S16-S33

[ 危险品运输编码 ]:
UN 1993

[ 包装等级 ]:
III

[ 危险类别 ]:
3.2

[ 海关编码 ]:
2909199090

2,3-二甲氧基-1,3-丁二烯合成路线

2,3-二甲氧基-1,3-丁二烯上下游产品

2,3-二甲氧基-1,3-丁二烯上游产品

2,3-二甲氧基-1,3-丁二烯下游产品

2,3-二甲氧基-1,3-丁二烯海关

[ 海关编码 ]: 2909199090

[ 中文概述 ]:
2909199090. 其他无环醚及其卤化衍生物（包括磺化，硝化或亚硝化衍生物）. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2909199090. other acyclic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

2,3-二甲氧基-1,3-丁二烯文献

Diels-Alder chemistry of graphite and graphene: graphene as diene and dienophile.

J. Am. Chem. Soc. 133(10) , 3324-7, (2011)

The zero-band-gap electronic structure of graphene enables it to function as either the diene or the dienophile in the Diels-Alder reaction, and this versatile synthetic method offers a powerful strat...

3-nitrocoumarins as dienophiles in the Diels-Alder reaction in water. An approach to the synthesis of nitrotetrahydrobenzo[c]chromenones and dihydrodibenzo[b,d]furans.

J. Org. Chem. 68(24) , 9263-8, (2003)

The [4 + 2] cycloadditions of 3-nitrocoumarin (1a), 6-chloro-3-nitrocoumarin (1b), and 6-, 7-, and 8-hydroxy-3-nitrocoumarins (1c, 5, and 6) with (E)-piperylene (7), isoprene (8), 2,3-dimethyl-1,3-but...

Organic chemistry of graphene: the Diels-Alder reaction.

Chemistry 19(46) , 15719-25, (2013)

Herein, by using dispersion-corrected density functional theory, we investigated the Diels-Alder chemistry of pristine and defective graphene. Three dienes were considered, namely 2,3-dimethoxy-1,3-bu...

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