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叔丁基对苯醌

叔丁基对苯醌用途

2-叔丁基-1,4-苯醌是丁基化羟基茴香醚的亲电代谢产物,也是2-叔丁基氢醌的氧化产物[1]。

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叔丁基对苯醌名称

[ CAS 号 ]:
3602-55-9

[ 中文名 ]:
叔丁基对苯醌

[ 英文名 ]:
2-tert-Butyl-1,4-benzoquinone

[中文别名 ]:

[英文别名 ]:

EINECS 222-757-8
2-tert-butylcyclohexa-2,5-diene-1,4-dione
MFCD00666928

叔丁基对苯醌生物活性

[ 描述 ]:

2-叔丁基-1,4-苯醌是丁基化羟基茴香醚的亲电代谢产物,也是2-叔丁基氢醌的氧化产物[1]。

[ 相关类别 ]:

信号通路 >> 细胞凋亡 >> 细胞凋亡

研究领域 >> 癌症

叔丁基对苯醌物理化学性质

[ 密度 ]:
1.092 g/cm3

[ 沸点 ]:
227.8ºC at 760 mmHg

[ 熔点 ]:
54-58 °C(lit.)

[ 分子式 ]:
C₁₀H₁₂O₂

[ 分子量 ]:
164.20100

[ 闪点 ]:
82.6ºC

[ 精确质量 ]:
164.08400

[ PSA ]:
34.14000

[ LogP ]:
1.66690

[ 外观性状 ]:
固体;Light yellow to Brown powder to crystal

[ 折射率 ]:
1.515

[ 储存条件 ]:
室温

叔丁基对苯醌MSDS

叔丁基对苯醌毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: DK3790000

CHEMICAL NAME :: p-Benzoquinone, 2-tert-butyl-

CAS REGISTRY NUMBER :: 3602-55-9

BEILSTEIN REFERENCE NO. :: 1860944

LAST UPDATED :: 199612

DATA ITEMS CITED :: 6

MOLECULAR FORMULA :: C10-H12-O2

MOLECULAR WEIGHT :: 164.22

WISWESSER LINE NOTATION :: L6V DVJ BX1&1&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :: Cytogenetic analysis

TEST SYSTEM :: Rodent - hamster Lung

DOSE/DURATION :: 1500 ug/L

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 241,125,1990

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叔丁基对苯醌安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi: Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S36

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ RTECS号 ]:
DK3790000

[ 海关编码 ]:
2914690090

叔丁基对苯醌合成路线

叔丁基对苯醌上下游产品

叔丁基对苯醌上游产品

叔丁基对苯醌下游产品

叔丁基对苯醌海关

[ 海关编码 ]: 2914690090

[ 中文概述 ]:
2914690090 其他醌. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:5.5% 普通关税:30.0%

[ Summary ]:
2914690090 other quinones。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

叔丁基对苯醌文献

Reduction of cytotoxic p-quinone metabolites of tert-butylhydroquinone by human aldo-keto reductase (AKR) 1B10.

Drug Metab. Pharmacokinet. 27(5) , 553-8, (2012)

2-tert-Butylhydroquinone (BHQ), an antioxidant used as a food additive, exhibits an anticancer effect, whereas it is carcinogenic in rodents at high doses. BHQ is metabolized into cytotoxic tert-butyl...

Paradoxical cytotoxicity of tert-butylhydroquinone in vitro: What kills the untreated cells?

Arch. Toxicol. 86(9) , 1481-7, (2012)

At high concentrations, tert-butylhydroquinone (tBHQ), a phenolic antioxidant frequently used as a food preservative, exerts cytotoxic effects, which are closely linked to its ability to form reactive...

Irreversible inhibition of rat hepatic glutathione S-transferase isoenzymes by a series of structurally related quinones.

Chem. Biol. Interact. 71(4) , 381-92, (1989)

The effect of several structurally related 1,4-benzoquinones (BQ) and 1,4-naphthoquinones (NQ) on the activity of rat hepatic glutathione S-transferases (GST) was studied. For the 1,4-benzoquinones, t...

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