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二氯丙烯胺

二氯丙烯胺用途

Dichlormid 是除草剂安全剂。Dichlormid 上调 ZmGST27 和 ZmMRP1 的表达并增加 ZmGT1。

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二氯丙烯胺名称

[ CAS 号 ]:
37764-25-3

[ 中文名 ]:
烯丙酰草胺

[ 英文名 ]:
Dichlormid

[中文别名 ]:

[英文别名 ]:

ACETAMIDE, 2,2-DICHLORO-N,N-DI-2-PROPENYL-
Acetamide, N,N-diallyl-2,2-dichloro-
2,2-dichloro-N,N-di-2-propen-1-ylacetamide
N,N-Diallyldichloroacetamide
MFCD00072464
N,N-diallyl-dichloroacetamide
N,N-Diallyldichloroacetamide,Dichloromid
Dichloromid
dichlorimid
Acetamide,2,2-dichloro-N,N-di-2-propenyl

二氯丙烯胺生物活性

[ 描述 ]:

Dichlormid 是除草剂安全剂。Dichlormid 上调 ZmGST27 和 ZmMRP1 的表达并增加 ZmGT1。

[ 相关类别 ]:

研究领域 >> 其他

信号通路 >> 其他 >> 其他

[参考文献]

[1]. D P Dixon, et al. Purification, Regulation and Cloning of a Glutathione Transferase (GST) From Maize Resembling the Auxin-Inducible type-III GSTs. Plant Mol Biol. 1998 Jan;36(1):75-87.

[2]. Sen Pang, et al. Co-induction of a glutathione-S-transferase, a Glutathione Transporter and an ABC Transporter in Maize by Xenobiotics. PLoS One. 2012;7(7):e40712.

二氯丙烯胺物理化学性质

[ 密度 ]:
1.2±0.1 g/cm3

[ 沸点 ]:
253.8±40.0 °C at 760 mmHg

[ 熔点 ]:
5.0-6.5°C

[ 分子式 ]:
C₈H₁₁Cl₂NO

[ 分子量 ]:
208.085

[ 闪点 ]:
107.3±27.3 °C

[ 精确质量 ]:
207.021774

[ PSA ]:
20.31000

[ LogP ]:
1.98

[ 外观性状 ]:
黄色透明液体

[ 蒸汽压 ]:
0.0±0.5 mmHg at 25°C

[ 折射率 ]:
1.495

[ 储存条件 ]:
0-6°C

二氯丙烯胺MSDS

详细MSDS(安全技术说明书)

二氯丙烯胺毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: AB6080000

CHEMICAL NAME :: Acetamide, N,N-diallyl-2,2-dichloro-

CAS REGISTRY NUMBER :: 37764-25-3

BEILSTEIN REFERENCE NO. :: 1768843

LAST UPDATED :: 199710

DATA ITEMS CITED :: 6

MOLECULAR FORMULA :: C8-H11-Cl2-N-O

MOLECULAR WEIGHT :: 208.10

WISWESSER LINE NOTATION :: GYGVN2U1&2U1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 2 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85ARAE "Agricultural Chemicals," Thomson, W.T., 4 vols., Fresno, CA, Thomson Publications, 1976/77 revision Volume(issue)/page/year: 3,109,1976/1977

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 5500 mg/m3/1H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,251,1991

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >5 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,251,1991

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二氯丙烯胺安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302-H332

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xi: Irritant;N: Dangerous for the environment;

[ 风险声明 (欧洲) ]:
R43;R50/53

[ 安全声明 (欧洲) ]:
S45

[ 危险品运输编码 ]:
NONH for all modes of transport

[ RTECS号 ]:
AB6080000

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二氯丙烯胺文献

Fatty acid elongation is important in the activity of thiocarbamate herbicides and in safening by dichlormid.

J. Exp. Bot. 54(385) , 1289-94, (2003)

The thiocarbamates, such as pebulate (S-propyl butyl (ethyl) thiocarbamate) are a well-established class of herbicides. They inhibit fatty acid elongation, which is necessary for the biosynthesis of c...

The inhibition of fatty acid elongation by pebulate can be effectively counteracted by the safener dichlormid.

Biochem. Soc. Trans. 28(6) , 650-1, (2000)

The thiocarbamate herbicide pebulate inhibits fatty acid elongation, which is necessary for surface lipid biosynthesis. As both barley and wild oats are susceptible to pebulate, the safener dichlormid...

Induction of glutathione S-transferases in Arabidopsis by herbicide safeners.

Plant Physiol. 130(3) , 1497-505, (2002)

Herbicide safeners increase herbicide tolerance in cereals but not in dicotyledenous crops. The reason(s) for this difference in safening is unknown. However, safener-induced protection in cereals is ...

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