二烯丙基胺
二烯丙基胺用途
用作有机合成原料、离子净水剂、聚合物单体、制药中间体等
【用途二】
有机中间体。
【用途三】
二烯丙基胺{124-02-7}应用于制做交联型无醛固色剂（二烯丙基胺与二甲基二烯丙基氯化铵共聚）、交联剂、制药中间体、以及农用化学品、染料和涂料、有机合成和树脂改良剂等的中间体。还可以用于制备两性高分子聚合物等。国内生产厂家较少，只有山东的铭兴化工和鲁岳在批量生产，国外生产的有德国洋樱集团生产的和美国利田化学的。
二烯丙基胺名称
[ CAS 号 ]:
124-02-7
[ 中文名 ]:
二烯丙基胺
[ 英文名 ]:
Diallylamine
[中文别名 ]:
[英文别名 ]:
- DAA
- N-Allylprop-2-en-1-amine
- EINECS 204-671-2
- diallyl-amin
- Amine, diallyl-
- N,N-diallylamine
- N-Allyl-2-propen-1-amine
- (CH2=CHCH2)2NH
- diallyamine
- bis(prop-2-en-1-yl)amine
二烯丙基胺物理化学性质
[ 密度 ]:
0.8±0.1 g/cm3
[ 沸点 ]:
115.3±9.0 °C at 760 mmHg
[ 熔点 ]:
-88 °C
[ 分子式 ]:
C6H11N
[ 分子量 ]:
97.158
[ 闪点 ]:
15.6±0.0 °C
[ 精确质量 ]:
97.089149
[ PSA ]:
12.03000
[ LogP ]:
1.11
[ 外观性状 ]:
透明至淡黄色液体
[ 蒸汽密度 ]:
3.35 (vs air)
[ 蒸汽压 ]:
19.2±0.2 mmHg at 25°C
[ 折射率 ]:
1.433
[ 储存条件 ]:
库房通风低温干燥,与氧化剂、酸类分开存放
[ 水溶解性 ]:
8.6 g/100mL
二烯丙基胺MSDS
二烯丙基胺毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- UC6650000
- CHEMICAL NAME :
- 2-Propen-1-amine, N-2-propenyl-
- CAS REGISTRY NUMBER :
- 124-02-7
- BEILSTEIN REFERENCE NO. :
- 0773718
- LAST UPDATED :
- 199710
- DATA ITEMS CITED :
- 16
- MOLECULAR FORMULA :
- C6-H11-N
- MOLECULAR WEIGHT :
- 97.18
- WISWESSER LINE NOTATION :
- 1U2M2U1
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- Open irritation test
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- REFERENCE :
- AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 23,95,1962
- TYPE OF TEST :
- Rinsed with water
- ROUTE OF EXPOSURE :
- Administration into the eye
- SPECIES OBSERVED :
- Rodent - rabbit
- REFERENCE :
- AEHLAU Archives of Environmental Health. (Heldref Pub., 4000 Albemarle St., NW, Washington, DC 20016) V.1- 1960- Volume(issue)/page/year: 1,343,1960 ** ACUTE TOXICITY DATA **
- TYPE OF TEST :
- TCLo - Lowest published toxic concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Human - man
- DOSE/DURATION :
- 5 ppm/5M
- TOXIC EFFECTS :
- Sense Organs and Special Senses (Eye) - lacrimation Lungs, Thorax, or Respiration - structural or functional change in trachea or bronchi
- REFERENCE :
- AEHLAU Archives of Environmental Health. (Heldref Pub., 4000 Albemarle St., NW, Washington, DC 20016) V.1- 1960- Volume(issue)/page/year: 1,343,1960
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 578 mg/kg
- TOXIC EFFECTS :
- Behavioral - tremor Lungs, Thorax, or Respiration - dyspnea Gastrointestinal - other changes
- REFERENCE :
- AEHLAU Archives of Environmental Health. (Heldref Pub., 4000 Albemarle St., NW, Washington, DC 20016) V.1- 1960- Volume(issue)/page/year: 1,343,1960
- TYPE OF TEST :
- LC50 - Lethal concentration, 50 percent kill
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 795 ppm/8H
- TOXIC EFFECTS :
- Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Sense Organs and Special Senses (Eye) - lacrimation Lungs, Thorax, or Respiration - dyspnea
- REFERENCE :
- AEHLAU Archives of Environmental Health. (Heldref Pub., 4000 Albemarle St., NW, Washington, DC 20016) V.1- 1960- Volume(issue)/page/year: 1,343,1960
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 355 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- 85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,43,1982
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 187 mg/kg
- TOXIC EFFECTS :
- Behavioral - tremor Lungs, Thorax, or Respiration - respiratory depression Gastrointestinal - other changes
- REFERENCE :
- AEHLAU Archives of Environmental Health. (Heldref Pub., 4000 Albemarle St., NW, Washington, DC 20016) V.1- 1960- Volume(issue)/page/year: 1,343,1960
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- 280 uL/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 23,95,1962
- TYPE OF TEST :
- LC50 - Lethal concentration, 50 percent kill
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Mammal - species unspecified
- DOSE/DURATION :
- 2100 mg/m3
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. (Izdatel'stvo Meditsina, Moscow, USSR) No.1- 1961- Volume(issue)/page/year: 14,80,1975
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Unreported
- SPECIES OBSERVED :
- Mammal - species unspecified
- DOSE/DURATION :
- 350 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. (Izdatel'stvo Meditsina, Moscow, USSR) No.1- 1961- Volume(issue)/page/year: 14,80,1975 ** OTHER MULTIPLE DOSE TOXICITY DATA **
- TYPE OF TEST :
- TCLo - Lowest published toxic concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 200 ppm/7H/50D-I
- TOXIC EFFECTS :
- Cardiac - changes in heart weight Liver - changes in liver weight Kidney, Ureter, Bladder - changes in bladder weight
- REFERENCE :
- AEHLAU Archives of Environmental Health. (Heldref Pub., 4000 Albemarle St., NW, Washington, DC 20016) V.1- 1960- Volume(issue)/page/year: 1,343,1960 *** REVIEWS *** TOXICOLOGY REVIEW TXCYAC Toxicology. (Elsevier Scientific Pub. Ireland, Ltd., POB 85, Limerick, Ireland) V.1- 1973- Volume(issue)/page/year: 44,129,1987 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 1 mg/m3;Skin JAN 1993
二烯丙基胺安全信息
[ 危害码 (欧洲) ]:
F:Flammable
[ 风险声明 (欧洲) ]:
R11;R20/22;R24;R34
[ 安全声明 (欧洲) ]:
S16-S26-S36/37/39-S45-S28A
[ 危险品运输编码 ]:
UN 2359 3/PG 2
[ WGK德国 ]:
3
[ RTECS号 ]:
UC6650000
[ 包装等级 ]:
II
[ 危险类别 ]:
3
[ 海关编码 ]:
2921300090
二烯丙基胺合成路线
二烯丙基胺上下游产品
二烯丙基胺上游产品
二烯丙基胺下游产品
二烯丙基胺制备
生产方法简述：由二烯丙基氰胺水解而得。水解反应在硫酸介质中进行，缓和回流6h。产率80-88%。
二烯丙基胺海关
[ 海关编码 ]: 2921199090
[ 中文概述 ]:
2921199090 其他无环单胺及其衍生物及其盐。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0%
[ 申报要素 ]: 品名, 成分含量, 用途
[ Summary ]:
2921199090 other acyclic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%
相关化工产品/化学物质：
推荐生产厂家/供应商：
公司名：上海吉至生化科技有限公司
区域：上海市奉贤区
价格：
￥78.0/100ml
￥228.0/500ml
联系人：刘佳
产品详情：二烯丙基胺
公司名：上海阿拉丁生化科技股份有限公司
区域：上海市浦东新区
价格：
￥需询单/1mg
￥需询单/1mg
￥需询单/1mg
￥需询单/1mg
联系人：阿拉丁李高志
产品详情：二烯丙基胺
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相关化合物
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