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R(+)-alpha-甲基苄胺

R(+)-alpha-甲基苄胺用途

【用途一】
手性胺，用于测定酸的异构体纯度。

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R(+)-alpha-甲基苄胺名称

[ CAS 号 ]:
3886-69-9

[ 中文名 ]:
R(+)-alpha-甲基苄胺

[ 英文名 ]:
(R)-(+)-1-Phenylethylamine

[中文别名 ]:

[英文别名 ]:

α-methyl benzylamine
R(+)-Alpha-methylbenzylamine
N-Ethyl-N-phenylamine
L-Phenethylamine
α-Phenylethylamine
(1R)-1-Phenylethylamine
α-Methylbenzylamine
Benzene, (1-amino-ethyl)-
N-Ethylaniline
rac-1-phenylethylamine

R(+)-alpha-甲基苄胺物理化学性质

[ 密度 ]:
0.95

[ 沸点 ]:
184-186 ºC

[ 熔点 ]:
-10 °C

[ 分子式 ]:
C₈H₁₁N

[ 分子量 ]:
121.180

[ 闪点 ]:
75 ºC

[ 精确质量 ]:
121.089149

[ PSA ]:
26.02000

[ LogP ]:
1.44

[ 外观性状 ]:
无色至淡黄色液体

[ 蒸汽压 ]:
0.8±0.3 mmHg at 25°C

[ 折射率 ]:
1.533

[ 储存条件 ]:
存放于惰性气体之中;避免空气,湿气 (吸湿)

[ 水溶解性 ]:
40 g/L (20 ºC)

R(+)-alpha-甲基苄胺MSDS

R(+)-alpha-甲基苄胺安全信息

[ 符号 ]:

GHS05, GHS07

[ 信号词 ]:
Danger

[ 危害声明 ]:
H302 + H312-H314

[ 警示性声明 ]:
P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
C:Corrosive

[ 风险声明 (欧洲) ]:
R21/22;R34

[ 安全声明 (欧洲) ]:
S26-S28-S36/37/39-S45-S28A

[ 危险品运输编码 ]:
UN 2735 8/PG 2

[ WGK德国 ]:
3

[ 包装等级 ]:
III

[ 危险类别 ]:
8

[ 海关编码 ]:
29214980

R(+)-alpha-甲基苄胺合成路线

R(+)-alpha-甲基苄胺上下游产品

R(+)-alpha-甲基苄胺上游产品

R(+)-alpha-甲基苄胺下游产品

R(+)-alpha-甲基苄胺海关

[ 海关编码 ]: 2921499090

[ 中文概述 ]:
2921499090 其他芳香单胺及衍生物及它们的盐. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2921499090 other aromatic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

R(+)-alpha-甲基苄胺文献

Interactions of an asymmetric amine with a non-C2 symmetric Cu-salen complex: an EPR/ENDOR and HYSCORE investigation.

Phys. Chem. Chem. Phys. 13(45) , 20427-34, (2011)

Single enantiomers of R-/S-methylbenzylamine (MBA) were found to selectively form adducts with the chiral non-C(2) symmetric Cu-salen complex N-(3,5-di-tert-butylsalicylidene)-N'-(salicylidene)-cycloh...

Synthesis, Crystal Structure, Absolute Configuration and Antitumor Activity of the Enantiomers of 5-Bromo-2-chloro-N-(1-phenylethyl)pyridine-3-sulfonamide.

Molecules 20 , 20926-38, (2015)

Pyridinesulfonamide is an important fragment which has a wide range of applications in novel drugs. R- and S-isomers of 5-bromo-2-chloro-N-(1-phenylethyl)pyridine-3-sulfonamide have been synthesized, ...

Towards the chiral metabolomics: Liquid chromatography-mass spectrometry based DL-amino acid analysis after labeling with a new chiral reagent, (S)-2,5-dioxopyrrolidin-1-yl-1-(4,6-dimethoxy-1,3,5-triazin-2-yl)pyrrolidine-2-carboxylate, and the application to saliva of healthy volunteers.

Anal. Chim. Acta 875 , 73-82, (2015)

A novel triazine-type chiral derivatization reagent, i.e., (S)-2,5-dioxopyrrolidin-1-yl-1-(4,6-dimethoxy-1,3,5-triazin-2-yl) pyrrolidine-2-carboxylate (DMT-(S)-Pro-OSu), was developed for the highly s...

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