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甲基硝基胍

甲基硝基胍用途

【用途一】
用作农药、医药中间体

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甲基硝基胍名称

[ CAS 号 ]:
4245-76-5

[ 中文名 ]:
1-甲基-3-硝基胍

[ 英文名 ]:
1-Methyl-2-nitroguanidine

[中文别名 ]:

[英文别名 ]:

WNMYZUN1
WNMYUM&M1
1-Methyl-2-nitroguanidine
1-Methyl-3-nitroguanidine
Guanidine, N-methyl-N'-nitro-
N-Methyl-N'-nitroguanidine
2-methyl-1-nitroguanidine
MFCD00024167
N-Methyl-N"-nitroguanidine

甲基硝基胍物理化学性质

[ 密度 ]:
1.6±0.1 g/cm3

[ 沸点 ]:
177.3±23.0 °C at 760 mmHg

[ 熔点 ]:
153-155 °C(lit.)

[ 分子式 ]:
C₂H₆N₄O₂

[ 分子量 ]:
118.095

[ 闪点 ]:
61.0±22.6 °C

[ 精确质量 ]:
118.049072

[ PSA ]:
93.73000

[ LogP ]:
-0.98

[ 外观性状 ]:
白色结晶粉末

[ 蒸汽压 ]:
1.0±0.3 mmHg at 25°C

[ 折射率 ]:
1.588

[ 储存条件 ]:
室温

甲基硝基胍MSDS

详细MSDS(安全技术说明书)

甲基硝基胍毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: MF4125000

CHEMICAL NAME :: Guanidine, 1-methyl-3-nitro-

CAS REGISTRY NUMBER :: 4245-76-5

LAST UPDATED :: 199412

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: C2-H6-N4-O2

MOLECULAR WEIGHT :: 118.12

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD - Lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >1 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :: Cytogenetic analysis

TEST SYSTEM :: Rodent - hamster Lung

DOSE/DURATION :: 3300 mg/L

REFERENCE :: GMCRDC Gann Monograph on Cancer Research. (Plenum Pub. Corp., 233 Spring St., New York, NY 10013) No. 11- 1971- Volume(issue)/page/year: 27,95,1981

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甲基硝基胍安全信息

[ 符号 ]:

GHS02, GHS07

[ 信号词 ]:
Danger

[ 危害声明 ]:
H228-H302-H312-H315-H319-H332-H335

[ 警示性声明 ]:
P210-P261-P280-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
F: Flammable;Xn: Harmful;

[ 风险声明 (欧洲) ]:
R11;R20/21/22;R36/37/38

[ 安全声明 (欧洲) ]:
S16-S26-S36/37/39-S48

[ 危险品运输编码 ]:
UN 1325 4.1/PG 2

[ WGK德国 ]:
3

[ RTECS号 ]:
MF4200000

[ 包装等级 ]:
III

[ 危险类别 ]:
4.1

[ 海关编码 ]:
2925290090

甲基硝基胍合成路线

详细合成路线

甲基硝基胍上下游产品

甲基硝基胍上游产品

甲基硝基胍下游产品

甲基硝基胍海关

[ 海关编码 ]: 2925290090

[ 中文概述 ]:
2925290090 其他亚胺及其衍生物，以及它们的盐。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2925290090 other imines and their derivatives; salts thereof。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

甲基硝基胍文献

Development of immunoassay based on monoclonal antibody reacted with the neonicotinoid insecticides clothianidin and dinotefuran.

Sensors (Basel.) 12(11) , 15858-72, (2012)

Enzyme-linked immunosorbent assay (ELISA) based on a monoclonal antibody (MoAb) was developed for the neonicotinoid insecticide clothianidin. A new clothianidin hapten (3-[5-(3-methyl-2-nitroguanidino...

Multiple-endpoint mutagenesis with Chinese hamster ovary (CHO) cells: evaluation with eight carcinogenic and non-carcinogenic compounds.

Mol. Toxicol. 1(2-3) , 217-34, (1987)

Previously, we have shown that Chinese hamster ovary (CHO) cells are useful for quantifying chemical-induced gene mutations. We have defined the conditions of a Multiplex CHO System which permits dete...

Hydroxyl free radical production by the reaction of N-methyl-N'-nitro-N-nitrosoguanidine with hydrogen peroxide without exposure to light.

Biochem. Cell Biol. 70(3-4) , 262-8, (1992)

We examined hydroxyl free radical (.OH) production in the mixture of H2O2 and N-methyl-N'-nitro-N-nitrosoguanidine (MNNG) without exposure to light using the electron spin resonance spin-trapping tech...

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