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乙烯硼酐吡啶络合物

乙烯硼酐吡啶络合物名称

[ CAS 号 ]:
442850-89-7

[ 中文名 ]:
2,4,6-三乙烯基环三硼烷吡啶复合物

[ 英文名 ]:
Vinylboronic anhydride pyridine complex

[中文别名 ]:

乙烯硼酐吡啶络合物

[英文别名 ]:

MFCD03839940

乙烯硼酐吡啶络合物物理化学性质

[ 沸点 ]:
78-80 ℃

[ 熔点 ]:
49 - 53 ℃

[ 分子式 ]:
C₁₁H₁₄B₃NO₃

[ 分子量 ]:
240.66700

[ 闪点 ]:
80 ℃ - 闭杯

[ 精确质量 ]:
241.12500

[ PSA ]:
40.58000

[ LogP ]:
1.77160

[ 外观性状 ]:
白色至深黄色结晶或粉末

[ 储存条件 ]:
-20 °C

乙烯硼酐吡啶络合物MSDS

详细MSDS(安全技术说明书)

乙烯硼酐吡啶络合物安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H319

[ 警示性声明 ]:
P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi

[ 风险声明 (欧洲) ]:
R36

[ 安全声明 (欧洲) ]:
S26

[ 危险品运输编码 ]:
NONH for all modes of transport

乙烯硼酐吡啶络合物文献

Transition metal-catalyzed synthesis and reactivity of N-alkenyl aziridines.

Org. Lett. 6th ed., 7 , 1161-1164, (2005)

[reaction: see text] Straightforward methods for palladium-catalyzed alkenylation of aziridines with alkenyl halides and copper-catalyzed alkenylation of aziridines with alkenyl boronic acids have bee...

Stereoselective isomerisation of N-allyl aziridines into geometrically stable Z enamines by using rhodium hydride catalysis.

Chemistry 3rd ed., 14 , 886-894, (2008)

In the presence of rhodium(I) hydride catalysts, tertiary N-allylamines are known to isomerise into E enamines. In contrast, we have recently found that N-allylaziridines isomerise to form Z enamines....

The alkyl-connected 2-amino-6-vinylpurine (AVP) crosslinking agent for improved selectivity to the cytosine base in RNA

Bioorg. Med. Chem. 8th ed., 18 , 2894-2901, (2010)

The ethylene-connected 2-amino-6-vinylpurine (AVP) crosslinking agent exhibited improved reactivity and selectivity to the cytosine base in RNA.

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