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异丁硫醇

异丁硫醇用途

石油分析用试剂及用于有机合成。

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异丁硫醇名称

[ CAS 号 ]:
513-44-0

[ 中文名 ]:
异丁硫醇

[ 英文名 ]:
Isobutanethiol

[中文别名 ]:

2-甲基-1-丙硫醇

[英文别名 ]:

2-Methyl-1-propanethiol
Isobutyl Mercaptan
Isobutylmercaptan
2-Methylpropane-1-thiol
1-ISOBUTANETHIOL
Isobutanethiol
1-Propanethiol, 2-methyl-
2-methylpropanethiol
MFCD00004882
Isobutyl thiol

异丁硫醇物理化学性质

[ 密度 ]:
0.8±0.1 g/cm3

[ 沸点 ]:
86.6±8.0 °C at 760 mmHg

[ 熔点 ]:
-145°C

[ 分子式 ]:
C₄H₁₀S

[ 分子量 ]:
90.187

[ 闪点 ]:
-9.4±0.0 °C

[ 精确质量 ]:
90.050323

[ PSA ]:
38.80000

[ LogP ]:
2.13

[ 外观性状 ]:
无色液体带有煮熟的蔬菜的,像芥末的气味

[ 蒸汽密度 ]:
3.1 (vs air)

[ 蒸汽压 ]:
74.1±0.2 mmHg at 25°C

[ 折射率 ]:
1.435

[ 储存条件 ]:
库房通风低温干燥,与氧化剂,酸类分开储运存放

[ 水溶解性 ]:
水溶性：微溶；可溶于：醇,乙醚

异丁硫醇MSDS

异丁硫醇毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TZ7630000

CHEMICAL NAME :: 1-Propanethiol, 2-methyl-

CAS REGISTRY NUMBER :: 513-44-0

BEILSTEIN REFERENCE NO. :: 1730890

LAST UPDATED :: 199709

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: C4-H10-S

MOLECULAR WEIGHT :: 90.20

WISWESSER LINE NOTATION :: SH1Y1&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 19,171,1958 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 7168 mg/kg

TOXIC EFFECTS :: Behavioral - muscle weakness Behavioral - ataxia Lungs, Thorax, or Respiration - cyanosis

REFERENCE :: AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 19,171,1958

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 917 mg/kg

TOXIC EFFECTS :: Peripheral Nerve and Sensation - spastic paralysis with or without sensory change Behavioral - excitement Lungs, Thorax, or Respiration - cyanosis

REFERENCE :: AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 19,171,1958

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异丁硫醇安全信息

[ 符号 ]:

GHS02, GHS07

[ 信号词 ]:
Danger

[ 危害声明 ]:
H225-H315-H319-H335

[ 警示性声明 ]:
P210-P261-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
F: Flammable;Xi: Irritant;

[ 风险声明 (欧洲) ]:
R11

[ 安全声明 (欧洲) ]:
S16-S26-S36

[ 危险品运输编码 ]:
UN 2347 3/PG 2

[ WGK德国 ]:
3

[ RTECS号 ]:
TZ7630000

[ 包装等级 ]:
II

[ 危险类别 ]:
3.1

[ 海关编码 ]:
2930909090

异丁硫醇合成路线

异丁硫醇上下游产品

异丁硫醇上游产品

异丁硫醇下游产品

异丁硫醇制备

由溴代异丁烷经下述步骤制取。硫脲和溴代异丁烷以甲醇为溶剂，回流反应4-5h，回收甲醇后加入碱液再回流4h，加稀酸至酸性，随即就有异丁硫醇蒸出，直至不再蒸为止。分去水层，油层用无水硫酸镁干燥后，分出干燥剂，进行分馏，收集85-86℃馏分即为成品。

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异丁硫醇海关

[ 海关编码 ]: 2930909090

[ 中文概述 ]:
2930909090. 其他有机硫化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

异丁硫醇文献

Targeting the cerebrovascular large neutral amino acid transporter (LAT1) isoform using a novel disulfide-based brain drug delivery system.

Drug Deliv. 14(1) , 25-31, (2007)

We describe a novel strategy to achieve high affinity recognition for the specific, cerebrovascular large neutral amino acid transporter (LAT1) isoform by covalent coupling of small molecules to the a...

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异丁硫醇

异丁硫醇用途

异丁硫醇名称

异丁硫醇物理化学性质

异丁硫醇MSDS

详细MSDS(安全技术说明书)

异丁硫醇毒性和生态

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

异丁硫醇安全信息

异丁硫醇合成路线

详细合成路线

异丁硫醇上下游产品

异丁硫醇上游产品

异丁硫醇下游产品

异丁硫醇制备

异丁硫醇海关

异丁硫醇文献

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