乙酸银

【用途一】
用作分析试剂，也用于制药工业
【用途二】
在分析中用以除去卤素，液氨的氧化。

[ 密度 ]:
3.25

[ 沸点 ]:
117.1ºC at 760mmHg

[ 熔点 ]:
2000ºC

[ 分子式 ]:
C₂H₃AgO₂

[ 分子量 ]:
166.912

[ 闪点 ]:
40ºC

[ 精确质量 ]:
165.918396

[ PSA ]:
26.30000

[ LogP ]:
0.01380

[ 外观性状 ]:
白色结晶粉末

[ 储存条件 ]:
存放于惰性气体之中;避免光,湿气 (吸湿)

[ 稳定性 ]:
Stability Stable, but light sensitive. Incompatible with strong reducing agents.

[ 水溶解性 ]:
10.2 g/L (20 ºC)

详细MSDS(安全技术说明书)

CHEMICAL IDENTIFICATION

RTECS NUMBER :

AJ4100000

CHEMICAL NAME :

Acetic acid, silver(1+) salt

CAS REGISTRY NUMBER :

563-63-3

LAST UPDATED :

199712

DATA ITEMS CITED :

17

MOLECULAR FORMULA :

C2-H3-O2.Ag

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Intraperitoneal

SPECIES OBSERVED :

Rodent - mouse

DOSE/DURATION :

34 mg/kg

TOXIC EFFECTS :

Behavioral - excitement Behavioral - ataxia Lungs, Thorax, or Respiration - dyspnea

REFERENCE :

DCTODJ Drug and Chemical Toxicology. (Marcel Dekker, 270 Madison Ave., New York, NY 10016) V.1- 1977/78- Volume(issue)/page/year: 6,267,1983 *** REVIEWS *** ACGIH TLV-TWA 0.01 mg(Ag)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.01 mg(Ag)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,231,1971 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-ARAB Republic of Egypt:TWA 0.01 mg(Ag)/m3 JAN 1993 OEL-AUSTRALIA:TWA 0.01 mg(Ag)/m3 JAN 1993 OEL-BELGIUM:TWA 0.01 mg(Ag)/m3 JAN 1993 OEL-DENMARK:TWA 0.01 mg(Ag)/m3 JAN 1993 OEL-FINLAND:TWA 0.01 mg(Ag)/m3;STEL 0.03 mg(Ag)/m3;Skin JAN 1993 OEL-THE NETHERLANDS:TWA 0.01 mg(Ag)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 0.01 mg(Ag)/m3 JAN 1993 OEL-SWITZERLAND:TWA 0.01 mg(Ag)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.01 mg(Ag)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - A1236 No. of Facilities: 103 (estimated) No. of Industries: 3 No. of Occupations: 6 No. of Employees: 553 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - A1236 No. of Facilities: 52 (estimated) No. of Industries: 4 No. of Occupations: 4 No. of Employees: 757 (estimated) No. of Female Employees: 397 (estimated)

[ 符号 ]:

GHS07, GHS09

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335-H400

[ 警示性声明 ]:
P261-P273-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi:Irritant

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S36-S37/39

[ 危险品运输编码 ]:
1759

[ WGK德国 ]:
3

[ RTECS号 ]:
AJ4100000

[ 危险类别 ]:
8.0

[ 海关编码 ]:
28432900

详细合成路线

乙酸银上游产品

乙酸银下游产品

1.由氧化银和乙酸作用而制得。

2.用硝酸银和醋酸钠通过沉淀反应制取。滤集晶体，用蒸馏水彻底洗涤，放在置有浓硫酸的真空干燥器中干燥至恒重。

3.用水合硝酸银与醋酸酐加热至回流温度制得。产品可用冰醋酸重结晶。

[ 海关编码 ]: 28432900

Silver acetate for smoking cessation.

Cochrane Database Syst. Rev. 9 , CD000191, (2012)

Silver acetate produces an unpleasant taste when combined with cigarettes, thereby producing an aversive stimulus. It has been marketed in various forms with the aim of extinguishing the urge to smoke...

Distribution of silver in rats following 28 days of repeated oral exposure to silver nanoparticles or silver acetate.

Part. Fibre Toxicol. 8 , 18, (2011)

The study investigated the distribution of silver after 28 days repeated oral administration of silver nanoparticles (AgNPs) and silver acetate (AgAc) to rats. Oral administration is a relevant route ...

Silver acetate catalyzed hydroamination of 1-(2-(sulfonylamino)phenyl)prop-2-yn-1-ols to (Z)-2-methylene-1-sulfonylindolin-3-ols.

J. Org. Chem. 77(17) , 7166-75, (2012)

A method to prepare (Z)-2-methylene-1-sulfonylindolin-3-ols efficiently that relies on silver acetate catalyzed hydroamination of 1-(2-(sulfonylamino)phenyl)prop-2-yn-1-ols is reported. The reactions ...

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公司名：上海化源世纪贸易有限公司

区域：上海市普陀区

价格：

联系人：徐经理

产品详情：乙酸银

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公司名：上海吉至生化科技有限公司

区域：上海市奉贤区

价格：
￥108.0/5g ￥348.0/25g ￥1118.0/100g ￥4188.0/500g

联系人：刘佳

产品详情：乙酸银

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公司名：上海阿拉丁生化科技股份有限公司

区域：上海市浦东新区

价格：
￥51.9/1g ￥926.9/25g ￥515.9/25g ￥116.9/5g

联系人：阿拉丁

产品详情：乙酸银

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公司名：中山市迪欣化工有限公司

区域：中山市三角镇

价格：
￥5000.0/10kg

联系人：董生

产品详情：醋酸银

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公司名：中山星瑞化工有限公司

区域：中山市中山火炬高技术产业开发区

价格：
￥需询单/25kg

联系人：王洁

产品详情：醋酸银

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