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乙酸锌,二水

乙酸锌,二水用途

【用途一】
测定钠、硫化氢、蛋白的试剂,色谱分析试剂、媒染剂,用于聚酯工业等
【用途二】
用作分析试剂、色谱分析试剂和媒染剂
【用途三】
用作醋酸乙烯、聚乙烯醇生产催化剂,印染媒染剂,医药收敛剂,木材防腐剂,瓷器釉料等
【用途四】
分析试剂,测定钙和锶,点滴分析钠,测定硫化氢,沉淀除去硫化物中的硫,检验蛋白、单宁、尿胆素、磷酸盐和血的试剂。
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乙酸锌,二水名称

[ CAS 号 ]:
5970-45-6

[ 中文名 ]:
醋酸锌

[ 英文名 ]:
Zinc acetate dihydrate

[中文别名 ]:

[英文别名 ]:

乙酸锌,二水物理化学性质

[ 密度 ]:
1.84

[ 沸点 ]:
242-4°C

[ 熔点 ]:
237 ºC

[ 分子式 ]:
C4H10O6Zn

[ 分子量 ]:
219.49900

[ 精确质量 ]:
217.97700

[ PSA ]:
98.72000

[ 外观性状 ]:
白色晶体

[ 储存条件 ]:
Store at RT.

[ 稳定性 ]:
Stable. Incompatible with alkalies, strong oxidizing agents.

[ 水溶解性 ]:
430 g/L (20 ºC)

乙酸锌,二水MSDS

乙酸锌,二水毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :
ZG8750000
CHEMICAL NAME :
Zinc acetate, dihydrate
CAS REGISTRY NUMBER :
5970-45-6
LAST UPDATED :
199506
DATA ITEMS CITED :
9
MOLECULAR FORMULA :
C4-H6-O4.Zn.2H2-O
MOLECULAR WEIGHT :
219.51
WISWESSER LINE NOTATION :
OV1 2 &-ZN- &QH 2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
794 mg/kg
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - miosis (pupillary constriction) Vascular - BP elevation not characterized in autonomic section Nutritional and Gross Metabolic - weight loss or decreased weight gain
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
162 mg/kg
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - miosis (pupillary constriction) Vascular - BP elevation not characterized in autonomic section Nutritional and Gross Metabolic - weight loss or decreased weight gain
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
287 mg/kg
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - conjunctive irritation Vascular - BP elevation not characterized in autonomic section Skin and Appendages - hair
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
108 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
58240 mg/kg/91D-C
TOXIC EFFECTS :
Kidney, Ureter, Bladder - urine volume decreased Blood - other changes Related to Chronic Data - death

MUTATION DATA

TYPE OF TEST :
Cytogenetic analysis
TEST SYSTEM :
Human Lymphocyte
DOSE/DURATION :
7 mg/L
REFERENCE :
CYGEDX Cytology and Genetics (English Translation). Translation of TGANAK. (Allerton Press Inc., 150 Fifth Ave., New York, NY 10011) V.8- 1974- Volume(issue)/page/year: 12(3),46,1978 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X1616 No. of Facilities: 68 (estimated) No. of Industries: 2 No. of Occupations: 2 No. of Employees: 699 (estimated) No. of Female Employees: 570 (estimated)
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乙酸锌,二水安全信息

[ 符号 ]:

GHS07, GHS09

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302-H319-H410

[ 警示性声明 ]:
P273-P305 + P351 + P338-P501

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xn,N

[ 风险声明 (欧洲) ]:
22-36-50/53

[ 安全声明 (欧洲) ]:
S26-S60-S61-S36

[ 危险品运输编码 ]:
UN 3077 9/PG 3

[ WGK德国 ]:
3

[ RTECS号 ]:
ZG8750000

[ 海关编码 ]:
2915299090

乙酸锌,二水上下游产品

乙酸锌,二水制备

1.醋酸、氧化锌与双氧水加热至回收进行反应,反应产物经沉降、过滤、浓缩、结晶、干燥即得产品。

2.50g氧化锌加至300mL 20%醋酸溶液中,搅拌下加热至75~80℃,过滤滤去未溶的氧化锌。在滤液中加入8~10mL 3%过氧化氢,加热至沸。再滴入2%醋酸钡溶液,直至溶液中含有微量的SO42-为止。过滤,往滤液中加入5g新制备的碳酸锌,煮沸5min后,再在水浴上加热40~50min。过滤,滤液中补充适量醋酸至略有醋酸时,冷却,抽滤出结晶,于室温下干燥。所得产品为化学纯成品。

3.用水将500g碳酸锌调成浆糊状,加入醋酸至反应后溶液中仍留有少量碳酸锌。滤去碳酸锌,在滤液中再加入30mL醋酸,浓缩滤液,冷却,抽滤出结晶,放在低温烘箱内干燥,产量600g。

4. 醋酸、氧化锌与双氧水加热至回流进行反应,反应产物经沉降、过滤、浓缩、结晶、干燥即得产品。

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乙酸锌,二水海关

[ 海关编码 ]: 2915299090

[ 中文概述 ]:
HS: 2915299090 其他乙酸盐 退税率:9.0% 监管条件:AB(入境货物通关单,出境货物通关单) 增值税率:17.0% 最惠国关税:5.5% 普通关税:50.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ 监管条件 ]: A.入境货物通关单 B.出境货物通关单

[ 检验检疫 ]: R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验

[ Summary ]:
2915299090 salts of acetic acid。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:5.5%。general tariff:50.0%

乙酸锌,二水文献

Zinc supplements for preventing otitis media.

Cochrane Database Syst. Rev. 4 , CD006639, (2012)

Otitis media (OM) is inflammation of the middle ear and is usually caused by infection. It affects people of all ages but is particularly common in young children. Around 164 million people worldwide ...

New structural motifs in lithium and zinc calix[4]arene chemistry.

Dalton Trans. 42(6) , 1983-6, (2013)

The structures of three novel compounds prepared from the reaction of the lower-rim 1,3-diacid calix[4]arene (LH(2)) with lithium carbonate (1), t-butyl-lithium (2) and zinc acetate (3) are reported.

Influence of trace elements on stabilization of aqueous solutions of ascorbic acid.

Biol. Trace Elem. Res. 150(1-3) , 509-12, (2012)

Together with vitamin C, zinc, selenium, manganese, and magnesium play a vital role in the preservation of organs scheduled for transplantation. In the present study, it is shown that addition of 1 mg...


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