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醋酸铜

醋酸铜用途

用作分析试剂，色谱分析试剂。还用作有机合成催化剂、陶瓷着色及农药等。

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醋酸铜名称

[ CAS 号 ]:
6046-93-1

[ 中文名 ]:
乙酸铜一水合物

[ 英文名 ]:
Cupric acetate monohydrate

[中文别名 ]:

[英文别名 ]:

MFCD00149570
copper,diacetate,hydrate
EINECS 205-553-3
Cupric acetate monohydrate

醋酸铜物理化学性质

[ 密度 ]:
1.882

[ 沸点 ]:
117.1ºC at 760 mmHg

[ 熔点 ]:
115ºC (dec.)

[ 分子式 ]:
C₄H₈CuO₅

[ 分子量 ]:
199.64900

[ 闪点 ]:
40ºC

[ 精确质量 ]:
198.96700

[ PSA ]:
89.49000

[ 外观性状 ]:
暗绿色结晶固体

[ 蒸汽密度 ]:
6.9 (vs air)

[ 储存条件 ]:
库房低温,通风,干燥,与强氧化剂分开存放

[ 稳定性 ]:
Stable. Incompatible with oxidizing agents.

[ 水溶解性 ]:
72 g/L (20 ºC)

醋酸铜MSDS

醋酸铜毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: AG3500000

CHEMICAL NAME :: Acetic acid, copper(2+) salt, monohydrate

CAS REGISTRY NUMBER :: 6046-93-1

LAST UPDATED :: 199701

DATA ITEMS CITED :: 34

MOLECULAR FORMULA :: C4-H6-O4.Cu.H2-O

MOLECULAR WEIGHT :: 199.66

WISWESSER LINE NOTATION :: OV1 2 &-CU- &QH

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 710 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 30,470,1969

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1600 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: AECTCV Archives of Environmental Contamination and Toxicology. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 070944) V.1- 1973- Volume(issue)/page/year: 14,111,1985

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Mammal - species unspecified

DOSE/DURATION :: 5 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Gastrointestinal - changes in structure or function of salivary glands Gastrointestinal - nausea or vomiting

REFERENCE :: JANSAG Journal of Animal Science. (American Soc. of Animal Science, 309 W. Clark St., Champaign, IL 61820) V.1- 1942- Volume(issue)/page/year: 55,337,1982 *** REVIEWS *** TOXICOLOGY REVIEW 85DHAX "Medical and Biologic Effects of Environmental Pollutants Series," Washington, DC, National Academy of Sciences, 1972-77 Volume(issue)/page/year: Cu,56,1977 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-ARAB Republic of Egypt:TWA 0.1 mg(Cu)/m3 (fume) JAN 1993 OEL-AUSTRALIA:TWA 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-AUSTRALIA:TWA 1 mg(Cu)/m3 (dust) JAN 1993 OEL-BELGIUM:TWA 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-BELGIUM:TWA 1 mg(Cu)/m3 (dust) JAN 1993 OEL-DENMARK:TWA 0.1 mg(Cu)/m3 (fume) JAN 1993 OEL-DENMARK:TWA 1 mg(Cu)/m3 (dust) JAN 1993 OEL-FINLAND:TWA 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-FINLAND:TWA 1 mg(Cu)/m3 JAN 1993 OEL-FRANCE:TWA 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-FRANCE:TWA 1 mg(Cu)/m3;STEL 2 mg(Cu)/m3 (dust) JAN 1993 OEL-GERMANY:TWA 0.1 mg(Cu)/m3 (fume) JAN 1993 OEL-GERMANY:TWA 1 mg(Cu)/m3 JAN 1993 OEL-HUNGARY:TWA 0.2 mg(Cu)/m3;STEL 0.4 mg(Cu)/m3 (dust) JAN 1993 OEL-INDIA:TWA 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-THE NETHERLANDS:TWA 02 mg(Cu)/m3 (fume) JAN 1993 OEL-THE NETHERLANDS:TWA 1 mg(Cu)/m3 (dust) JAN 1993 OEL-THE PHILIPPINES:TWA 1.0 mg(Cu)/m3 (fume) JAN 1993 OEL-POLAND:TWA 0.1 mg(Cu)/m3 (fume) JAN 1993 OEL-RUSSIA:STEL 0.5 ppm (1 mg(Cu)/m3) (dust) JAN 1993 OEL-SWEDEN:TWA 0.2 mg(Cu)/m3 (resp. dust) JAN 1993 OEL-SWEDEN:TWA 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-SWEDEN:TWA 1 mg(Cu)/m3 (total dust) JAN 1993 OEL-SWITZERLAND:TWA 0.1 mg(Cu)/m3;STEL 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-SWITZERLAND:TWA 1 mg(Cu)/m3;STEL 1 mg(Cu)/m3 JAN 1993 OEL-THAILAND:TWA 0.1 mg(Cu)/m3 (fume) JAN 1993 OEL-THAILAND:TWA 1 mg(Cu)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-UNITED KINGDOM:TWA 1 mg(Cu)/m3 JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X4554 No. of Facilities: 1064 (estimated) No. of Industries: 3 No. of Occupations: 8 No. of Employees: 6695 (estimated) No. of Female Employees: 2725 (estimated)

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醋酸铜安全信息

[ 符号 ]:

GHS05, GHS07, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H302-H314-H410

[ 警示性声明 ]:
P260-P280-P301 + P312 + P330-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xn: Harmful;N: Dangerous for the environment;

[ 风险声明 (欧洲) ]:
R22;R36/37/38;R50/53

[ 安全声明 (欧洲) ]:
36/37/39-60-61-36-26

[ 危险品运输编码 ]:
UN 9106/3077

[ WGK德国 ]:
3

[ RTECS号 ]:
AG3500000

[ 危险类别 ]:
9.0

[ 海关编码 ]:
2915299011

醋酸铜合成路线

醋酸铜上下游产品

醋酸铜上游产品

醋酸铜下游产品

醋酸铜制备

1.将五水合硫酸铜溶于水中，过滤，另取十水合碳酸钠溶于水，慢慢加入硫酸铜溶液，滤出沉淀，放在水中，加入氨水搅拌，得碱式碳酸铜，再加入冰乙酸，过滤，用水洗涤，干燥得成品。

2.取50g五水硫酸铜溶于500mL水中，备用。另取57g十水碳酸钠溶于240mL水中，加热至60℃，边搅拌边将已配好的硫酸铜溶液加至上述溶液中，碱式碳酸铜析出，静置，抽滤出沉淀，用热水洗涤至无SO2-4为止。

将所得沉淀置于300mL水中，搅拌下加入2mL氨水，静置，倾泻出上层清液，再用氨水及蒸馏水洗涤沉淀数次。

在烧杯中加入180mL水，加入22g醋酸，加热至60℃，然后边搅拌边将已洗好的碱式碳酸铜加入，至容器底部略有碱式碳酸铜剩余。抽滤，将滤液蒸发至原体积1/3时，冷却，晶体析出，滤集晶体，用2mL水洗涤，于室温下干燥，得成品。母液进一步继续蒸发，至快出结晶时，加入5mL 25%醋酸，静置，可再得部分结晶，产量32～35g。

分析纯无水醋酸铜（Ⅱ）用稀醋酸重结晶，可得到一水醋酸铜（Ⅱ）大单晶。

3.将硫酸铜溶于热水中，加入热碳酸钠溶液，即生成碳酸铜沉淀；过滤，洗涤，再用乙酸溶解，蒸发浓缩，结晶后进行洗涤，干燥，即得乙酸铜：

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醋酸铜海关

[ 海关编码 ]: 2915299011

[ 中文概述 ]:
2915299011 乙酸铜。监管条件:无。增值税率:17.0%。退税率:9.0%。最低关税:5.5%。普通关税:50.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2915299011 copper(ii) acetate。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。Lowest tariff:5.5%。General tariff:50.0%

醋酸铜文献

Fundamentals of MOF Thin Film Growth via Liquid-Phase Epitaxy: Investigating the Initiation of Deposition and the Influence of Temperature.

Langmuir 31 , 6114-21, (2015)

Thin films can integrate the versatility and great potential found in the emerging field of metal-organic frameworks directly into device architectures. For fabrication of smart interfaces containing ...

Fine tuning of copper(II)-chlorophyll interactions in organic media. Metalation versus oxidation of the macrocycle.

Dalton Trans. 44(13) , 6012-22, (2015)

The nature of chlorophyll interactions with copper(II) ions varies considerably in organic solvents, depending on the dominant coordinative form. Besides formation of the metallo tetrapyrrolic complex...

Biochemical characterization of Yarrowia lipolytica LIP8, a secreted lipase with a cleavable C-terminal region.

Biochim. Biophys. Acta 1851(2) , 129-40, (2015)

Yarrowia lipolytica is a lipolytic yeast possessing 16 paralog genes coding for lipases. Little information on these lipases has been obtained and only the major secreted lipase, namely YLLIP2, had be...

更多文献

醋酸铜

醋酸铜用途

醋酸铜名称

醋酸铜物理化学性质

醋酸铜MSDS

详细MSDS(安全技术说明书)

醋酸铜毒性和生态

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

醋酸铜安全信息

醋酸铜合成路线

详细合成路线

醋酸铜上下游产品

醋酸铜上游产品

醋酸铜下游产品

醋酸铜制备

醋酸铜海关

醋酸铜文献

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