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1-金刚烷基氟甲酸

1-金刚烷基氟甲酸名称

[ CAS 号 ]:
62087-82-5

[ 中文名 ]:
1-金刚烷基氟甲酸

[ 英文名 ]:
1-ADAMANTYLOXYCARBONYL FLUORIDE

[英文别名 ]:

MFCD00074772
1-Adamantyl fluoroformate
EINECS 263-400-6
Adamantyl fluoroformate
1-ADAMANTYLOXYCARBONYL FLUORIDE

1-金刚烷基氟甲酸物理化学性质

[ 密度 ]:
1.2g/cm3

[ 沸点 ]:
253.2ºC at 760 mmHg

[ 熔点 ]:
30-32ºC(lit.)

[ 分子式 ]:
C₁₁H₁₅FO₂

[ 分子量 ]:
198.23400

[ 闪点 ]:
192 °F

[ 精确质量 ]:
198.10600

[ PSA ]:
26.30000

[ LogP ]:
3.06130

[ 外观性状 ]:
无色结晶

[ 折射率 ]:
1.503

[ 储存条件 ]:
2-8°C

1-金刚烷基氟甲酸MSDS

1-金刚烷基氟甲酸安全信息

[ 符号 ]:

GHS05

[ 信号词 ]:
Danger

[ 危害声明 ]:
H314

[ 警示性声明 ]:
P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
C

[ 风险声明 (欧洲) ]:
34

[ 安全声明 (欧洲) ]:
26-36/37/39-45

[ 危险品运输编码 ]:
UN 2921 8/PG 1

[ 海关编码 ]:
2915900090

1-金刚烷基氟甲酸合成路线

1-金刚烷基氟甲酸上下游产品

1-金刚烷基氟甲酸上游产品

1-金刚烷基氟甲酸下游产品

1-金刚烷基氟甲酸海关

[ 海关编码 ]: 2915900090

[ 中文概述 ]:
2915900090. 其他饱和无环一元羧酸及其酸酐（酰卤、过氧）化物、过氧酸及其卤化、硝化、磺化、亚硝化衍生物. 增值税率:17.0%. 退税率:9.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ 监管条件 ]: A.入境货物通关单 B.出境货物通关单

[ 检验检疫 ]: R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

1-金刚烷基氟甲酸文献

[1-Adamanty fluoroformate, a useful reagent in peptide chemistry (author's transl)].

Hoppe. Seylers. Z. Physiol. Chem. 357 , 1647, (1976)

1-Adamantyl fluoroformate was prepared from 1-adamantol and fluorophosgene. The cristalline and stable fluoroformate was allowed to react with amino acids to give the corresponding 1-adamantyloxycarbo...

G.W. Kenner et al.

Tetrahedron 35 , 2767, (1979)

I.J. Galpin et al.

Tetrahedron 35 , 2771, (1979)

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