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苯锈啶

苯锈啶用途

安非他定是一种甾醇生物合成抑制剂杀菌剂[1]。

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苯锈啶名称

[ CAS 号 ]:
67306-00-7

[ 中文名 ]:
苯锈啶

[ 英文名 ]:
Fenpropidin

[中文别名 ]:

[英文别名 ]:

Ro 12-3049
Fenpropidine
fenpropidin
Patrol
Fenpropidin [BSI:ISO]
Fenpropidin
Fenpropidine [ISO-French]

苯锈啶生物活性

[ 描述 ]:

安非他定是一种甾醇生物合成抑制剂杀菌剂[1]。

[ 相关类别 ]:

研究领域 >> 感染

信号通路 >> 抗感染 >> 真菌

[参考文献]

[1]. Ignaz J Buerge, et al. Stereoselective Metabolism of the Sterol Biosynthesis Inhibitor Fungicides Fenpropidin, Fenpropimorph, and Spiroxamine in Grapes, Sugar Beets, and Wheat. J Agric Food Chem. 2016 Jul 6;64(26):5301-9.

苯锈啶物理化学性质

[ 密度 ]:
0.924 g/cm3

[ 沸点 ]:
368.9ºC at 760 mmHg

[ 熔点 ]:
25°C

[ 分子式 ]:
C₁₉H₃₁N

[ 分子量 ]:
273.45600

[ 闪点 ]:
159.3ºC

[ 精确质量 ]:
273.24600

[ PSA ]:
3.24000

[ LogP ]:
4.58650

[ 外观性状 ]:
棕色透明液体

[ 折射率 ]:
1.507

[ 储存条件 ]:
室温

苯锈啶MSDS

苯锈啶毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TM7292000

CHEMICAL NAME :: Piperidine, 1-(3-(4-(1,1-dimethylethyl)phenyl)-2-methylpropyl)-

CAS REGISTRY NUMBER :: 67306-00-7

BEILSTEIN REFERENCE NO. :: 1245248

LAST UPDATED :: 199710

DATA ITEMS CITED :: 7

MOLECULAR FORMULA :: C19-H31-N

MOLECULAR WEIGHT :: 273.51

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1447 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: DEVEAA Defense des Vegetaux. (Federation Nationale des Groupements de Protection des Cultures, 149, rue de Bercy, 75595 Paris Cedex, 12, France) V.1- 1947- Volume(issue)/page/year: 42(254),33,1988

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1200 gm/m3

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: DEVEAA Defense des Vegetaux. (Federation Nationale des Groupements de Protection des Cultures, 149, rue de Bercy, 75595 Paris Cedex, 12, France) V.1- 1947- Volume(issue)/page/year: 42(252),15,1988

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1820 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: DEVEAA Defense des Vegetaux. (Federation Nationale des Groupements de Protection des Cultures, 149, rue de Bercy, 75595 Paris Cedex, 12, France) V.1- 1947- Volume(issue)/page/year: 42(254),33,1988

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: >2600 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,378,1991

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - duck

DOSE/DURATION :: 1900 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,378,1991

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Unreported

SPECIES OBSERVED :: Bird - domestic

DOSE/DURATION :: 369 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: DEVEAA Defense des Vegetaux. (Federation Nationale des Groupements de Protection des Cultures, 149, rue de Bercy, 75595 Paris Cedex, 12, France) V.1- 1947- Volume(issue)/page/year: 42(254),33,1988

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苯锈啶安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302-H312-H319

[ 警示性声明 ]:
P280-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xn:Harmful;

[ 风险声明 (欧洲) ]:
R21/22;R36

[ 安全声明 (欧洲) ]:
S26-S36/37

[ 危险品运输编码 ]:
UN 2902

[ WGK德国 ]:
3.0

[ RTECS号 ]:
TM7292000

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1(b)

[ 海关编码 ]:
29333990

苯锈啶合成路线

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苯锈啶文献

Investigations into the source of two fungicides measured in the air for 24 hours following application to a cereal crop.

Commun. Agric. Appl. Biol. Sci. 74(1) , 37-46, (2009)

Airborne pesticides can be detected near to recently-treated arable fields for a period of days following the application. Identifying the source of such pesticides is important in developing predicti...

Inhibition of microbial cholesterol oxidases by dimethylmorpholines.

J. Steroid Biochem. 35(1) , 107-13, (1990)

Cholesterol oxidase is a potentially important enzyme in steroid transformations, catalysing the conversion of 3-hydroxy-5-ene steroids to 3-keto-4-ene derivatives via a 3-keto-5-ene intermediate. Mor...

A sterol C-14 reductase encoded by FgERG24B is responsible for the intrinsic resistance of Fusarium graminearum to amine fungicides.

Microbiology 157(Pt 6) , 1665-75, (2011)

Fusarium graminearum, the causal agent of wheat head blight, shows intrinsic resistance to amine fungicides. It is commonly accepted that the amines target sterol C-14 reductase and sterol Δ(8)-Δ(7) i...

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