对氯苯甲酸
对氯苯甲酸用途
用作医药、农药和染料及有机合成中间体
【用途二】
用于有机合成
【用途三】
对氯苯甲酸是杀菌剂烯酰吗啉,杀鼠剂杀鼠灵、杀鼠醚和杀虫剂氟氯苯菊酯的中间体,也是染料和医药的中间体。
【用途四】
染料、农药、医药的中间体。
【用途五】
有机微量分析测定碳、氢、氯的标准样品。
对氯苯甲酸名称
[ CAS 号 ]:
74-11-3
[ 中文名 ]:
香橙素
[ 英文名 ]:
4-Chlorobenzoic acid
[中文别名 ]:
[英文别名 ]:
- 4-CHLOROBENZOIC ACID FOR SYNTHESIS
- 4-CHLORO BENZOIC ACID
- p-Chlorobenzoic acid
- 4-Cl-PhCOOH
- PCBA
- P-CHLOROBENZOICACID
- 4-Chlorobenzoic acid
- p-Carboxychlorobenzene
- 4 CHLOROBENZOIC ACID
- Benzoic acid, p-chloro-
对氯苯甲酸物理化学性质
[ 密度 ]:
1.4±0.1 g/cm3
[ 沸点 ]:
287.2±13.0 °C at 760 mmHg
[ 熔点 ]:
238-241 °C(lit.)
[ 分子式 ]:
C7H5ClO2
[ 分子量 ]:
156.566
[ 闪点 ]:
127.5±19.8 °C
[ 精确质量 ]:
155.997803
[ PSA ]:
37.30000
[ LogP ]:
2.65
[ 外观性状 ]:
白色至灰白色结晶片
[ 蒸汽压 ]:
0.0±0.6 mmHg at 25°C
[ 折射率 ]:
1.583
[ 储存条件 ]:
库房低温通风干燥
[ 稳定性 ]:
Stable. Combustible. Incompatible with bases, strong oxidizing agents.
[ 水溶解性 ]:
soluble in hot water
对氯苯甲酸MSDS
对氯苯甲酸毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- DG4976010
- CHEMICAL NAME :
- Benzoic acid, p-chloro-
- CAS REGISTRY NUMBER :
- 74-11-3
- BEILSTEIN REFERENCE NO. :
- 0907196
- LAST UPDATED :
- 199701
- DATA ITEMS CITED :
- 4
- MOLECULAR FORMULA :
- C7-H5-Cl-O2
- MOLECULAR WEIGHT :
- 156.57
- WISWESSER LINE NOTATION :
- QVR DG
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 1170 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- JAFCAU Journal of Agricultural and Food Chemistry. (American Chemical Soc., Distribution Office Dept. 223, POB 57136, West End Stn., Washington, DC 20037) V.1- 1953- Volume(issue)/page/year: 21,794,1973
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 1 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- BCFAAI Bollettino Chimico Farmaceutico. (Societa Editoriale Farmaceutica, Via Ausonio 12, 20123 Milan, Italy) V.33- 1894- Volume(issue)/page/year: 112,53,1973
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 1170 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- JAFCAU Journal of Agricultural and Food Chemistry. (American Chemical Soc., Distribution Office Dept. 223, POB 57136, West End Stn., Washington, DC 20037) V.1- 1953- Volume(issue)/page/year: 23,724,1975
对氯苯甲酸安全信息
[ 符号 ]:
GHS07
[ 信号词 ]:
Warning
[ 危害声明 ]:
H302
[ 警示性声明 ]:
P301 + P312 + P330
[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves
[ 危害码 (欧洲) ]:
Xn:Harmful
[ 风险声明 (欧洲) ]:
R22;R36/37/38
[ 安全声明 (欧洲) ]:
S26-S36-S37/39
[ 危险品运输编码 ]:
NONH for all modes of transport
[ WGK德国 ]:
2
[ RTECS号 ]:
DG4976010
[ 海关编码 ]:
4002191900
对氯苯甲酸上下游产品
对氯苯甲酸上游产品
对氯苯甲酸下游产品
对氯苯甲酸制备
其制备方法是将高锰酸钾溶液分次加入对氯甲苯和水的混合物中,在75~90℃搅拌下回流5~6h,反应毕用盐酸酸化至pH=2,过滤得粗品,乙醇重结晶得成品。
对氯苯甲酸海关
[ 海关编码 ]: 2916399090
[ 中文概述 ]:
2916399090 其他芳香一元羧酸. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0%
[ 申报要素 ]: 品名, 成分含量, 用途, 丙烯酸、丙烯酸盐或酯应报明包装
[ Summary ]:
2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%
对氯苯甲酸文献
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Polyethylene glycols (PEGs) are attractive as excipients in the manufacture of drug products because they are water soluble and poorly immunogenic. They are used in various pharmaceutical preparations...
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Combination of ozone together with electrolysis (ozone-electrolysis) is a promising wastewater treatment technology. This work investigated the potential use of carbon nanotube (CNT)-based gas diffusi...
Benzenepolycarboxylic acids with potential anti-hemorrhagic properties and structure–activity relationshipsBioorg. Med. Chem. 19 , 7000-2, (2011)
Previously, we reported the structural requirements of the cinnamic acid relatives for inhibition of snake venom hemorrhagic action. In the present study, we examined the effect of benzenepolycarboxyl...
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