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三甲基氰硅烷

三甲基氰硅烷用途

【用途一】
氰基化试剂

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三甲基氰硅烷名称

[ CAS 号 ]:
7677-24-9

[ 中文名 ]:
三甲基氰硅烷

[ 英文名 ]:
Trimethylsilyl cyanide

[中文别名 ]:

[英文别名 ]:

Trimethylsilyl cyanide
trimethylsilylformonitrile
EINECS 231-657-3
Silanecarbonitrile, 1,1,1-trimethyl-
Trimethylsilanecarbonitrile
MFCD00001765
Silanecarbonitrile, trimethyl-
TRIMETHYLSILYLCYANIDE

三甲基氰硅烷物理化学性质

[ 密度 ]:
0.8±0.1 g/cm3

[ 沸点 ]:
118.5±0.0 °C at 760 mmHg

[ 熔点 ]:
8-11 °C(lit.)

[ 分子式 ]:
C₄H₉NSi

[ 分子量 ]:
99.206

[ 闪点 ]:
1.1±0.0 °C

[ 精确质量 ]:
99.050423

[ PSA ]:
23.79000

[ LogP ]:
1.00

[ 外观性状 ]:
透明无色液体

[ 蒸汽压 ]:
16.6±0.2 mmHg at 25°C

[ 折射率 ]:
1.388

[ 储存条件 ]:
0-6°C

[ 水溶解性 ]:
reacts

三甲基氰硅烷MSDS

详细MSDS(安全技术说明书)

三甲基氰硅烷安全信息

[ 符号 ]:

GHS02, GHS06

[ 信号词 ]:
Danger

[ 危害声明 ]:
H225-H300 + H310 + H330

[ 补充危害声明 ]:
Contact with water liberates toxic gas.

[ 警示性声明 ]:
P210-P260-P264-P280-P284-P301 + P310

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
F:Flammable

[ 风险声明 (欧洲) ]:
R11;R26/27/28;R29;R50/53

[ 安全声明 (欧洲) ]:
S16-S36/37/39-S45-S61-S28A-S26

[ 危险品运输编码 ]:
UN 3384 6.1/PG 1

[ WGK德国 ]:
3

[ 包装等级 ]:
II

[ 危险类别 ]:
6.1

[ 海关编码 ]:
29310095

三甲基氰硅烷上下游产品

三甲基氰硅烷上游产品

三甲基氰硅烷下游产品

三甲基氰硅烷制备

在1升烧瓶中盛65克(1摩尔)干燥氛化钾，43.4克和0.4摩尔)三甲基氯硅烷和1}}毫升N一甲基吡咯烷酮。在机械搅拌下加热过夜(16小时)。此时回流温度达到大约105℃。接上蒸馏头和长15厘米的分馏柱，在蒸出少量含六甲基二硅氧烷和氛基三甲基硅烷的混合物前彼分后，收集纯产物，得28.0克(71%）。

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三甲基氰硅烷海关

[ 海关编码 ]: 2931900090

[ 中文概述 ]:
2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

三甲基氰硅烷文献

Asymmetric activation of tropos 2,2'-biphenol with cinchonine generates an effective catalyst for the asymmetric strecker reaction of N-tosyl-protected aldimines and ketoimines.

Angew. Chem. Int. Ed. Engl. 46(44) , 8468-70, (2007)

A chemoselective Ugi-type reaction in water using TMSCN as a functional isonitrile equivalent: generation of heteroaromatic molecular diversity.

Org. Biomol. Chem. 10(46) , 9271-7, (2012)

KF-mediated nucleophilic activation of TMSCN as a functional isonitrile equivalent establishes an efficient and chemoselective Ugi-type multicomponent reaction of a heterocyclic amidine and aldehyde w...

Sc₂(pydc)₂ unit based 1D, 2D and 3D metal-organic frameworks as heterogeneous Lewis acid catalysts for cyanosilylation.

Dalton Trans. 44(4) , 1942-7, (2014)

Three scandium metal-organic frameworks (Sc-MOFs), [Sc(pydc)(Hpydc)(H2O)]·H2O (1), [Sc2(pydc)3(H2O)4]·5H2O (2) and [Sc(pydc)(H2O)(NO3)] (3) with similar Sc2(pydc)2 building unit were prepared by using...

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