硫氰酸苯甲酯
硫氰酸苯甲酯用途
用于杀虫剂的制备
硫氰酸苯甲酯名称
[ CAS 号 ]:
3012-37-1
[ 中文名 ]:
硫氰酸苄酯
[ 英文名 ]:
benzyl thiocyanate
[中文别名 ]:
[英文别名 ]:
- Benzyl thiocyanate
- Solvat 14
- EINECS 221-144-2
- Benzylrhodonid
- Thiocyanic acid,benzyl ester
- MFCD00001832
- Benzyl-thiocyanate
- Thiocyanic Acid Benzyl Ester
- Thiocyanic acid,phenylmethyl ester
- Tropeolin
硫氰酸苯甲酯物理化学性质
[ 密度 ]:
1.32
[ 沸点 ]:
230-235 °C(lit.)
[ 熔点 ]:
39-41 °C(lit.)
[ 分子式 ]:
C8H7NS
[ 分子量 ]:
149.21300
[ 闪点 ]:
>230 °F
[ 精确质量 ]:
149.03000
[ PSA ]:
49.09000
[ LogP ]:
2.40088
[ 外观性状 ]:
黄色-类白色晶体
[ 折射率 ]:
1.561 (20ºC)
[ 储存条件 ]:
低温通风干燥,与库房食品原料分开存放
[ 水溶解性 ]:
insoluble
硫氰酸苯甲酯MSDS
硫氰酸苯甲酯毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- XK8155000
- CHEMICAL NAME :
- Thiocyanic acid, benzyl ester
- CAS REGISTRY NUMBER :
- 3012-37-1
- BEILSTEIN REFERENCE NO. :
- 1859726
- LAST UPDATED :
- 199701
- DATA ITEMS CITED :
- 5
- MOLECULAR FORMULA :
- C8-H7-N-S
- MOLECULAR WEIGHT :
- 149.22
- WISWESSER LINE NOTATION :
- NCS1R
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 40 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- ARZNAD Arzneimittel-Forschung. Drug Research. (Editio Cantor Verlag, Postfach 1255, W-7960 Aulendorf, Fed. Rep. Ger.) V.1- 1951- Volume(issue)/page/year: 16,870,1966
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 17 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- PCBPBS Pesticide Biochemistry and Physiology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1971- Volume(issue)/page/year: 2,95,1972
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Subcutaneous
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 100 mg/kg
- TOXIC EFFECTS :
- Peripheral Nerve and Sensation - flaccid paralysis without anesthesia (usually neuromuscular blockage) Lungs, Thorax, or Respiration - respiratory stimulation Lungs, Thorax, or Respiration - other changes
- REFERENCE :
- JJPAAZ Japanese Journal of Pharmacology. (Japanese Pharmacological Soc., c/o Dept. of Pharmacology, Faculty of Medicine, Kyoto Univ., Sakyo-ku, Kyoto 606, Japan) V.1- 1951- Volume(issue)/page/year: 3,99,1954 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - A1248 No. of Facilities: 28 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 112 (estimated)
硫氰酸苯甲酯安全信息
[ 符号 ]:
GHS07
[ 信号词 ]:
Warning
[ 危害声明 ]:
H302 + H312 + H332
[ 警示性声明 ]:
P280
[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves
[ 危害码 (欧洲) ]:
Xn:Harmful;
[ 风险声明 (欧洲) ]:
R20/21/22;R32
[ 安全声明 (欧洲) ]:
S13-S36/37-S50A
[ 危险品运输编码 ]:
UN 1759 8/PG 2
[ WGK德国 ]:
3
[ RTECS号 ]:
XK8155000
[ 包装等级 ]:
III
[ 危险类别 ]:
6.1
[ 海关编码 ]:
29309070
硫氰酸苯甲酯合成路线
硫氰酸苯甲酯上下游产品
硫氰酸苯甲酯上游产品
硫氰酸苯甲酯下游产品
硫氰酸苯甲酯海关
[ 海关编码 ]: 2930909090
[ 中文概述 ]:
2930909090. 其他有机硫化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%
[ 申报要素 ]: 品名, 成分含量, 用途
[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%
硫氰酸苯甲酯文献
J. Sci. Food Agric. 95 , 2244-51, (2015)
Glucosinolates are abundant in Brassicaceae vegetables, and they are degraded into various organic breakdown products (BPs) (R-CN, -NCS and -SCN) by myrosinase when plant tissues are damaged. This stu...
Subcellular localization of enzymes in Streptomyces aureofaciens and its alteration by benzyl thiocyanate. I. Phosphatases and ATP-glucokinase.Folia Microbiol. (Praha) 32(5) , 402-10, (1987)
Mycelia of a low- and a high-production strain of Streptomyces aureofaciens were converted into protoplasts and divided into five subcellular fractions in order to localize exopolyphosphatases (EC 3.6...
Protein profiles of Streptomyces aureofaciens producing tetracyclines: reappraisal of the effect of benzyl thiocyanate.Curr. Microbiol. 31(2) , 84-91, (1995)
Cell protein profiles of submerged cultures of Streptomyces aureofaciens cultivated in the absence or presence of 12 microM benzyl thiocyanate (BT) were analyzed by one-dimensional SDS polyacrylamide ...
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