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4-苯基哌啶

4-苯基哌啶名称

[ CAS 号 ]:
771-99-3

[ 中文名 ]:
4-苯基哌啶

[ 英文名 ]:
4-Phenylpiperidine

[中文别名 ]:

4-苯基呱啶

[英文别名 ]:

Piperidine,4-phenyl
4-phenylpiperazine
MFCD00005957
4-Ph-piperdine
EINECS 212-243-1
4-phenyl-piperidine

4-苯基哌啶物理化学性质

[ 密度 ]:
1.0±0.1 g/cm3

[ 沸点 ]:
259.9±29.0 °C at 760 mmHg

[ 熔点 ]:
61-65 °C(lit.)

[ 分子式 ]:
C₁₁H₁₅N

[ 分子量 ]:
161.243

[ 闪点 ]:
113.0±19.7 °C

[ 精确质量 ]:
161.120453

[ PSA ]:
12.03000

[ LogP ]:
2.39

[ 外观性状 ]:
灰白色至淡棕色结晶粉末和/或晶体

[ 蒸汽压 ]:
0.0±0.5 mmHg at 25°C

[ 折射率 ]:
1.522

[ 储存条件 ]:
存放于惰性气体之中;避免空气

[ 水溶解性 ]:
可溶于：甲醇

4-苯基哌啶MSDS

4-苯基哌啶安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi:Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S36/37/39-S45-S37/39-S36/37

[ 危险品运输编码 ]:
UN 2922 8/PG 2

[ WGK德国 ]:
3

[ RTECS号 ]:
TM2625000

[ 海关编码 ]:
2933399090

4-苯基哌啶合成路线

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4-苯基哌啶海关

[ 海关编码 ]: 2933399090

[ 中文概述 ]:
2933399090. 其他结构含非稠合吡啶环的化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

4-苯基哌啶文献

A strategy for isotope containment during radiosynthesis--devolatilisation of bromobenzene by fluorous-tagging-Ir-catalysed borylation en route to the 4-phenylpiperidine pharmacophore.

Org. Biomol. Chem. 6 , 4093-4095, (2008)

Syntheses of two 4-phenylpiperidines from bromobenzene have been developed involving anchoring to a fluorous-tag, Ir-catalysed borylation, Pd- and Co-catalysed elaboration then traceless cleavage. Alt...

Structure-activity studies of morphine fragments. I. 4-alkyl-4-(m-hydroxy-phenyl)-piperidines.

Mol. Pharmacol. 34(3) , 363-76, (1988)

The 4-(m-OH-phenyl)piperidines are a flexible fragment of the morphine/benzomorphan fused-ring opioids. Analogs in this family were synthesized with varying 4-alkyl substituents increasing in bulk fro...

Radical-mediated nitrile translocation as the key step in the stereoselective transformation of 2-(4-chloro-2-cyanobutyl)aziridines to methyl cis-(1-arylmethyl-4-phenylpiperidin-2-yl)acetates.

Org. Biomol. Chem. 10(16) , 3308-14, (2012)

Non-activated 2-(4-chloro-2-cyano-2-phenylbutyl)aziridines were used as building blocks for the stereoselective synthesis of novel cis-2-cyanomethyl-4-phenylpiperidines via a microwave-assisted azirid...

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