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丙烯酰氯

丙烯酰氯用途

【用途一】
主要用于合成丙烯酸酯、丙烯酰胺类化合物，也用于制备防灰雾剂I的中间体
【用途二】
该品用于有机合成。国外市售98%商品，沸点72-76℃，相对密度1.114，闪点16℃。
【用途三】
有机合成中间体。高分子化合物单体。

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丙烯酰氯名称

[ CAS 号 ]:
814-68-6

[ 中文名 ]:
丙烯酰氯

[ 英文名 ]:
Acrylyl chloride

[中文别名 ]:

[英文别名 ]:

2-Propenoyl chloride
prop-2-enoyl chloride
Prop-2-enoylchlorid
MFCD00000731
PROPENOYL CHLORIDE
EINECS 212-399-0
Acryloyl chloride

丙烯酰氯物理化学性质

[ 密度 ]:
1.1±0.1 g/cm3

[ 沸点 ]:
75.5±0.0 °C at 760 mmHg

[ 熔点 ]:
72-76ºC

[ 分子式 ]:
C₃H₃ClO

[ 分子量 ]:
90.508

[ 闪点 ]:
16.1±0.0 °C

[ 精确质量 ]:
89.987244

[ PSA ]:
17.07000

[ LogP ]:
1.06

[ 外观性状 ]:
透明液体

[ 蒸汽密度 ]:
>1 (vs air)

[ 蒸汽压 ]:
104.8±0.1 mmHg at 25°C

[ 折射率 ]:
1.417

[ 储存条件 ]:
库房通风低温干燥

[ 稳定性 ]:
Stable, but reacts violently with water. Incompatible with alcohols, oxidizing agents, strong bases. Light-sensitive. Highly flammable.

[ 水溶解性 ]:
易溶于：氯仿

丙烯酰氯MSDS

丙烯酰氯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: AT7350000

CHEMICAL NAME :: Acryloyl chloride

CAS REGISTRY NUMBER :: 814-68-6

BEILSTEIN REFERENCE NO. :: 0635744

LAST UPDATED :: 199701

DATA ITEMS CITED :: 5

MOLECULAR FORMULA :: C3-H3-Cl-O

MOLECULAR WEIGHT :: 90.51

WISWESSER LINE NOTATION :: GV1U1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 25 ppm/4H

TOXIC EFFECTS :: Sense Organs and Special Senses (Eye) - iritis Behavioral - ataxia Lungs, Thorax, or Respiration - emphysema

REFERENCE :: BJIMAG British Journal of Industrial Medicine. (British Medical Journal, Box 560B, Kennebunkport, ME 04046) V.1- 1944- Volume(issue)/page/year: 27,1,1970

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 92 mg/m3/2H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,17,1982

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 180 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#03367 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 0.3 mg/m3;Skin JAN 1993

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丙烯酰氯安全信息

[ 符号 ]:

GHS02, GHS05, GHS06

[ 信号词 ]:
Danger

[ 危害声明 ]:
H225-H314-H330

[ 警示性声明 ]:
P210-P260-P280-P284-P305 + P351 + P338-P310

[ 危害码 (欧洲) ]:
C:Corrosive

[ 风险声明 (欧洲) ]:
R11;R34

[ 安全声明 (欧洲) ]:
S16-S26-S28-S36/37/39-S45-S7/9

[ 危险品运输编码 ]:
UN 3383 6.1/PG 1

[ WGK德国 ]:
3

[ RTECS号 ]:
AT7350000

[ 包装等级 ]:
II

[ 危险类别 ]:
3

[ 海关编码 ]:
2916190090

丙烯酰氯合成路线

丙烯酰氯上下游产品

丙烯酰氯上游产品

丙烯酰氯下游产品

丙烯酰氯制备

由丙烯酸和三氯化磷作用，丙烯酸与三氯化磷的摩尔配比为1：0.333，将两者混合后，加热至沸腾。将反应混合物慢慢冷却到60-70℃。再反应15min，然后在室温下放置2h。反应物分二层，分出上层产物，加入氯化亚铜进行减压蒸馏，收集30-40℃(18.7kPa)的馏分，重蒸一次，收集30-32℃(18.7kPa)的馏分，得到丙烯酰氯。产率66%。

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丙烯酰氯海关

[ 海关编码 ]: 2916190090

[ 中文概述 ]:
2916190090 其他不饱和无环一元羧酸（包括其酸酐、酰卤化物，过氧化物和过氧酸以及它们的衍生物）。监管条件:AB(入境货物通关单,出境货物通关单)。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 丙烯酸、丙烯酸盐或酯应报明包装

[ 监管条件 ]: A.入境货物通关单 B.出境货物通关单

[ 检验检疫 ]: R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验

[ Summary ]:
2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

丙烯酰氯文献

iRGD conjugated TPGS mediates codelivery of paclitaxel and survivin shRNA for the reversal of lung cancer resistance.

Mol. Pharm. 11(8) , 2579-91, (2014)

Multidrug resistance (MDR) is one of the major obstacles in tumor treatment. Herein, we reported an active targeting strategy with peptide-mediated nanoparticles deep into tumor parenchyma, which iRGD...

Controlling osteogenic stem cell differentiation via soft bioinspired hydrogels.

PLoS ONE 9(6) , e98640, (2014)

Osteogenic differentiation of human mesenchymal stem cells (hMSCs) is guided by various physical and biochemical factors. Among these factors, modulus (i.e., rigidiy) of the ECM has gained significant...

Effect of Relative Arrangement of Cationic and Lipophilic Moieties on Hemolytic and Antibacterial Activities of PEGylated Polyacrylates.

Int. J. Mol. Sci. 16 , 23867-80, (2015)

Synthetic amphiphilic polymers have been established as potentially efficient agents to combat widespread deadly infections involving antibiotic resistant superbugs. Incorporation of poly(ethylene gly...

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丙烯酰氯

丙烯酰氯用途

丙烯酰氯名称

丙烯酰氯物理化学性质

丙烯酰氯MSDS

详细MSDS(安全技术说明书)

丙烯酰氯毒性和生态

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

丙烯酰氯安全信息

丙烯酰氯合成路线

详细合成路线

丙烯酰氯上下游产品

丙烯酰氯上游产品

丙烯酰氯下游产品

丙烯酰氯制备

丙烯酰氯海关

丙烯酰氯文献

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