氟氯菊酯

氟氯菊酯用途

联苯菊酯是一种人工合成的拟除虫菊酯杀虫剂,它能延长钠通道的开放时间,导致昆虫神经系统的膜去极化和传导阻滞。联苯菊酯对冈比亚疟原虫和致倦库蚊有效(LD50s分别为0.15和0.16ng/mg),并增加了处理过的玉米和高粱植株的内生线虫死亡率。

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氟氯菊酯名称

[ CAS 号 ]:
82657-04-3

[ 中文名 ]:
联苯菊酯

[ 英文名 ]:
bifenthrin

[中文别名 ]:

[英文别名 ]:

UNII-6B66JED0KN
MFCD00143694
biphenate
capture
Brookade
biphenthrin
Talster
brigade
TALSTAR
bifenthrin

氟氯菊酯生物活性

[ 描述 ]:

[ 相关类别 ]:

信号通路 >> 跨膜转运 >> 钠通道

氟氯菊酯物理化学性质

[ 密度 ]:
1.3±0.1 g/cm3

[ 沸点 ]:
453.2±45.0 °C at 760 mmHg

[ 熔点 ]:
68-71°C

[ 分子式 ]:
C₂₃H₂₂ClF₃O₂

[ 分子量 ]:
422.868

[ 闪点 ]:
136.5±17.9 °C

[ 精确质量 ]:
422.126038

[ PSA ]:
26.30000

[ LogP ]:
7.30

[ 外观性状 ]:
白色结晶固体

[ 蒸汽压 ]:
0.0±1.1 mmHg at 25°C

[ 折射率 ]:
1.564

[ 储存条件 ]:
库房通风低温干燥,与食品原料分开储运

[ 水溶解性 ]:
0.01 g/100 mL

氟氯菊酯MSDS

氟氯菊酯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: GZ1227800

CHEMICAL NAME :: Cyclopropanecarboxylic acid, 3-(2-chloro-3,3,3-trifluoro-1-propenyl)-2,2-dimethyl- , (2-methyl(1,1'-biphenyl)-3-yl)methyl ester, (Z)-

CAS REGISTRY NUMBER :: 82657-04-3

LAST UPDATED :: 199710

DATA ITEMS CITED :: 6

MOLECULAR FORMULA :: C23-H22-Cl-F3-O2

MOLECULAR WEIGHT :: 422.90

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 54500 ug/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,73,1991

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >2 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,73,1991

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - quail

DOSE/DURATION :: 1800 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,73,1991

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - duck

DOSE/DURATION :: >4450 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,73,1991

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氟氯菊酯安全信息

[ 符号 ]:

GHS02, GHS07, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H225-H302 + H312 + H332-H319-H411

[ 警示性声明 ]:
P210-P273-P280-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xn:Harmful

[ 风险声明 (欧洲) ]:
R20/21/22;R50/53

[ 安全声明 (欧洲) ]:
S13-S60-S61-S36/37-S16

[ 危险品运输编码 ]:
UN 2588

[ RTECS号 ]:
GZ1227800

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1(b)

氟氯菊酯合成路线

氟氯菊酯上下游产品

氟氯菊酯上游产品

氟氯菊酯下游产品

氟氯菊酯制备

制备方法一由2-苯基苯甲酸与SOCl2反应制得2-苯基苯甲酰氯，再与二甲基甲酰胺反应制得相应的2-苯基苯甲酰胺，经氢化锂铝还原制得2-苯基二甲苄胺。将2-苯基二甲苄胺与CH3I反应制得相应的铵盐，再经异构化后与氯甲酸乙酯反应，制得2-甲基-3-苯基氯苄。最后与相应的酸在KOH存在下，于乙腈中回流16h，制得联苯菊酯。制备方法二由3，3-二甲基-1-烯戊酸2-甲基-3-苯基溴苄经缩合、环合、脱氯化氢制得

2.由3,3-二甲基-1-烯戊酸2-甲基-3-苯基溴苄经缩合、环合、脱氯化氢制得。

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氟氯菊酯文献

Efficacy and duration of three residual insecticides on cotton duck and vinyl tent surfaces for control of the sand fly Phlebotomus papatasi (Diptera: Psychodidae).

US Army Med. Dep. J. , 66-72, (2013)

This study evaluated the toxicity and duration of 3 residual insecticides against the Old World sand fly, Phlebotomus papatasi, an important vector of cutaneous leishmaniasis, on 2 types of tent mater...

Pyrethroid insecticides in municipal wastewater.

Environ. Toxicol. Chem. 32(11) , 2460-8, (2013)

Pyrethroids are widely used insecticides, but minimal information has been published on their presence in municipal wastewater in the United States. Pyrethroids in wastewater from the Sacramento, Cali...

Monitoring of pesticide residues levels in fresh vegetable form Heibei Province, North China.

Environ. Monit. Assess. 186(10) , 6341-9, (2014)

In this study, 226 samples of seven types of domestic vegetables collected from several vegetable-growing regions in Hebei Province of China were tested for the presence of 38 different agricultural p...

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氟氯菊酯

氟氯菊酯用途

氟氯菊酯名称

氟氯菊酯生物活性

氟氯菊酯物理化学性质

氟氯菊酯MSDS

详细MSDS(安全技术说明书)

氟氯菊酯毒性和生态

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

氟氯菊酯安全信息

氟氯菊酯合成路线

详细合成路线

氟氯菊酯上下游产品

氟氯菊酯上游产品

氟氯菊酯下游产品

氟氯菊酯制备

氟氯菊酯文献

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