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磷酰基乙酸三乙酯

磷酰基乙酸三乙酯用途

甲氧基甲基二乙基膦酸酯是一种生物化学试剂,可作为生物材料或有机化合物进行生命科学相关研究。

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磷酰基乙酸三乙酯名称

[ CAS 号 ]:
867-13-0

[ 中文名 ]:
膦酰乙酸三乙酯

[ 英文名 ]:
Triethyl phosphonoacetate

[中文别名 ]:

[英文别名 ]:

EINECS 212-757-6
Triethyl phosphonacetate
Triethyl phosphonoac
Triethyl phosphono acetate
(ETHOXYCARBONYLMETHYL)DIETHOXYPHOSPHINEOXIDE
AURORA KA-1452
diethyl ethoxycarbonylmethanephosphonate
Ethyl (diethoxyphosphoryl)acetate
ethyl diethoxyphosphorylacetate
MFCD00009177

磷酰基乙酸三乙酯生物活性

[ 描述 ]:

甲氧基甲基二乙基膦酸酯是一种生物化学试剂,可作为生物材料或有机化合物进行生命科学相关研究。

[ 相关类别 ]:

研究领域 >> 其他

[体外研究]

2个-(二乙氧基磷酰基)乙酸乙酯是参与霍纳·沃兹沃斯·埃蒙斯反应和分子内赫克型循环和异构化等反应的反应物。

磷酰基乙酸三乙酯物理化学性质

[ 密度 ]:
1.1±0.1 g/cm3

[ 沸点 ]:
287.4±23.0 °C at 760 mmHg

[ 熔点 ]:
-24°C

[ 分子式 ]:
C₈H₁₇O₅P

[ 分子量 ]:
224.19

[ 闪点 ]:
141.6±42.9 °C

[ 精确质量 ]:
224.081360

[ PSA ]:
71.64000

[ LogP ]:
0.92

[ 外观性状 ]:
无色和淡黄色透明液体

[ 蒸汽压 ]:
0.0±0.6 mmHg at 25°C

[ 折射率 ]:
1.424

[ 储存条件 ]:
Refrigerator

[ 水溶解性 ]:
水溶性：与水接触发生分解,实际上不溶；可溶于：乙醇,甲苯

磷酰基乙酸三乙酯MSDS

磷酰基乙酸三乙酯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: AG9800000

CHEMICAL NAME :: Acetic acid, diethylphosphono-, ethyl ester

CAS REGISTRY NUMBER :: 867-13-0

LAST UPDATED :: 199701

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C8-H17-O5-P

MOLECULAR WEIGHT :: 224.22

WISWESSER LINE NOTATION :: OPO&O&2&2&1VO2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD - Lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NCNSA6 National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review. (Washington, DC) Volume(issue)/page/year: 5,15,1953

TYPE OF TEST :: LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1180 mg/m3/10M

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NDRC** National Defense Research Committee, Office of Scientific Research and Development, Progress Report. Volume(issue)/page/year: NDCrc-132,NOV1942

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磷酰基乙酸三乙酯安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi:Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38;R51/53

[ 安全声明 (欧洲) ]:
S61-S37/39-S26

[ 危险品运输编码 ]:
UN 3082 9/PG 3

[ WGK德国 ]:
3

[ RTECS号 ]:
AG9800000

[ 危险类别 ]:
9.0

[ 海关编码 ]:
2931901990

磷酰基乙酸三乙酯合成路线

磷酰基乙酸三乙酯上下游产品

磷酰基乙酸三乙酯上游产品

磷酰基乙酸三乙酯下游产品

磷酰基乙酸三乙酯海关

[ 海关编码 ]: 2931900090

[ 中文概述 ]:
2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

磷酰基乙酸三乙酯文献

"Carba" peptide bond surrogates. Different approaches to Gly-psi(CH2-CH2)-D,L-Xaa pseudo-dipeptide units.

Int. J. Pept. Protein Res. 39(3) , 273-7, (1992)

Racemic "carba" pseudo-dipeptide units such as Gly-psi(CH2-CH2)-D,L-Xaa were obtained either through the Horner-Emmons condensation of N-tert.-butyloxycarbonyl-beta alaninal with the appropriate subst...

J. Boutagy, R. Thomas

Chem. Rev. 74 , 87, (1974)

T. Minami, J. Motoyoshiya

Synthesis , 333, (1991)

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