叶醇

cis-3-Hexen-1-ol ((Z)-3-Hexen-1-ol) 是一种在许多新鲜水果和蔬菜中发现的绿色草味化合物,被广泛用作加工食品的附加风味剂,以提供新鲜的绿色品质。cis-3-Hexen-1-ol 是多种昆虫的引诱剂。

[ 描述 ]:

[ 相关类别 ]:

[参考文献]

[ 密度 ]:
0.848

[ 沸点 ]:
156-157 ºC

[ 熔点 ]:
-60ºC

[ 分子式 ]:
C₆H₁₂O

[ 分子量 ]:
100.159

[ 闪点 ]:
44 ºC

[ 精确质量 ]:
100.088814

[ PSA ]:
20.23000

[ LogP ]:
1.61

[ 外观性状 ]:
无色液体

[ 蒸汽密度 ]:
3.45 (vs air)

[ 蒸汽压 ]:
1.0±0.6 mmHg at 25°C

[ 折射率 ]:
1.438-1.441

[ 储存条件 ]:
Flammables area

[ 稳定性 ]:
Stable. Substances to be avoided include strong oxidizing agents and strong acids. Flammable.

[ 水溶解性 ]:
INSOLUBLE

详细MSDS(安全技术说明书)

CHEMICAL IDENTIFICATION

RTECS NUMBER :

MP8400000

CHEMICAL NAME :

3-Hexen-1-ol, (Z)-

CAS REGISTRY NUMBER :

928-96-1

BEILSTEIN REFERENCE NO. :

1719712

LAST UPDATED :

199803

DATA ITEMS CITED :

7

MOLECULAR FORMULA :

C6-H12-O

MOLECULAR WEIGHT :

100.18

WISWESSER LINE NOTATION :

Q3U3 -C

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Oral

SPECIES OBSERVED :

Rodent - rat

DOSE/DURATION :

4700 mg/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 12,909,1974

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Intraperitoneal

SPECIES OBSERVED :

Rodent - rat

DOSE/DURATION :

600 mg/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 7,451,1969

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Oral

SPECIES OBSERVED :

Rodent - mouse

DOSE/DURATION :

7 gm/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 7,451,1969

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Intraperitoneal

SPECIES OBSERVED :

Rodent - mouse

DOSE/DURATION :

400 mg/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 7,451,1969

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Administration onto the skin

SPECIES OBSERVED :

Rodent - rabbit

DOSE/DURATION :

>5 gm/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 12,909,1974 ** OTHER MULTIPLE DOSE TOXICITY DATA **

TYPE OF TEST :

TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :

Oral

SPECIES OBSERVED :

Rodent - rat

DOSE/DURATION :

40180 mg/kg/14W-C

TOXIC EFFECTS :

Kidney, Ureter, Bladder - other changes in urine composition Kidney, Ureter, Bladder - changes in bladder weight Endocrine - changes in adrenal weight

REFERENCE :

NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: PB234-882

[ 符号 ]:

GHS02

[ 信号词 ]:
Warning

[ 危害声明 ]:
H226

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
F

[ 风险声明 (欧洲) ]:
R10

[ 安全声明 (欧洲) ]:
S16

[ 危险品运输编码 ]:
UN 1987 3/PG 3

[ WGK德国 ]:
1

[ RTECS号 ]:
MP8400000

[ 包装等级 ]:
III

[ 危险类别 ]:
3

[ 海关编码 ]:
29052990

详细合成路线

叶醇上游产品

叶醇下游产品

1.在液氨中使金属锂（或金属钠）与乙炔反应生成乙炔（或乙炔钠），再与乙醇反应生成乙基乙炔。乙基乙炔与环氧乙烷反应得到3-乙炔-1-醇，最后加氢制得产品叶醇。由四氢呋喃为起始原料，或用3-己炔醇经选择性氢化而成。也可由3一氯丙醇、三苯基膦和丙醛进行Wittig反应而成。

2.烟草：BU，56；FC，9，18；BU，18；FC，40。以乙炔和三乙基铝为原料制取；以氯化丙炔和格氏试剂反应制取；以乙烯基乙炔为原料制取；以己二烯酸酯为原料制取。

[ 海关编码 ]: 2905290000

[ 中文概述 ]:
2905290000 其他不饱和一元醇。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:5.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 包装

[ Summary ]:
2905290000 unsaturated monohydric alcohols。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

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区域：上海市普陀区

价格：

联系人：徐经理

产品详情：叶醇

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公司名：上海吉至生化科技有限公司

区域：上海市奉贤区

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联系人：刘佳

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公司名：上海阿拉丁生化科技股份有限公司

区域：上海市浦东新区

价格：
￥476.9/100ml ￥159.9/25ml ￥1911.9/500ml ￥43.9/5ml

联系人：阿拉丁

产品详情：顺-3-己烯-1-醇

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公司名：上海创赛科技有限公司

区域：上海市嘉定区

价格：
￥59.0/5ml ￥178.0/25ml ￥481.0/100ml ￥1709.0/500ml

联系人：夏言

产品详情：[Perfemiker]叶醇,98%

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公司名：中山市迪欣化工有限公司

区域：中山市三角镇

价格：
￥770.0/150kg

联系人：陈雪萍

产品详情：叶醇

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