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N,N'-双(亚水杨基)乙二胺

N,N'-双(亚水杨基)乙二胺用途

荧光法测定镁。金属离子的抑制剂。

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N,N'-双(亚水杨基)乙二胺名称

[ CAS 号 ]:
94-93-9

[ 中文名 ]:
N,N'-双(亚水杨基)乙二胺

[ 英文名 ]:
n,n'-bis(salicylidene)ethylenediamine

[中文别名 ]:

[英文别名 ]:

EINECS 202-376-3
n,n'-bis(salicylidene)ethylenediamine
MFCD00002244

N,N'-双(亚水杨基)乙二胺物理化学性质

[ 密度 ]:
1.324g/cm3

[ 沸点 ]:
498.2ºC at 760mmHg

[ 熔点 ]:
127-128 °C(lit.)

[ 分子式 ]:
C₁₆H₁₆N₂O₂

[ 分子量 ]:
268.31000

[ 闪点 ]:
193.6ºC

[ 精确质量 ]:
268.12100

[ PSA ]:
65.18000

[ LogP ]:
2.63580

[ 外观性状 ]:
黄色细结晶粉末

[ 折射率 ]:
1.581

[ 储存条件 ]:
2~8℃

[ 水溶解性 ]:
chloroform: 0.1 g/mL, clear

N,N'-双(亚水杨基)乙二胺MSDS

N,N'-双(亚水杨基)乙二胺毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: SL3780000

CHEMICAL NAME :: Phenol, 2,2'-(1,2-ethanediylbis(nitrilomethylidyne))bis-

CAS REGISTRY NUMBER :: 94-93-9

BEILSTEIN REFERENCE NO. :: 0535296

LAST UPDATED :: 199712

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C16-H16-N2-O2

MOLECULAR WEIGHT :: 268.34

WISWESSER LINE NOTATION :: QR B1UN2NU1R BQ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 90,260,1947

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 100 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD277-689

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N,N'-双(亚水杨基)乙二胺安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi: Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ RTECS号 ]:
SL3780000

[ 海关编码 ]:
2925290090

N,N'-双(亚水杨基)乙二胺合成路线

N,N'-双(亚水杨基)乙二胺上下游产品

N,N'-双(亚水杨基)乙二胺上游产品

N,N'-双(亚水杨基)乙二胺下游产品

N,N'-双(亚水杨基)乙二胺海关

[ 海关编码 ]: 2925290090

[ 中文概述 ]:
2925290090 其他亚胺及其衍生物，以及它们的盐。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2925290090 other imines and their derivatives; salts thereof。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

N,N'-双(亚水杨基)乙二胺文献

Anion-induced self-assembly of luminescent and magnetic homoleptic cyclic tetranuclear Ln4(salen)4 and Ln4(salen)2 complexes (Ln = Nd, Yb, Er, or Gd).

Inorg. Chem. 51(21) , 11377-86, (2012)

Unique homoleptic cyclic tetranuclear Ln(4)(Salen)(4) complexes [Ln(4)(L)(2)(HL)(2)(μ(3)-OH)(2)Cl(2)]·2Cl (Ln = Nd, 1; Ln = Yb, 2; Ln = Er, 3; Ln = Gd, 4) or Ln(4)(Salen)(2) complexes [Ln(4)(L)(2)(μ(3...

Ligand contributions to the electronic structures of the oxidized cobalt(II) salen complexes.

Inorg. Chem. 51(20) , 10557-71, (2012)

Square planar cobalt(II) complexes of salen ligands N,N'-bis(3-tert-butyl-5R-salicylidene)-1,2-cyclohexanediamine), where R = OMe (1) and tert-butyl (2), were prepared. 1 and 2 were electrochemically ...

Synthesis, spectroscopy, magnetic and redox behaviors of copper(II) complexes with tert-butylated salen type ligands bearing bis(4-aminophenyl)ethane and bis(4-aminophenyl)amide backbones.

Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 104 , 203-12, (2013)

New salen type ligands, N,N'-bis(X-3-tert-butylsalicylidene)-4,4'-ethylenedianiline [(X=H (1), 5-tert-butyl (2)] and N,N'-bis(X-3-tert-butylsalicylidene)-4,4'-amidedianiline [X=H (3), 5-tert (4)] and ...

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