苯并三氮唑
苯并三氮唑用途
苯并三氮唑名称
[ CAS 号 ]:
95-14-7
[ 中文名 ]:
苯三氮唑
[ 英文名 ]:
1H-Benzotriazole
[中文别名 ]:
[英文别名 ]:
- BENZOTRIAZOLE PHOTOGRADE
- 1H-Benzo[d][1,2,3]triazole
- Benzotriazol
- HETEROCYLIC NITROGEN
- cobratec99
- 1h-benzo
- U-6233
- 1, 2, 3 BENZOTRIAZOLE
- T706
- 1,2,3-1H-Benzotriazole
苯并三氮唑生物活性
苯并三氮唑物理化学性质
[ 密度 ]:
1.3±0.1 g/cm3
[ 沸点 ]:
204 ºC (15 mmHg)
[ 熔点 ]:
97-99 °C(lit.)
[ 分子式 ]:
C6H5N3
[ 分子量 ]:
119.12
[ 闪点 ]:
170 ºC
[ 精确质量 ]:
119.048347
[ PSA ]:
41.57000
[ LogP ]:
1.34
[ 外观性状 ]:
白色至淡黄褐色的晶体或白色粉末
[ 蒸汽密度 ]:
4.1 (vs air)
[ 蒸汽压 ]:
0.0±0.8 mmHg at 25°C
[ 折射率 ]:
1.715
[ 储存条件 ]:
通风低温干燥
[ 稳定性 ]:
Stable, but may be light sensitive. Incompatible with strong oxidizing agents, heavy metals.
[ 水溶解性 ]:
25 g/l in water (20 ºC)
苯并三氮唑MSDS
苯并三氮唑毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- DM1225000
- CHEMICAL NAME :
- 1H-Benzotriazole
- CAS REGISTRY NUMBER :
- 95-14-7
- BEILSTEIN REFERENCE NO. :
- 0112133
- LAST UPDATED :
- 199710
- DATA ITEMS CITED :
- 21
- MOLECULAR FORMULA :
- C6-H5-N3
- MOLECULAR WEIGHT :
- 119.14
- WISWESSER LINE NOTATION :
- T56 BMNNJ
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 560 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LC50 - Lethal concentration, 50 percent kill
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 1910 mg/m3/3H
- TOXIC EFFECTS :
- Lungs, Thorax, or Respiration - structural or functional change in trachea or bronchi Lungs, Thorax, or Respiration - dyspnea Lungs, Thorax, or Respiration - other changes
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- >1 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 615 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 400 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intravenous
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 238 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- 450 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - guinea pig
- DOSE/DURATION :
- 500 mg/kg
- TOXIC EFFECTS :
- Autonomic Nervous System - other (direct) parasympathomimetic Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - cyanosis
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 109 mg/kg/26W-I
- TOXIC EFFECTS :
- Endocrine - other changes Blood - normocytic anemia Blood - leukopenia
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 220 gm/kg/78W-I
- TOXIC EFFECTS :
- Tumorigenic - equivocal tumorigenic agent by RTECS criteria Brain and Coverings - tumors
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 770 gm/kg/78W-I
- TOXIC EFFECTS :
- Tumorigenic - equivocal tumorigenic agent by RTECS criteria Lungs, Thorax, or Respiration - tumors Lungs, Thorax, or Respiration - bronchiogenic carcinoma
MUTATION DATA
- TYPE OF TEST :
- Morphological transformation
- TEST SYSTEM :
- Rodent - rat Embryo
- DOSE/DURATION :
- 94 ug/plate
- REFERENCE :
- JJATDK JAT, Journal of Applied Toxicology. (John Wiley & Sons Ltd., Baffins Lane, Chichester, W. Sussex PO19 1UD, UK) V.1- 1981- Volume(issue)/page/year: 1,190,1981 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 5 mg/m3;Skin JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 82113 No. of Facilities: 1661 (estimated) No. of Industries: 23 No. of Occupations: 33 No. of Employees: 5550 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 82113 No. of Facilities: 17143 (estimated) No. of Industries: 144 No. of Occupations: 107 No. of Employees: 279549 (estimated) No. of Female Employees: 40869 (estimated)
苯并三氮唑安全信息
[ 符号 ]:
GHS07
[ 信号词 ]:
Warning
[ 危害声明 ]:
H302 + H332-H319-H412
[ 警示性声明 ]:
P273-P305 + P351 + P338
[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves
[ 危害码 (欧洲) ]:
F:Flammable
[ 风险声明 (欧洲) ]:
R11;R20/21/22;R36/37/38;R5
[ 安全声明 (欧洲) ]:
S26-S36/37-S61-S45-S36/37/39-S28A
[ 危险品运输编码 ]:
2811
[ WGK德国 ]:
1
[ RTECS号 ]:
DM1225000
[ 海关编码 ]:
2933990090
苯并三氮唑合成路线
苯并三氮唑上下游产品
苯并三氮唑上游产品
苯并三氮唑下游产品
苯并三氮唑制备
1.由邻苯三胺与亚硝酸钠反应而得。将邻苯二胺加入50℃水中溶解,再加入冰醋酸,降温至5℃,加入亚硝酸钠搅拌反应。反应物渐渐变成暗绿色,温度升至70-80℃,溶液变为桔红色,于室温放置2h,冷却,滤出结晶,用冰水洗涤,干燥得粗品,将粗品减压蒸馏,收集201-204℃(2.0kPa)的馏分,再用苯重结晶,可得熔点为96-97℃的产品,产率80%左右。曾有报道用亚硝酸钠处理多菌灵的缩合废水而得副产物苯并三氮唑。
2.邻苯二胺重氮化法。将邻苯二胺重氮化,再在乙酸中环合制得粗苯并三唑,再重结晶法精制、真空干燥,即可制得较纯的苯并三唑。
3.邻苯二胺法 邻苯二胺法是最经典的合成苯并三氮唑的方法,它包括邻苯二胺常压合成法和经过改进的邻苯二胺高压法。
①邻苯二胺常压法 先将邻苯二胺溶于醋酸水溶液中,并配制40%左右的亚硝酸钠水溶液。两种溶液预冷至1~5℃后混合反应,并保持在冰浴中,随后迅速升温至80℃闭环生成苯并三氮唑,冷却后过滤、水洗得到粗产品。在绝对压力为2000Pa下蒸馏,收集2.0~204℃的馏分,用苯结晶得到产品,收率为70%~80%。另一生产实例为:将邻苯二胺加入50℃水溶液中溶解,再加入冰醋酸,降温至5℃,加入亚硝酸钠搅拌反应,反应物渐渐变成暗绿色,温度升至70~80℃,溶液变成橘红色,于室温放置2h,冷却、滤出结晶,用冰水洗涤,干燥得粗品;将粗品减压蒸馏,收集201~204℃(2.0kPa)的馏分,再用苯重结晶,可得熔点为96~97℃的产品,产率约80%。
②邻苯二胺高压法 邻苯二胺与亚硝酸钠的投料摩尔比为1∶(1~1.05),反应温度为200~300℃,压力为4.8×106~6.9×106Pa。反应完毕后,用酸调pH值为6。由于重氮化闭环反应没有酸参加,所以减少了重氮偶合产生深颜色焦油状物的机会,从而提高了产品的收率,同时使产品的纯化变得容易。例如,邻苯二胺同37%的亚硝酸钠水溶液,在温度为260℃、压力为3.0×106~3.3×106Pa条件下,反应3h后冷却,用浓硫酸将Pa值从11.7调到6,得到纯度为100%、收率为96.9%的苯并三氮唑。
4.苯并咪唑酮法 苯并咪唑酮与亚硝酸钠水溶液在190℃、高压下反应75min,经酸化、水洗、干燥,获得产品,收率为85.3%。
5.邻硝基苯肼法 邻硝基苯肼在氨水、异丙醇和己二醇混合水溶液中,在140℃和高压下反应1.5h,生成1-羟基苯并三氮唑(HBTA)。用铜三氧化二铬作催化剂,按照92∶8比例通入氢气和氮气,在160~170℃和高压下脱氧加氢反应1h,HBTA脱氧加氢生成BTA,最终苯并三氮唑的收率为89%。反应式如下:
6.邻硝基氯苯法 先由邻硝基氯苯与水合肼直接合成HBTA,然后脱氧加氢生成BTA,最高总收率可达8.6%。此法优点是收率高、中间环节少,是一种很有前途而且十分重要的方法。
苯并三氮唑海关
[ 海关编码 ]: 2933990090
[ 中文概述 ]:
2933990090. 其他仅含氮杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
[ 申报要素 ]: 品名, 成分含量, 用途, 乌洛托品请注明外观, 6-己内酰胺请注明外观, 签约日期
[ Summary ]:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%
苯并三氮唑文献
Environ. Sci. Pollut. Res. Int. 22(8) , 5842-9, (2015)
Textiles play an important role in our daily life, and textile production is one of the oldest industries. In the manufacturing chain from natural and/or synthetic fibers to the final clothing product...
Analysis of endocrine disrupters and related compounds in sediments and sewage sludge using on-line turbulent flow chromatography-liquid chromatography-tandem mass spectrometry.J. Chromatogr. A. 1352 , 29-37, (2014)
A novel fully automated method based on dual column switching using turbulent flow chromatography followed by liquid chromatography coupled to tandem mass spectrometry (TFC-LC-MS/MS) was applied for t...
A multi-residue method for determination of 70 organic micropollutants in surface waters by solid-phase extraction followed by gas chromatography coupled to tandem mass spectrometry.Environ. Sci. Pollut. Res. Int. 22(2) , 1095-112, (2015)
A multi-residue method, based on gas chromatography coupled to tandem mass spectrometry (GC-MS/MS), has been developed for the determination of 70 organic micropollutants from various chemical classes...
相关化工产品/化学物质:
推荐生产厂家/供应商:
公司名:上海化源生化科技有限公司
区域:上海市普陀区
价格:
联系人:徐经理
产品详情:苯骈三氮唑
公司名:南通润丰石油化工有限公司
区域:南通市崇川区
价格:
¥需询单/1kg
¥需询单/1ton
联系人:曹经理
产品详情:苯骈三氮唑
公司名:上海吉至生化科技有限公司
区域:上海市奉贤区
价格:
¥138.0/500g
联系人:刘佳
产品详情:苯骈三氮唑
公司名:上海阿拉丁生化科技股份有限公司
区域:上海市浦东新区
价格:
¥48.9/100g
¥126.9/500g
¥31.9/100g
¥89.9/500g
联系人:阿拉丁
产品详情:苯骈三氮唑
公司名:中山市迪欣化工有限公司
区域:中山市三角镇
价格:
¥65.0/25kg
联系人:董生
产品详情:苯并三氮唑
查看所有供应商请点击:
相关化合物
【苯并三氮唑】化源网提供苯并三氮唑CAS号95-14-7,苯并三氮唑MSDS及其说明、性质、英文名、生产厂家、作用/用途、分子量、密度、沸点、熔点、结构式等。CAS号查询苯并三氮唑上化源网,专业又轻松。>>电脑版:苯并三氮唑
标题:苯并三氮唑_MSDS_用途_密度_苯并三氮唑CAS号【95-14-7】_化源网 地址:https://m.chemsrc.com/mip/cas/95-14-7_402923.html