二羟基富马酸二水合物结构式
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常用名 | 二羟基富马酸二水合物 | 英文名 | Dihydroxyfumaric acid dihydrate |
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CAS号 | 20688-70-4 | 分子量 | 184.10200 | |
密度 | N/A | 沸点 | N/A | |
分子式 | C4H8O8 | 熔点 | -155ºC (dec.) | |
MSDS | 美版 | 闪点 | N/A |
Exploratory experiments on the chemistry of the "glyoxylate scenario": formation of ketosugars from dihydroxyfumarate.
J. Am. Chem. Soc. 134(7) , 3577-89, (2012) In the context of a "glyoxylate scenario" of primordial metabolism, the reactions of dihydroxyfumarate (DHF) with reactive small molecule aldehydes (e.g., glyoxylate, formaldehyde, glycolaldehyde, and glyceraldehyde) in water were investigated and shown to fo... |
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Production of tartrates by cyanide-mediated dimerization of glyoxylate: a potential abiotic pathway to the citric acid cycle.
J. Am. Chem. Soc. 135(36) , 13440-5, (2013) An abiotic formation of meso- and DL-tartrates in 80% yield via the cyanide-catalyzed dimerization of glyoxylate under alkaline conditions is demonstrated. A detailed mechanism for this conversion is proposed, supported by NMR evidence and (13)C-labeled react... |
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The preparation and properties of lithium hydroxypyruvate and hydroxypyruvic acid.
Biochem. J. 68(1) , 74-81, (1958)
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The crystal structure of dihydroxyfumaric acid dihydrate. Gupta MP and Gupta NP.
Acta Crystallogr. B 24(5) , 631-636, (1968)
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