间苯二甲醚结构式
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常用名 | 间苯二甲醚 | 英文名 | 1,3-Dimethoxybenzene |
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| CAS号 | 151-10-0 | 分子量 | 138.164 | |
| 密度 | 1.0±0.1 g/cm3 | 沸点 | 217.5±0.0 °C at 760 mmHg | |
| 分子式 | C8H10O2 | 熔点 | -52°C | |
| MSDS | 中文版 美版 | 闪点 | 87.8±0.0 °C |
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Rotamers of o- and m-dimethoxybenzenes studied by mass-analyzed threshold ionization spectroscopy and theoretical calculations.
J. Phys. Chem. A 114(42) , 11144-52, (2010) We applied two-color resonant two-photon mass-analyzed threshold ionization (MATI) spectroscopy to investigate the molecular properties of the selected rotamers of o-dimethoxybenzene (ODMB) and m-dimethoxybenzene (MDMB). The present experimental results show ... |
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Stereoselective glycosylations using oxathiane spiroketal glycosyl donors.
Carbohydr. Res. 348 , 6-13, (2012) Novel oxathiane spiroketal donors have been synthesised and activated via an umpolung S-arylation strategy using 1,3,5-trimethoxybenzene and 1,3-dimethoxybenzene. The comparative reactivity of the resulting 2,4,6-trimethoxyphenyl (TMP)- and 2,4-dimethoxypheny... |
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Solvation of dichlorocarbene: complexation with aryl ethers.
J. Phys. Chem. A 114(1) , 209-17, (2010) Dichlorocarbene (CCl(2)), generated by laser flash photolysis of dichlorodiazirine, formed pi- and O-ylidic complexes with aromatic ethers such as anisole, 1,3-dimethoxybenzene, 1,3,5-trimethoxybenzene, dibenzofuran, and dibenzo-18-crown-6 and with the aromat... |
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Decrease in glucose oxidation in isolated brown fat cells from rats due to tropolone and dimethoxybenzene.
Gen. Pharmacol. 12(1) , 47-50, (1981) 1. 1. Glucose conversion to carbon dioxide in control and insulin treated brown fat cells is reduced in the presence of tropolone and dimethoxybenzene. 2. 2. The effects of ortho-, meta- and para-dimethoxybenzene are similar to each other; all are more potent... |
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C-terminal N-alkylated peptide amides resulting from the linker decomposition of the Rink amide resin: a new cleavage mixture prevents their formation.
J. Pept. Sci. 12(3) , 227-32, (2006) Decomposition of the resin linkers during TFA cleavage of the peptides in the Fmoc strategy leads to alkylation of sensitive amino acids. The C-terminal amide alkylation, reported for the first time, is shown to be a major problem in peptide amides synthesize... |
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Optimization of the solid-phase microextraction method in the determination of Ixodes ricinus (L.) volatiles.
J. Sep. Sci. 29(2) , 236-41, (2006) For the first time, headspace solid-phase microextraction coupled with GC-MS analysis was used to study volatile compounds emitted by the tick Ixodes ricinus (L.). Variables such as the type of SPME fibre, equilibration time and extraction time have been eval... |
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Short-step synthesis of a resveratrol derivative from commercially available 1,3-dimethoxybenzene and 4-vinylanisole.
Biosci. Biotechnol. Biochem. 73(11) , 2547-8, (2009) An efficient synthesis of tri-O-methylated resveratrol is presented using an advanced Heck reaction promoted by Pd(dba)(2) in the presence of P(t-Bu)(3). |
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Formation of an unusual dimeric compound by lead tetraacetate oxidation of a corynanthe-type indole alkaloid, mitragynine.
Chem. Pharm. Bull. 50(7) , 960-3, (2002) Lead tetraacetate oxidation of a Corynanthe-type indole alkaloid, mitragynine, produced mainly 7-acetoxyindolenine derivative (2) together with a dimeric compound (4) as a minor product. The novel structure having a bridge between the C-11' and C-7 positions ... |