2-乙酰基环己酮
2-乙酰基环己酮结构式
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常用名 | 2-乙酰基环己酮 | 英文名 | 2-Acetylcyclohexanone |
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| CAS号 | 874-23-7 | 分子量 | 140.180 | |
| 密度 | 1.0±0.1 g/cm3 | 沸点 | 224.3±0.0 °C at 760 mmHg | |
| 分子式 | C8H12O2 | 熔点 | N/A | |
| MSDS | 美版 | 闪点 | 79.4±0.0 °C |
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Tautomerization of 2-acetylcyclohexanone. 1. Characterization of keto-enol/enolate equilibria and reaction rates in water.
J. Org. Chem. 68(7) , 2680-8, (2003) The keto-enol tautomerism of 2-acetylcyclohexanone (ACHE) was studied in water under different experimental conditions. By contrast with other previously studied beta-diketones, the keto-enol interconversion in the ACHE system is a slow process. Under equilib... |
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Copper-catalyzed amination of (bromophenyl)ethanolamine for a concise synthesis of aniline-containing analogues of NMDA NR2B antagonist ifenprodil.
Org. Biomol. Chem. 8(5) , 1111-20, (2010) An operationally simple and concise synthesis of anilinoethanolamines, as NMDA NR2B receptor antagonist ifenprodil analogues, was developed via a copper-catalyzed amination of the corresponding bromoarene. Coupling was achieved with linear primary alkylamines... |
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An alternative to the classical α-arylation: the transfer of an intact 2-iodoaryl from ArI(O₂CCF₃)₂.
Angew. Chem. Int. Ed. Engl. 53(42) , 11298-301, (2014) The α-arylation of carbonyl compounds is generally accomplished under basic conditions, both under metal catalysis and via aryl transfer from the diaryl λ(3)-iodanes. Here, we describe an alternative metal-free α-arylation using ArI(O2CCF3)2 as the source of ... |
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Nitrosation of 2-acetylcyclohexanone. 2. Reaction in water in the absence and presence of cyclodextrins.
J. Org. Chem. 68(7) , 2689-97, (2003) The kinetic study of the nitrosation of the enol of 2-acetylcyclohexanone (ACHE) has been performed in aqueous acid media in the absence and presence of alpha- and beta-cyclodextrin. The reaction is first-order with respect to both reactants concentration: [n... |