烯丙基苯基醚结构式
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常用名 | 烯丙基苯基醚 | 英文名 | (Allyloxy)benzene |
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CAS号 | 1746-13-0 | 分子量 | 134.175 | |
密度 | 0.9±0.1 g/cm3 | 沸点 | 192.4±9.0 °C at 760 mmHg | |
分子式 | C9H10O | 熔点 | N/A | |
MSDS | 中文版 美版 | 闪点 | 62.8±0.0 °C |
SmI2/water/amine mediates cleavage of allyl ether protected alcohols: application in carbohydrate synthesis and mechanistic considerations.
Org. Lett. 5(22) , 4085-8, (2003) [reaction: see text]. SmI2/H2O/amine provides selective cleavage of unsubstituted allyl ethers in good to excellent yields. This method is therefore useful in deprotection of alcohols and carbohydrates. |
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Pd-catalyzed synthesis of allylic silanes from allylic ethers.
Org. Lett. 12(1) , 28-31, (2010) Allylic phenyl ethers serve as electrophiles toward Pd(0) en route to a variety of allylic silanes. The reactions can be run at room temperature in water as the only medium using micellar catalysis. |
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Stereoselective epoxidation of phenyl allyl ether by alkene-utilizing bacteria.
Appl. Microbiol. Biotechnol. 37(1) , 28-31, (1992) Eighteen newly isolated ethene- and propene-utilizing bacteria were screened for the ability to produce phenyl glycidyl ether, a common precursor for the synthesis of beta blockers, from phenyl allyl ether. These organisms included Aerococcus, Alcaligenes, Mi... |