((4R,5R)-(+)-O-[1-苯甲基-1-(5-甲基-2-苯基-4,5-二氢恶唑-4-基)-2-苯基乙基](二苯基膦亚盐)(1,5-COD)铱(I)四(3,5-二(三氟甲基)苯基硼酸结构式
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常用名 | ((4R,5R)-(+)-O-[1-苯甲基-1-(5-甲基-2-苯基-4,5-二氢恶唑-4-基)-2-苯基乙基](二苯基膦亚盐)(1,5-COD)铱(I)四(3,5-二(三氟甲基)苯基硼酸 | 英文名 | ((4R,5R)-(+)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)-2-phenylethyl] (diphenylphosphinite)(1,5-COD)iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenylborate (R,R)-[COD]Ir[Ph2P |
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CAS号 | 880262-16-8 | 分子量 | 1735.25000 | |
密度 | N/A | 沸点 | N/A | |
分子式 | C77H58BF24IrNO3P | 熔点 | N/A | |
MSDS | 美版 | 闪点 | N/A |
A New Class of Modular Phosphinite-Oxazoline Ligands: Ir-Catalyzed Enantioselective Hydrogenation of Alkenes We thank Dr. Martin Studer and Dr. Beno_t Pugin (Solvias AG, Basel) for fruitful discussions, and Prof. Kevin Burgess (Texas A&M University) for preprints of related unpublished work. Financial support by the Swiss National Science Foundation is gratefully acknowledged.
Angew. Chem. Int. Ed. Engl. 40 , 4445-4447, (2001)
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Threonine-derived phosphinite-oxazoline ligands for the Ir-catalyzed enantioselective hydrogenation. Menges, F. and Pfaltz, A.
Adv. Synth. Catal. 344 , 40-44, (2002)
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