五甲基环戊二烯基双(三苯基膦)氯化钌(II)结构式
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常用名 | 五甲基环戊二烯基双(三苯基膦)氯化钌(II) | 英文名 | PENTAMETHYLCYCLOPENTADIENYLBIS(TRIPHENY& |
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| CAS号 | 92361-49-4 | 分子量 | 796.32000 | |
| 密度 | N/A | 沸点 | N/A | |
| 分子式 | C46H45ClP2Ru | 熔点 | 128ºC (D) | |
| MSDS | 中文版 美版 | 闪点 | N/A |
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Metal-catalyzed living radical polymerization.
Chem. Rev. 101 , 3689, (2001)
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Ruthenium-catalyzed cycloaddition of alkynes and organic azides.
J. Am. Chem. Soc. 127 , 15998, (2005) Cp*RuCl(PPh3)2 is an effective catalyst for the regioselective "fusion" of organic azides and terminal alkynes, producing 1,5-disubstituted 1,2,3-triazoles. Internal alkynes also participate in this catalysis, resulting in fully substituted 1,2,3-triazoles. |