(1,3-双(2,4,6-三甲基苯基)-2-咪唑烷亚基)二氯(邻异丙氧基苯亚甲基)合钌
(1,3-双(2,4,6-三甲基苯基)-2-咪唑烷亚基)二氯(邻异丙氧基苯亚甲基)合钌结构式
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常用名 | (1,3-双(2,4,6-三甲基苯基)-2-咪唑烷亚基)二氯(邻异丙氧基苯亚甲基)合钌 | 英文名 | Hoveyda-Grubbs II |
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| CAS号 | 301224-40-8 | 分子量 | 626.622 | |
| 密度 | N/A | 沸点 | N/A | |
| 分子式 | C31H38Cl2N2ORu | 熔点 | 216-220ºC(lit.) | |
| MSDS | 美版 | 闪点 | N/A |
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Highly efficient ruthenium catalysts for the formation of tetrasubstituted olefins via ring-closing metathesis.
Org. Lett. 9 , 1589, (2007) [reaction: see text] A series of ruthenium-based metathesis catalysts with N-heterocyclic carbene (NHC) ligands have been prepared in which the N-aryl groups have been changed from mesityl to mono-ortho-substituted phenyl (e.g., tolyl). These new catalysts of... |
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Sequential catalysis: a metathesis/dihydroxylation sequence.
Angew. Chem. Int. Ed. Engl. 45 , 1900, (2006)
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Ruthenium catalysed cross metathesis with fluorinated olefins.
Chem. Commun. (Camb.) , 1692, (2001) The E-selective cross metathesis (CM) of fluorinated olefins with various functionalised alkenes in good to excellent yields is reported. |
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Ring-opening metathesis/oxy-cope rearrangement: a new strategy for the synthesis of bicyclic medium ring-containing compounds.
J. Am. Chem. Soc. 125 , 14901, (2003) Ring-opening/ring-closing metathesis on cyclobutene-containing substrates with angular oxygen functionality provides a stereospecific introduction of 1,5-bis-dienes required for an anion-accelerated oxy-Cope rearrangement. The reaction sequence offers general... |
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