L-赤藓酮糖结构式
|
常用名 | L-赤藓酮糖 | 英文名 | L-(+)-Erythrulose |
|---|---|---|---|---|
| CAS号 | 533-50-6 | 分子量 | 120.104 | |
| 密度 | 1.4±0.1 g/cm3 | 沸点 | 349.6±27.0 °C at 760 mmHg | |
| 分子式 | C4H8O4 | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | 179.4±20.2 °C |
|
Double diastereoselection in aldol reactions mediated by dicyclohexylchloroborane between L-erythrulose derivatives and chiral aldehydes. The Felkin-Anh versus Cornforth dichotomy.
J. Org. Chem. 68 , 8577-8582, (2003) Both matched and mismatched diastereoselections have been observed in aldol reactions of the B,B-dicyclohexylboron enolate of a protected l-erythrulose derivative with a range of chiral aldehydes. The stereochemical outcome of reactions with alpha-methyl alde... |
|
|
Aldol reactions between L-erythrulose derivatives and chiral alpha-amino and alpha-fluoro aldehydes: competition between Felkin-Anh and Cornforth transition states.
Chemistry 14 , 9240-9254, (2008) Both matched and mismatched diastereoselection have been observed in aldol reactions of a boron enolate of a protected L-erythrulose derivative with several chiral alpha-fluoro and alpha-amino aldehydes. Strict adherence to the Felkin-Anh model for the respec... |
|
|
Double diastereoselection in aldol reactions mediated by dicyclohexylchloroborane between chiral aldehydes and a chiral ethyl ketone derived from L-erythrulose. synthesis of a C1-C9 fragment of the structure of the antifungal metabolite soraphen A1alpha.
J. Org. Chem. 70 , 8130-8139, (2005) [Chemical reaction: See text] Both matched and mismatched diastereoselections have been observed in the aldol reactions of a range of chiral aldehydes with the dicyclohexylboron enolate of a chiral ethyl ketone related to L-erythrulose. As was previously obse... |
|
|
Characterization and inactivation of the membrane-bound polyol dehydrogenase in Gluconobacter oxydans DSM 7145 reveals a role in meso-erythritol oxidation.
Microbiology 156 , 1890-1899, (2010) The growth of Gluconobacter oxydans DSM 7145 on meso-erythritol is characterized by two stages: in the first stage, meso-erythritol is oxidized almost stoichiometrically to L-erythrulose according to the Bertrand-Hudson rule. The second phase is distinguished... |
|
|
Identification of novel thermostable taurine-pyruvate transaminase from Geobacillus thermodenitrificans for chiral amine synthesis.
Appl. Microbiol. Biotechnol. 100 , 3101-11, (2016) ω-Transaminases (ω-TAs) are one of the most popular candidate enzymes in the biosynthesis of chiral amines. Determination of yet unidentified ω-TAs is important to broaden their potential for synthetic application. Taurine-pyruvate TA (TPTA, EC 2.6.1.77) is a... |
|
|
The non-oxidative degradation of ascorbic acid at physiological conditions.
Biochim. Biophys. Acta 1501(1) , 12-24, (2000) The degradation of L-ascorbate (AsA) and its primary oxidation products, L-dehydroascorbate (DHA) and 2,3-L-diketogulonate (2, 3-DKG) were studied under physiological conditions. Analysis determined that L-erythrulose (ERU) and oxalate were the primary degrad... |