2,6-二甲基苯硼酸结构式
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常用名 | 2,6-二甲基苯硼酸 | 英文名 | 3,5-Dimethylphenylboronic acid |
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| CAS号 | 100379-00-8 | 分子量 | 149.98 | |
| 密度 | 1.1±0.1 g/cm3 | 沸点 | 299.9±50.0 °C at 760 mmHg | |
| 分子式 | C8H11BO2 | 熔点 | 105 °C (dec.)(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 135.2±30.1 °C |
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Highly efficient aerobic oxidative hydroxylation of arylboronic acids: photoredox catalysis using visible light.
Angew. Chem. Int. Ed. Engl. 3rd ed., 51 , 784-788, (2012)
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Room-temperature synthesis of tetra-ortho-substituted biaryls by NHC-catalyzed Suzuki-Miyaura couplings.
Chemistry 46th ed., 17 , 12886-12890, (2011)
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ipso-Nitration of arylboronic acids with bismuth nitrate and perdisulfate.
Org. Lett. 7th ed., 14 , 1736-1739, (2012) An efficient and one pot synthetic method of ipso-nitration of arylboronic acids has been developed. The high efficiency, general applicability, and broader substrate scope including heterocycles and functional groups make this method advantageous. Due to its... |
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Solid-phase synthesis of smac peptidomimetics incorporating triazoloprolines and biarylalanines.
ACS Comb. Sci. 6th ed., 13 , 667-675, (2011) Apoptotic induction mechanisms are of crucial importance for the general homeostasis of multicellular organisms. In cancer the apoptotic pathways are downregulated, which, at least partly, is due to an abundance of inhibitors of apoptosis proteins (IAPs) that... |
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Nickel-catalyzed cross-coupling of chromene acetals and boronic acids.
Org. Lett. 6th ed., 14 , 1616-1619, (2012) A modular and highly efficient protocol for the synthesis of 2-aryl- and heteroaryl-2H-chromenes is described. Under base-free conditions, readily accessible 2-ethoxy-2H-chromenes undergo C(sp(3))-O activation and C(sp(3))-C bond formation in the presence of ... |
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Discovery of phenylpropanoic acid derivatives containing polar functionalities as potent and orally bioavailable G protein-coupled receptor 40 agonists for the treatment of type 2 diabetes.
J. Med. Chem. 8th ed., 55 , 3756-3776, (2012) As part of a program to identify potent GPR40 agonists with drug-like properties suitable for clinical development, the incorporation of polar substituents was explored with the intention of decreasing the lipophilicity of our recently disclosed phenylpropano... |
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Identification of inhibitors of the Leishmania cdc2-related protein kinase CRK3.
ChemMedChem 12th ed., 6 , 2214-2224, (2011) New drugs are urgently needed for the treatment of tropical parasitic diseases such as leishmaniasis and human African trypanosomiasis (HAT). This work involved a high-throughput screen of a focussed kinase set of ~3400 compounds to identify potent and parasi... |
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Rhodium(I)-catalyzed 1,4-addition of arylboronic acids to acrylic acid in water: one-step preparation of 3-arylpropionic acids Vautravers, N. R.; Breit, B.
Synlett 17 , 2517-2520, (2011)
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Santos-Filho, E. F.; et al.
Tetrahedron Lett. 52 , 5288, (2011)
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Expanding the scope of the Cu assisted Suzuki-Miyaura reaction Crowley, B. M.; et al.
Tetrahedron Lett. 52 , 5055-5059, (2011)
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