1,3-环庚二酮
1,3-环庚二酮结构式
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常用名 | 1,3-环庚二酮 | 英文名 | 1,3-Cycloheptanedione |
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| CAS号 | 1194-18-9 | 分子量 | 126.15 | |
| 密度 | 1.1±0.1 g/cm3 | 沸点 | 250.7±23.0 °C at 760 mmHg | |
| 分子式 | C7H10O2 | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | 92.2±19.6 °C |
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A Mild, Large-Scale Synthesis of 1,3-Cyclooctanedione: Expanding Access to Difluorinated Cyclooctyne for Copper-Free Click Chemistry.
Tetrahedron Lett. 52(16) , 1871-1873, (2011) We report the large-scale synthesis of 1,3-cyclooctanedione in five steps with 29% yield. This molecule is a synthetic precurser to difluorinated cyclooctyne, which participates in a bioorthogonal copper-free click reaction with azides. The final step demonst... |
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Michael addition of 1, 3-cyclopentanedione, 1, 3-cyclohexanedione and 1, 3-cycloheptanedione to 1-(X-phenyl)-2-nitroethylenes. Hrnciar P and Culák I.
Collect. Czech. Chem. Commun. 49(6) , 1421-1431, (1984)
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Methylation of 1, 3-cyclopentanedione, 1, 3-cyclohexanedione, and 1, 3-cycloheptanedione with iodomethane in aprotic solvents in the absence and in the presence of 18-crown-6. Šraga J and Hrnciar P.
Chemical Papers (Slovak Acad. Sci.) 35(1) , 119-126, (1981)
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Michael additions of 1, 3-cycloalkanediones to dimethyl acety-lenedicarboxylate. Hrnciar P, et al.
Chemical Papers (Slovak Acad. Sci.) 43(1) , 87-95, (1989)
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