甲基丙二酸亚异丙酯
甲基丙二酸亚异丙酯结构式
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常用名 | 甲基丙二酸亚异丙酯 | 英文名 | 2,2,5-Trimethyl-1,3-dioxane-4,6-dione |
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| CAS号 | 3709-18-0 | 分子量 | 158.152 | |
| 密度 | 1.1±0.1 g/cm3 | 沸点 | 343.6±35.0 °C at 760 mmHg | |
| 分子式 | C7H10O4 | 熔点 | 111-114 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 183.4±24.4 °C |
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Three-component synthesis of dialkyl 2-(alkylimino-methylene)3- (2,2,5-trimethyl-4,6-dioxo-1,3-dioxan-5-yl)-succinates.
Mol. Divers. 10(2) , 247-50, (2006) The adduct produced in the reaction between alkyl isocyanides and dialkyl acetylenedicarboxylates was trapped by 2,2,5-trimethyl-1,3-dioxane-4,6-dione (methyl Meldrum's acid), to afford highly functionalized ketenimines in good yields. |
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An ESR, ENDOR, and ELDOR study of tunneling rotation of a hindered methyl group in x-irradiated 2, 2, 5-trimethyl-1, 3-dioxane-4, 6-dione crystals. Geoffroy M, et al.
J. Chem. Phys. 70(9) , 4238-42, (2008)
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