![]() 内消旋-氢化苯偶烟结构式
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常用名 | 内消旋-氢化苯偶烟 | 英文名 | meso-1,2-Diphenyl-1,2-ethanediol |
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CAS号 | 579-43-1 | 分子量 | 214.26000 | |
密度 | 1.193 g/cm3 | 沸点 | 373ºC at 760 mmHg | |
分子式 | C14H14O2 | 熔点 | 134-137ºC | |
MSDS | 中文版 美版 | 闪点 | 179.8ºC |
Desymmetrization of meso-hydrobenzoin using chiral, nucleophilic phosphine catalysts.
J. Org. Chem. 69(4) , 1389-92, (2004) The desymmetrization of meso-hydrobenzoin is described using chiral phosphine catalysts 8b-d and 9-11. The best enantioselectivity at room temperature was obtained with the newly synthesized phospholane 8c and benzoic anhydride, but the reaction is very slow.... |
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Preparation and crystal structures of trans-methyl meso-hydrobenzoin phosphite and phosphate. Newton MG and Campbell BS.
J. Am. Chem. Soc. 96(25) , 7790-97, (1974)
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Conversion of meso-Hydrobenzoin with Arylsulfonyl Chlorides and Base to trans-Stilbene Oxide and to 1, 1-Diphenyl-2-(p-toluenesulfonyloxy) ethylene1. Curtin DY and Hendrickson YG.
J. Org. Chem. 21(11) , 1260-63, (1956)
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