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内消旋-氢化苯偶烟

内消旋-氢化苯偶烟结构式
内消旋-氢化苯偶烟结构式
品牌特惠专场
常用名 内消旋-氢化苯偶烟 英文名 meso-1,2-Diphenyl-1,2-ethanediol
CAS号 579-43-1 分子量 214.26000
密度 1.193 g/cm3 沸点 373ºC at 760 mmHg
分子式 C14H14O2 熔点 134-137ºC
MSDS 中文版 美版 闪点 179.8ºC

Desymmetrization of meso-hydrobenzoin using chiral, nucleophilic phosphine catalysts.

J. Org. Chem. 69(4) , 1389-92, (2004)

The desymmetrization of meso-hydrobenzoin is described using chiral phosphine catalysts 8b-d and 9-11. The best enantioselectivity at room temperature was obtained with the newly synthesized phospholane 8c and benzoic anhydride, but the reaction is very slow....

Preparation and crystal structures of trans-methyl meso-hydrobenzoin phosphite and phosphate. Newton MG and Campbell BS.

J. Am. Chem. Soc. 96(25) , 7790-97, (1974)

Conversion of meso-Hydrobenzoin with Arylsulfonyl Chlorides and Base to trans-Stilbene Oxide and to 1, 1-Diphenyl-2-(p-toluenesulfonyloxy) ethylene1. Curtin DY and Hendrickson YG.

J. Org. Chem. 21(11) , 1260-63, (1956)